1.
    发明专利
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    公开(公告)号:CH599216A5

    公开(公告)日:1978-05-12

    申请号:CH267076

    申请日:1976-03-03

    Applicant: BASF AG

    Abstract: 1535855 Lactones BASF AG 4 March 1976 [6 March 1975] 08652/76 Heading C4P [Also in Division C2] The invention comprises diazarhodamine lactones of the general formula wherein R 1 is H or C 1 -C 4 alkyl, R 2 is C 1 -C 4 alkyl, phenyl which may be substituted by one or two C 1 -C 3 alkyl, Cl or Br substituents which may be different, R 3 and R 4 are H, C 1 -C 7 alkyl, C 5 -C 7 cycloalkyl, phenylalkyl having 7-10 C atoms or alkoxyalkyl having 3-8 C atoms or the group -N(R 3 )R 4 may form a 5-, 6- or 7- membered saturated heterocyclic ring or a 6-membered saturated heterocyclic ring which contains one of the groups -O-, -S-or-N(R 6 )- where R 6 is H, methyl or ethyl, and R 5 is phenyl which may be substituted by C 1 -C 3 alkyl, methoxy, ethoxy, Cl or Br. They are prepared by condensing a benzoylbenzoic acid of the general formula with a 2-aminopyrimidine of the general formula wherein R 1 -R 5 are as above and R 7 and R 8 are independently H, C 1 -C 4 -alkyl or C-acyl having 2-7 C atoms. Condensation takes place at 60-160‹C. in an acid solvent in presence of one or more acidic dehydrating agents. The compounds are used in pressure sensitive copying processes.

    Pyrimidine disperse azo dyes - prepd from diazotisable aromatic amines,for textiles

    公开(公告)号:DE2258609A1

    公开(公告)日:1974-06-06

    申请号:DE2258609

    申请日:1972-11-30

    Applicant: BASF AG

    Abstract: Title dyes are of formula: D-N=N-A (I) where D is the residue of a diazotisable aniline substd by in not 1 2nd order substit., or of a diazotisable amino-naphthalene, aminobiphenyl, aminoazobenzene, aminoanthraquinone, or heterocyclic amine, and A is a gp. of formula: where Z is H or a (substd). (cyclo)aliphatic, araliphatic aromatic, or heterocyclic gp; Z1 is H or a (substd). (cyclo)aliphatic, araliphatic or aromatic gp; Z2 is H or a (substd) aliphatic gp. or Z1 and Z2 form a heterocyclic gp. with the N atom; Z3 has the same meaning as Z1, Z4 has the same meaning as Z2, Z3 and Z4 may form a heterocyclic gp. with the N atom, and 1 of the gps. Z1-Z4 is not H. Suitable 2nd order substits. include NO2. CN, alkanoyl, aroyl, alkyl- or phenyl-sulphonyl, carbalkoxy (substd). carbamoyl, or sulphamoyl, or sulphonic acid ester gps. I are yellow to blue and can be used to dye polyacrylonitrile, synthetic polyamide, cellulose, ester and esp. linear polyester textiles. Fast dyeings of good colour strength are obtd.

    Monoazo dispersion dyes - from 4,6-or 2,6-diamino pyrimidine coupling components

    公开(公告)号:DE2202820A1

    公开(公告)日:1973-07-26

    申请号:DE2202820

    申请日:1972-01-21

    Applicant: BASF AG

    Abstract: The dyes are of formula D-N=N-A, (in which D is the group of a diazo component and A is a group of formula (I) or (II): in which B is hydrogen, alkyl opt. substd. with hydroxy, alkoxy, alkanoyl oxy, or phenoxy, aralkyl cycloalkyl or opt. substd. phenyl, R is hydrogen, 1-8 C alkyl, 2-7 C hydroxyalkyl, 3-11 C alkoxyalkyl, up to 11 C phenoxyalkyl, 2-15 C carbalkoxyalkyl, up to 15 C acyloxyalkyl, opt. substd. phenyl, cyclohexyl, benzyl, phenylethyl or epsilon -N-pyrrolidonalkyl, R1 is hydrogen, 1-8 C alkyl, 2-7 C hydroxyalkyl or up to 15 C acyloxyalkyl, or RR1 together with N form a pyrrolidine, piperidine or morpholine group, R2 is as R and R3 as R1, but not all are hydrogen. The alkyl chains may be interrupted by O atoms. The dyes are yellow to blue and suitable for colouring of textiles of polyacrylonitrile, synthetic polyamides, cellulose esters, and esp. linear polyester, giving strong colours with good fastness.

    Pyrimidine disperse azo dyes - prepd from diazotisable aromatic amines,for textiles

    公开(公告)号:DE2261755A1

    公开(公告)日:1974-06-27

    申请号:DE2261755

    申请日:1972-12-16

    Applicant: BASF AG

    Abstract: Title dyes are of formula: D-N=N-A (I) where D is the residue of a diazotisable aniline substd by in not 1 2nd order substit., or of a diazotisable amino-naphthalene, aminobiphenyl, aminoazobenzene, aminoanthraquinone, or heterocyclic amine, and A is a gp. of formula: where Z is H or a (substd). (cyclo)aliphatic, araliphatic aromatic, or heterocyclic gp; Z1 is H or a (substd). (cyclo)aliphatic, araliphatic or aromatic gp; Z2 is H or a (substd) aliphatic gp. or Z1 and Z2 form a heterocyclic gp. with the N atom; Z3 has the same meaning as Z1, Z4 has the same meaning as Z2, Z3 and Z4 may form a heterocyclic gp. with the N atom, and 1 of the gps. Z1-Z4 is not H. Suitable 2nd order substits. include NO2. CN, alkanoyl, aroyl, alkyl- or phenyl-sulphonyl, carbalkoxy (substd). carbamoyl, or sulphamoyl, or sulphonic acid ester gps. I are yellow to blue and can be used to dye polyacrylonitrile, synthetic polyamide, cellulose, ester and esp. linear polyester textiles. Fast dyeings of good colour strength are obtd.

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