Abstract:
THE RECOVERY OF EPSILON CAPROLACTONE AND OF ALKANE DICARBOXYLIC ACIDS FROM MIXTURES SUCH AS ARE OBTAINED IN THE INDIVIDUAL WASHING STEPS OF THE PROCESS FOR OXIDATION OF CYCLOHEXANE WITH AIR AT ELEVATED TEMPERATURE AND AT SUPERATMOSPHERIC PRESSURE AND CONTAINING SUBSTANTIALLY MONOCARBOXYLIC ACIDS, DICARBOXYLIC ACIDS AND EPSILON-HYDROXYCAPROIC ACID (IF DESIRED AFTER PART OF THE ADIPIC ACID PRESENT HAS BEEN SEPARATED) BY REMOVING WATER (IF PRESENT) AND THE MAJOR PORTION OF THE MONOCARBOXYLIC ACIDS (IF PRESENT) BY DISTILLATION, ADDING 1 TO 30% BY WEIGHT OF PHOSPHORIC ACID OR A COMPOUND FORMING THE SAME OR BORIC ACID, HEATING THE MIXTURE OBTAINED UNDER SUBATMOSPHERIC COMPONENTS, CONDENSING THE INDIVIDUAL FRACTIONS AND RECTIFYING AND/OR CRYSTALLIZING THE FRACTIONS. DISTILLATION TEMPERATURES ABOVE 150*C. ARE AVOIDED. EPSILON CAPROLACTONE IS USEFUL FOR THE PRODUCTION OF CAPROLACTAM, A STARTING MATERIAL FOR THE PRODUCTION OF FIBERS.
Abstract:
PCT No. PCT/EP97/02571 Sec. 371 Date Nov. 5, 1998 Sec. 102(e) Date Nov. 5, 1998 PCT Filed May 20, 1997 PCT Pub. No. WO97/44366 PCT Pub. Date Nov. 27, 1997Polyalkeneamines of the formula (I) where R1, R2, R3, R4, R5 and R6 may have different meanings, are prepared by a process in which a polyalkene epoxide is reacted with an amine and the amino alcohol is dehydrated and reduced to give the compound of the formula (I).
Abstract:
PCT No. PCT/EP97/02571 Sec. 371 Date Nov. 5, 1998 Sec. 102(e) Date Nov. 5, 1998 PCT Filed May 20, 1997 PCT Pub. No. WO97/44366 PCT Pub. Date Nov. 27, 1997Polyalkeneamines of the formula (I) where R1, R2, R3, R4, R5 and R6 may have different meanings, are prepared by a process in which a polyalkene epoxide is reacted with an amine and the amino alcohol is dehydrated and reduced to give the compound of the formula (I).
Abstract:
PCT No. PCT/EP97/02571 Sec. 371 Date Nov. 5, 1998 Sec. 102(e) Date Nov. 5, 1998 PCT Filed May 20, 1997 PCT Pub. No. WO97/44366 PCT Pub. Date Nov. 27, 1997Polyalkeneamines of the formula (I) where R1, R2, R3, R4, R5 and R6 may have different meanings, are prepared by a process in which a polyalkene epoxide is reacted with an amine and the amino alcohol is dehydrated and reduced to give the compound of the formula (I).
Abstract:
PCT No. PCT/EP97/02571 Sec. 371 Date Nov. 5, 1998 Sec. 102(e) Date Nov. 5, 1998 PCT Filed May 20, 1997 PCT Pub. No. WO97/44366 PCT Pub. Date Nov. 27, 1997Polyalkeneamines of the formula (I) where R1, R2, R3, R4, R5 and R6 may have different meanings, are prepared by a process in which a polyalkene epoxide is reacted with an amine and the amino alcohol is dehydrated and reduced to give the compound of the formula (I).
Abstract:
In the present invention, there is described a process for preparing polyalkene amines of the general formula I wherein the preparation process is characterized in that epoxide of the general formula IV is brought into reaction with a nitrogen-bearing compound of the general formula V to give amino alcohol of the general formula VI and this amino alcohol of the general formula VI is then catalytically dehydrated and obtained olefin is hydrogenated to give the amine of the general formula I. Substituents in the indicated compounds have meaning explained in description.
Abstract:
PCT No. PCT/EP97/02571 Sec. 371 Date Nov. 5, 1998 Sec. 102(e) Date Nov. 5, 1998 PCT Filed May 20, 1997 PCT Pub. No. WO97/44366 PCT Pub. Date Nov. 27, 1997Polyalkeneamines of the formula (I) where R1, R2, R3, R4, R5 and R6 may have different meanings, are prepared by a process in which a polyalkene epoxide is reacted with an amine and the amino alcohol is dehydrated and reduced to give the compound of the formula (I).
Abstract:
PCT No. PCT/EP97/02571 Sec. 371 Date Nov. 5, 1998 Sec. 102(e) Date Nov. 5, 1998 PCT Filed May 20, 1997 PCT Pub. No. WO97/44366 PCT Pub. Date Nov. 27, 1997Polyalkeneamines of the formula (I) where R1, R2, R3, R4, R5 and R6 may have different meanings, are prepared by a process in which a polyalkene epoxide is reacted with an amine and the amino alcohol is dehydrated and reduced to give the compound of the formula (I).
Abstract:
PCT No. PCT/EP97/02571 Sec. 371 Date Nov. 5, 1998 Sec. 102(e) Date Nov. 5, 1998 PCT Filed May 20, 1997 PCT Pub. No. WO97/44366 PCT Pub. Date Nov. 27, 1997Polyalkeneamines of the formula (I) where R1, R2, R3, R4, R5 and R6 may have different meanings, are prepared by a process in which a polyalkene epoxide is reacted with an amine and the amino alcohol is dehydrated and reduced to give the compound of the formula (I).
Abstract:
PCT No. PCT/EP97/02571 Sec. 371 Date Nov. 5, 1998 Sec. 102(e) Date Nov. 5, 1998 PCT Filed May 20, 1997 PCT Pub. No. WO97/44366 PCT Pub. Date Nov. 27, 1997Polyalkeneamines of the formula (I) where R1, R2, R3, R4, R5 and R6 may have different meanings, are prepared by a process in which a polyalkene epoxide is reacted with an amine and the amino alcohol is dehydrated and reduced to give the compound of the formula (I).