公开(公告)号：WO2006106123A3

公开(公告)日：2007-01-18

申请号：PCT/EP2006061352

申请日：2006-04-05

Applicant: BASF AG ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  AECHTNER TOBIAS ,  SCHEIDEL JENS ,  DIENES CHRISTIAN ,  TEMPEL ALEXANDER ,  HOFRICHTER THORSTEN ,  WEINLE WERNER

Inventor： BARTSCH MICHAEL ,  HADERLEIN GERD ,  AECHTNER TOBIAS ,  SCHEIDEL JENS ,  DIENES CHRISTIAN ,  TEMPEL ALEXANDER ,  HOFRICHTER THORSTEN ,  WEINLE WERNER

IPC: C07C37/11 ,  C07C39/15 ,  C07F9/02

CPC classification number: C07C37/11 ,  C07C39/15

Abstract: The invention relates to a method for producing biphenols of general formula (I) by reacting monophenols of general formula (II), wherein the radicals R1, R2 and R3 independently represent hydrogen, alkyl, aryl or arylalkyl, with 1 - 10 C-atoms, in the presence of an oxidation agent in a reactor. Said method is characterised in that a) the reactor does not contain any stationary integrated components which act as a current agitator, b) a maximum of 0,6 mol of oxidation agents are used per mol of monophenol, and c) the oxidation agent is added in a continuous or discontinuous manner in a plurality of portions within a time span of between 10 min - 24 hours, whereby the amount of oxidation agent which is added per time unit is not constant over the entire tine span, but is varied.

Abstract translation: 一种用于在一个存在下，通过式（II）其中基团R1，R2和R3独立地是氢，烷基，芳基或芳烷基的碳原子数1〜10中的一元酚的反应由通式（I）制备双酚过程 氧化剂在反应器中，其特征在于：a）反应器含有不作为挡板作用固定设备，b）中的最大0.6摩尔的氧化剂是每单酚的一倍摩尔使用的，和c）在一段10分钟至24氧化剂 小时或者连续，或间歇地在几个部分中，加入，引入氧化剂的每单位量不随时间恒定的整个期间而被改变。

公开(公告)号：WO2006042675A2

公开(公告)日：2006-04-27

申请号：PCT/EP2005010956

申请日：2005-10-12

Applicant: BASF AG ,  DECKERT PETRA ,  BASSLER PETER ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  PFAB PETER ,  AECHTNER TOBIAS ,  SIEGEL WOLFGANG

Inventor： DECKERT PETRA ,  BASSLER PETER ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  PFAB PETER ,  AECHTNER TOBIAS ,  SIEGEL WOLFGANG

CPC classification number: B01J31/4053 ,  B01D11/0434 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J31/403 ,  B01J2231/323 ,  B01J2531/847 ,  C07C253/10 ,  C07C253/32 ,  Y02P20/584 ,  C07C255/04

Abstract: The invention relates to a method for the extractive separation of homogeneously dissolved catalysts from a reaction product from a hydrocyanation of unsaturated mononitriles to dinitriles, by extraction with a carbon material (K), characterised in that a) a non-polar aprotic liquid (F) is added to the reaction product to give a stream (I) and b) the stream (I) is extracted with a carbon material (K) at a temperature (T), to give a stream (II), containing the carbon material (K), enriched with the catalyst and a stream (III), stripped of catalyst.

Abstract translation: 通过烃的装置（K），其特征在于用于由不饱和单腈向二腈，通过萃取的氢氰化反应流出物均匀溶解的催化剂的提取分离方法，包括：a）向所述反应在非极性非质子液体（F），由此电流 在温度（T）（与烃K（I）获得，以及b）的电流（I））被提取，其特征在于，一个流（II）含有富含与催化剂烃（K）和催化剂贫流（ III）。

公开(公告)号：WO2005073166A2

公开(公告)日：2005-08-11

申请号：PCT/EP2005000773

申请日：2005-01-27

Applicant: BASF AG ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  SCHINDLER GOETZ-PETER ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  BRODHAGEN ANDREAS

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  SCHINDLER GOETZ-PETER ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  BRODHAGEN ANDREAS

IPC: C07C253/10 ,  C07C255/07 ,  C07C253/00

CPC classification number: C07C253/10 ,  C07C255/07

Abstract: The invention relates to a method for hydrocyanation of 1,3-butadiene on at least one nickel(o) complex with phosphor-containing ligands as a catalyst, wherein 1,3-butadiene is used in a mixture with n-butane and the mixture contains 60 - 90 vol. % 1,3-butadiene and 40 -10 vol. % n-butane.

Abstract translation: 公开了一种用于1,3-丁二烯的在至少一个镍（O）氢氰化过程复杂具有磷配体作为催化剂，其中，所述1,3-丁二烯以与正丁烷的混合物和60至90体积混合物中使用 .-％含有1,3-丁二烯和40至10％（体积）正丁烷。

公开(公告)号：WO2005073178A3

公开(公告)日：2005-09-22

申请号：PCT/EP2005000724

申请日：2005-01-26

Applicant: BASF AG ,  JUNGKAMP TIM ,  POLKA HANS-MARTIN ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS

Inventor： JUNGKAMP TIM ,  POLKA HANS-MARTIN ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS

IPC: C07C253/34 ,  C07C255/04 ,  C07C255/07

CPC classification number: C07C253/34 ,  C07C255/07 ,  C07C255/04

Abstract: The invention relates to a method for separating hydrogen cyanide from mixtures containing pentenenitrile, by means of the azeotropic distillation of hydrogen cyanide with 1,3-butadiene.

Abstract translation: 公开了一种用于氰化氢的从含有其中通过与1,3-丁二烯氰化氢的共沸蒸馏分离进行戊烯腈混合物中分离的方法。

公开(公告)号：WO2007074046A3

公开(公告)日：2007-09-07

申请号：PCT/EP2006069528

申请日：2006-12-11

Applicant: BASF AG ,  SIEGEL WOLFGANG ,  HADERLEIN GERD ,  STAEB TOBIAS

Inventor： SIEGEL WOLFGANG ,  HADERLEIN GERD ,  STAEB TOBIAS

IPC: C07C213/06 ,  C07C217/52

CPC classification number: C07C213/06 ,  C07C2601/14 ,  C07C217/52

Abstract: Method for producing O-alkylated aminoalcohols by reacting N-unsubstituted or N-monosubstituted aminoalcoholates with alkyl halides, the aminoalcoholates being formed by means of alkali hydroxides or alkaline earth hydroxides.

Abstract translation: 一种用于通过N-未取代的或N-单取代的Aminoalkoholatsalzen用烷基卤，其中所述Aminoalkoholatsalze由碱金属或碱土金属氢氧化物来形成反应制备O-烷基化氨基醇的过程。

公开(公告)号：WO2007115936A3

公开(公告)日：2007-11-29

申请号：PCT/EP2007052955

申请日：2007-03-28

Applicant: BASF AG ,  HADERLEIN GERD ,  AECHTNER TOBIAS ,  BARTSCH MICHAEL ,  LUYKEN HERMANN ,  PFAB PETER ,  SCHEIDEL JENS ,  LEITNER ANDREAS

Inventor： HADERLEIN GERD ,  AECHTNER TOBIAS ,  BARTSCH MICHAEL ,  LUYKEN HERMANN ,  PFAB PETER ,  SCHEIDEL JENS ,  LEITNER ANDREAS

IPC: B01D11/04 ,  B01J31/18 ,  B01J31/24 ,  B01J31/40 ,  C07C253/10 ,  C07C253/32

CPC classification number: B01J31/403 ,  B01D11/0426 ,  B01D11/0457 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/24 ,  B01J31/4053 ,  C07C253/34 ,  C07D333/48 ,  Y02P20/584 ,  C07C255/09

Abstract: The invention relates to a method for extractive separation of nickel (0) complexes with phosphorous ligands, from a reaction product of a hydrocyanation of unsaturated mononitriles to give dinitriles, by means of extraction with a hydrocarbon, wherein a phase separation of the hydrocarbon and the nitrile-containing solution into two phases occurs, by addition of a polar additive to the reaction product (feed stream) and/or the extraction stage.

Abstract translation: 一种用于提取处理中除去镍处理（0）通过烃的装置具有由不饱和单腈向二腈，通过萃取的氢氰化反应流出物的磷配位体配合物，所述烃和含腈溶液的相分离成两相是由氢氰化进行 放电（进料流）和/或提取阶段被提供至少一种极性添加剂。

公开(公告)号：WO2005042157A3

公开(公告)日：2005-07-21

申请号：PCT/EP2004012180

申请日：2004-10-28

Applicant: BASF AG ,  HADERLEIN GERD ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG

Inventor： HADERLEIN GERD ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG

IPC: B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C255/04 ,  C07F15/04 ,  B01J37/16 ,  B01J31/30

CPC classification number: C07F15/045 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/1875 ,  B01J31/24 ,  B01J2231/323 ,  B01J2231/52 ,  B01J2531/847 ,  C07C253/10 ,  C07F15/04 ,  C07C255/04

Abstract: The invention relates to a method for the production of nickel(0)-phosphorous ligand complexes from nickel(II)-ether adducts.

Abstract translation: 本发明是从镍（II）醚加合物开始制备镍（0）磷配体配合物的方法。

公开(公告)号：WO0213964A2

公开(公告)日：2002-02-21

申请号：PCT/EP0108522

申请日：2001-07-24

Applicant: BASF AG ,  BARTSCH MICHAEL ,  KUNSMANN KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  SIEGEL WOLFGANG

Inventor： BARTSCH MICHAEL ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  SIEGEL WOLFGANG

IPC: B01J31/18 ,  B01J31/28 ,  C07F9/145 ,  C07F9/46 ,  C07F9/48 ,  C07F9/6574 ,  C07F15/04 ,  C07C253/10

CPC classification number: C07F15/045 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/28 ,  B01J2231/323 ,  B01J2231/52 ,  B01J2531/847 ,  C07F9/145 ,  C07F9/46 ,  C07F9/4875 ,  C07F9/65746

Abstract: The invention relates to a catalyst containing a nickel complex (0) with ligands of formula (I) Y - E - X - E - Y wherein X represents arylene or heteroarylene, E , E independently represent O or NZ . Y , Y can be the same or different and independently represent a radical of formula (II.1) or (II.2), -P(-E -R )(-E -R ) wherein E 3, E , E , E can be the same or different and independently represent a chemical bond or independently represent O or NZ . R , R can be the same or different and independently represent a cycloalkyl, aryl, heterocycloalkyl or heteroaryl group. R together with part of the system -E -P-E -,to which it is bonded, represents a 5-, 6-, 7- or 8-membered heterocycle.

Abstract translation: 包含镍（0）配合物与式（I）的配体的催化剂：Y <1> - 电子<1> - X - 电子<2> - ý<2>，其中X是亚芳基或亚杂芳基，E < 1>，E <2>彼此5>独立地是O或NZ <，Y <1>，Y <2>可以相同或unterschliedlich是和各自独立地为式基团（II.1）的： - P（ - ë<3> -R <1>）（ - 电子<4> -R <2>中提供（II.2）），或者其中，e <3>，E <4>中，E <5>电子<6> 可以相同或不同，并且可以是一个化学键或彼此独立地独立地为O或NZ <11>，R <1>，R <2>可以相同或不同，且独立地表示环烷基，芳基，杂环烷基 - 或杂芳基，R <3>与所述系统的所述部分一起-E <5> -PE <6> - 其所键合的，代表一个5-，6-，7-或8-元杂环。

公开(公告)号：BRPI0506587B1

公开(公告)日：2014-10-29

申请号：BRPI0506587

申请日：2005-01-27

Applicant: BASF AG

Inventor： SCHEIDEL JENS ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  JUNGKAMP TIM ,  BARTSCH MICHAEL ,  BAUMANN ROBERT

IPC: C07C253/10 ,  C07C253/34 ,  C07C255/07

Abstract: A process is described for preparing 3-pentenenitrile, characterized by the following process steps: (a) reacting 1,3-butadiene with hydrogen cyanide over at least one catalyst to obtain a stream 1 which comprises 3-pentenenitrile, 2-methyl-3-butenenitrile, the at least one catalyst and 1,3-butadiene, (b) distilling stream 1 in a column to obtain a high-1,3-butadiene stream 2 as the top product and a low-1,3-butadiene stream 3 as the bottom product which comprises 3-pentenenitrile, the at least one catalyst and 2-methyl-3-butenenitrile, (c) distilling stream 3 in a column to obtain a stream 4 as the top product which comprises 1,3-butadiene, a stream 5 which comprises 3-pentenenitrile and 2-methyl-3-butenenitrile at a side draw of the column, and a stream 6 as the bottom product which comprises the at least one catalyst, (d) distilling stream 5 to obtain a stream 7 as the top product which comprises 2-methyl-3-butenenitrile, and a stream 8 as the bottom product which comprises 3-pentenenitrile.

公开(公告)号：BRPI0506581B1

公开(公告)日：2014-10-29

申请号：BRPI0506581

申请日：2005-01-27

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  SCHEIDEL JENS ,  JUNGKAMP TIM ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD

IPC: C07C253/10 ,  C07C255/04

Abstract: An adiponitrile/methylglutaronitrile preparation process includes distilling a reaction stream to obtain stream 3 depleted in pentenenitriles (bottom product) and stream 4 enriched in pentenenitriles (top product); extracting stream 3 obtaining stream 6 enriched with extractant (top product) and stream 7 depleted in extractant (bottom product); distilling stream 6 obtaining stream 8 comprising the catalyst (bottom product) and stream 9 comprising the extractant (top product); distilling stream 7 obtaining stream 10 (bottom product) and stream 11 comprising the extractant (top product); distilling stream 10 obtaining stream 12 comprising catalyst degradation products, at least one promotor, adiponitrile and methylglutaronitrile (bottom product) and stream 13 comprising pentenenitriles (top product); distilling stream 12 obtaining stream 14 comprising catalyst degradation products and the promotor(s) (bottom product) and stream 15 comprising adiponitrile and methylglutaronitrile (top product); distilling stream 15 obtaining stream 16 comprising adiponitrile (bottom product) and stream 17 comprising methylglutaronitrile (top product).