公开(公告)号：JP2002338530A

公开(公告)日：2002-11-27

申请号：JP2002100061

申请日：2002-04-02

Applicant: BASF AG

Inventor： WINSEL HARALD ,  SIEGEL WOLFGANG DR ,  BARTSCH MICHAEL

IPC: C07B61/00 ,  C07C209/52 ,  C07C211/27 ,  C07C211/30 ,  C07C213/02 ,  C07C217/58 ,  C07C249/02 ,  C07C251/24

Abstract: PROBLEM TO BE SOLVED: To provide a simpler process for preparing N-benzylamine. SOLUTION: This process for preparing the N-benzylamine comprises (i) in a first step, reacting benzaldehyde with a primary amine and providing an imine and (ii) in a second step, hydrogenating the imine with hydrogen in the presence of a catalyst containing one or more kinds of metals of groups 8 to 10 of the periodic table of elements and affording the N-benzylamine, wherein the imination (i) is carried out in a water-miscible solvent without removing formed water of reaction and the hydrogenation (ii) is carried out in the imine solution obtained by the imination (i) and containing the water of reaction.

公开(公告)号：WO2006106123A3

公开(公告)日：2007-01-18

申请号：PCT/EP2006061352

申请日：2006-04-05

Applicant: BASF AG ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  AECHTNER TOBIAS ,  SCHEIDEL JENS ,  DIENES CHRISTIAN ,  TEMPEL ALEXANDER ,  HOFRICHTER THORSTEN ,  WEINLE WERNER

Inventor： BARTSCH MICHAEL ,  HADERLEIN GERD ,  AECHTNER TOBIAS ,  SCHEIDEL JENS ,  DIENES CHRISTIAN ,  TEMPEL ALEXANDER ,  HOFRICHTER THORSTEN ,  WEINLE WERNER

IPC: C07C37/11 ,  C07C39/15 ,  C07F9/02

CPC classification number: C07C37/11 ,  C07C39/15

Abstract: The invention relates to a method for producing biphenols of general formula (I) by reacting monophenols of general formula (II), wherein the radicals R1, R2 and R3 independently represent hydrogen, alkyl, aryl or arylalkyl, with 1 - 10 C-atoms, in the presence of an oxidation agent in a reactor. Said method is characterised in that a) the reactor does not contain any stationary integrated components which act as a current agitator, b) a maximum of 0,6 mol of oxidation agents are used per mol of monophenol, and c) the oxidation agent is added in a continuous or discontinuous manner in a plurality of portions within a time span of between 10 min - 24 hours, whereby the amount of oxidation agent which is added per time unit is not constant over the entire tine span, but is varied.

Abstract translation: 一种用于在一个存在下，通过式（II）其中基团R1，R2和R3独立地是氢，烷基，芳基或芳烷基的碳原子数1〜10中的一元酚的反应由通式（I）制备双酚过程 氧化剂在反应器中，其特征在于：a）反应器含有不作为挡板作用固定设备，b）中的最大0.6摩尔的氧化剂是每单酚的一倍摩尔使用的，和c）在一段10分钟至24氧化剂 小时或者连续，或间歇地在几个部分中，加入，引入氧化剂的每单位量不随时间恒定的整个期间而被改变。

公开(公告)号：WO03062171A2

公开(公告)日：2003-07-31

申请号：PCT/EP0300545

申请日：2003-01-21

Applicant: BASF AG ,  MAASE MATTHIAS ,  MASSONNE KLEMENS ,  HALBRITTER KLAUS ,  NOE RALF ,  BARTSCH MICHAEL ,  SIEGEL WOLFGANG ,  STEGMANN VEIT ,  FLORES MIGUEL ,  HUTTENLOCH OLIVER ,  BECKER MICHAEL

Inventor： MAASE MATTHIAS ,  MASSONNE KLEMENS ,  HALBRITTER KLAUS ,  NOE RALF ,  BARTSCH MICHAEL ,  SIEGEL WOLFGANG ,  STEGMANN VEIT ,  FLORES MIGUEL ,  HUTTENLOCH OLIVER ,  BECKER MICHAEL

IPC: C07D233/58 ,  B01J31/24 ,  C07B61/00 ,  C07B63/00 ,  C07B63/02 ,  C07C1/30 ,  C07C7/10 ,  C07C13/23 ,  C07C45/50 ,  C07C67/14 ,  C07C67/58 ,  C07C69/14 ,  C07C69/78 ,  C07C403/12 ,  C07D233/60 ,  C07D403/12 ,  C07F7/18 ,  C07F9/02 ,  C07F9/12 ,  C07F9/142 ,  C07F9/145 ,  C07F9/22 ,  C07F9/46 ,  C07F9/48 ,  C07F9/50 ,  C07F9/52 ,  C07F9/572 ,  C07F9/6503 ,  C07F9/6574 ,  C07F9/6584

CPC classification number: C07C403/12 ,  C07C1/30 ,  C07C45/50 ,  C07C51/412 ,  C07C51/58 ,  C07C67/14 ,  C07C2531/02 ,  C07C2601/16 ,  C07D295/185 ,  C07D317/36 ,  C07F9/142 ,  C07F9/145 ,  C07F9/46 ,  C07F9/4841 ,  C07F9/52 ,  C07F9/5721 ,  C07F9/5728 ,  C07F9/65038 ,  C07F9/65746 ,  C07F9/65848 ,  C07C47/02 ,  C07C13/23 ,  C07C69/78 ,  C07C69/24 ,  C07C69/14 ,  C07C53/10

Abstract: Disclosed is a method for separating acids from chemical reaction mixtures by means of an auxiliary base. Said auxiliary base b) forms a salt with the acid, which is liquid at temperatures at which the valuable product is not significantly decomposed during separation, and c) the salt of the auxiliary base and the valuable product or the solution of the valuable product form two immiscible fluid phases in a suitable solvent.

Abstract translation: 一种用于通过辅助碱，其中所述辅助底座B形成盐与作为在在对所需产物不显著液体盐和c的分离过程中分解的温度下是液体的酸的手段分离从反应混合物中的酸处理是辅助碱与所需产物的盐 或在合适的溶剂中的期望的产物的溶液形成两个不混溶的液相。

公开(公告)号：WO2006042675A2

公开(公告)日：2006-04-27

申请号：PCT/EP2005010956

申请日：2005-10-12

Applicant: BASF AG ,  DECKERT PETRA ,  BASSLER PETER ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  PFAB PETER ,  AECHTNER TOBIAS ,  SIEGEL WOLFGANG

Inventor： DECKERT PETRA ,  BASSLER PETER ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  PFAB PETER ,  AECHTNER TOBIAS ,  SIEGEL WOLFGANG

CPC classification number: B01J31/4053 ,  B01D11/0434 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J31/403 ,  B01J2231/323 ,  B01J2531/847 ,  C07C253/10 ,  C07C253/32 ,  Y02P20/584 ,  C07C255/04

Abstract: The invention relates to a method for the extractive separation of homogeneously dissolved catalysts from a reaction product from a hydrocyanation of unsaturated mononitriles to dinitriles, by extraction with a carbon material (K), characterised in that a) a non-polar aprotic liquid (F) is added to the reaction product to give a stream (I) and b) the stream (I) is extracted with a carbon material (K) at a temperature (T), to give a stream (II), containing the carbon material (K), enriched with the catalyst and a stream (III), stripped of catalyst.

Abstract translation: 通过烃的装置（K），其特征在于用于由不饱和单腈向二腈，通过萃取的氢氰化反应流出物均匀溶解的催化剂的提取分离方法，包括：a）向所述反应在非极性非质子液体（F），由此电流 在温度（T）（与烃K（I）获得，以及b）的电流（I））被提取，其特征在于，一个流（II）含有富含与催化剂烃（K）和催化剂贫流（ III）。

公开(公告)号：WO2005073166A2

公开(公告)日：2005-08-11

申请号：PCT/EP2005000773

申请日：2005-01-27

Applicant: BASF AG ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  SCHINDLER GOETZ-PETER ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  BRODHAGEN ANDREAS

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  SCHINDLER GOETZ-PETER ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  BRODHAGEN ANDREAS

IPC: C07C253/10 ,  C07C255/07 ,  C07C253/00

CPC classification number: C07C253/10 ,  C07C255/07

Abstract: The invention relates to a method for hydrocyanation of 1,3-butadiene on at least one nickel(o) complex with phosphor-containing ligands as a catalyst, wherein 1,3-butadiene is used in a mixture with n-butane and the mixture contains 60 - 90 vol. % 1,3-butadiene and 40 -10 vol. % n-butane.

Abstract translation: 公开了一种用于1,3-丁二烯的在至少一个镍（O）氢氰化过程复杂具有磷配体作为催化剂，其中，所述1,3-丁二烯以与正丁烷的混合物和60至90体积混合物中使用 .-％含有1,3-丁二烯和40至10％（体积）正丁烷。

公开(公告)号：WO2005073178A3

公开(公告)日：2005-09-22

申请号：PCT/EP2005000724

申请日：2005-01-26

Applicant: BASF AG ,  JUNGKAMP TIM ,  POLKA HANS-MARTIN ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS

Inventor： JUNGKAMP TIM ,  POLKA HANS-MARTIN ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS

IPC: C07C253/34 ,  C07C255/04 ,  C07C255/07

CPC classification number: C07C253/34 ,  C07C255/07 ,  C07C255/04

Abstract: The invention relates to a method for separating hydrogen cyanide from mixtures containing pentenenitrile, by means of the azeotropic distillation of hydrogen cyanide with 1,3-butadiene.

Abstract translation: 公开了一种用于氰化氢的从含有其中通过与1,3-丁二烯氰化氢的共沸蒸馏分离进行戊烯腈混合物中分离的方法。

公开(公告)号：WO0222261A2

公开(公告)日：2002-03-21

申请号：PCT/EP0110735

申请日：2001-09-17

Applicant: BASF AG ,  AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

CPC classification number: C07F9/65746 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/22 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/80 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/845 ,  C07C45/50 ,  C07F9/65522 ,  C07F9/65719 ,  C07C47/02

Abstract: The invention relates to a method for the hydroformylation of ethylenically unsaturated compounds, whereby at least one complex of a metal of subgroup VIII is used as the hydroformylation catalyst, having at least one compound containing phosphorus, arsenic, or antimony as a ligand. Each compound comprises two groups having a P, As, or Sb atom and at least two other heteroatoms, said groups being bound to a xanthene-type molecular structure. The invention also relates to novel compounds of this type and catalysts comprising at least one complex of a metal of subgroup VIII having at least one such compound as a ligand.

Abstract translation: 本发明涉及用于烯属不饱和化合物的加氢甲酰化过程中，被用作羰基化催化剂包括VIII的金属中的至少一种配合物。具有至少一个磷，砷或含锑化合物作为配体的亚组，该化合物为二P- 含有基团As或Sb原子和至少两个另外的杂原子附接至具有呫吨状分子骨架。 本发明还涉及到这种类型和催化剂包括VIII的金属中的至少一种配合物的新化合物。与作为配体的至少一个这样的化合物亚类。

公开(公告)号：WO2007115936A3

公开(公告)日：2007-11-29

申请号：PCT/EP2007052955

申请日：2007-03-28

Applicant: BASF AG ,  HADERLEIN GERD ,  AECHTNER TOBIAS ,  BARTSCH MICHAEL ,  LUYKEN HERMANN ,  PFAB PETER ,  SCHEIDEL JENS ,  LEITNER ANDREAS

Inventor： HADERLEIN GERD ,  AECHTNER TOBIAS ,  BARTSCH MICHAEL ,  LUYKEN HERMANN ,  PFAB PETER ,  SCHEIDEL JENS ,  LEITNER ANDREAS

IPC: B01D11/04 ,  B01J31/18 ,  B01J31/24 ,  B01J31/40 ,  C07C253/10 ,  C07C253/32

CPC classification number: B01J31/403 ,  B01D11/0426 ,  B01D11/0457 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/24 ,  B01J31/4053 ,  C07C253/34 ,  C07D333/48 ,  Y02P20/584 ,  C07C255/09

Abstract: The invention relates to a method for extractive separation of nickel (0) complexes with phosphorous ligands, from a reaction product of a hydrocyanation of unsaturated mononitriles to give dinitriles, by means of extraction with a hydrocarbon, wherein a phase separation of the hydrocarbon and the nitrile-containing solution into two phases occurs, by addition of a polar additive to the reaction product (feed stream) and/or the extraction stage.

Abstract translation: 一种用于提取处理中除去镍处理（0）通过烃的装置具有由不饱和单腈向二腈，通过萃取的氢氰化反应流出物的磷配位体配合物，所述烃和含腈溶液的相分离成两相是由氢氰化进行 放电（进料流）和/或提取阶段被提供至少一种极性添加剂。

公开(公告)号：WO2005042157A3

公开(公告)日：2005-07-21

申请号：PCT/EP2004012180

申请日：2004-10-28

Applicant: BASF AG ,  HADERLEIN GERD ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG

Inventor： HADERLEIN GERD ,  BAUMANN ROBERT ,  BARTSCH MICHAEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG

IPC: B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C255/04 ,  C07F15/04 ,  B01J37/16 ,  B01J31/30

CPC classification number: C07F15/045 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/1875 ,  B01J31/24 ,  B01J2231/323 ,  B01J2231/52 ,  B01J2531/847 ,  C07C253/10 ,  C07F15/04 ,  C07C255/04

Abstract: The invention relates to a method for the production of nickel(0)-phosphorous ligand complexes from nickel(II)-ether adducts.

Abstract translation: 本发明是从镍（II）醚加合物开始制备镍（0）磷配体配合物的方法。

公开(公告)号：WO0213964A2

公开(公告)日：2002-02-21

申请号：PCT/EP0108522

申请日：2001-07-24

Applicant: BASF AG ,  BARTSCH MICHAEL ,  KUNSMANN KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  SIEGEL WOLFGANG

Inventor： BARTSCH MICHAEL ,  KUNSMANN-KEITEL DAGMAR PASCALE ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  SIEGEL WOLFGANG

IPC: B01J31/18 ,  B01J31/28 ,  C07F9/145 ,  C07F9/46 ,  C07F9/48 ,  C07F9/6574 ,  C07F15/04 ,  C07C253/10

CPC classification number: C07F15/045 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/28 ,  B01J2231/323 ,  B01J2231/52 ,  B01J2531/847 ,  C07F9/145 ,  C07F9/46 ,  C07F9/4875 ,  C07F9/65746

Abstract: The invention relates to a catalyst containing a nickel complex (0) with ligands of formula (I) Y - E - X - E - Y wherein X represents arylene or heteroarylene, E , E independently represent O or NZ . Y , Y can be the same or different and independently represent a radical of formula (II.1) or (II.2), -P(-E -R )(-E -R ) wherein E 3, E , E , E can be the same or different and independently represent a chemical bond or independently represent O or NZ . R , R can be the same or different and independently represent a cycloalkyl, aryl, heterocycloalkyl or heteroaryl group. R together with part of the system -E -P-E -,to which it is bonded, represents a 5-, 6-, 7- or 8-membered heterocycle.

Abstract translation: 包含镍（0）配合物与式（I）的配体的催化剂：Y <1> - 电子<1> - X - 电子<2> - ý<2>，其中X是亚芳基或亚杂芳基，E < 1>，E <2>彼此5>独立地是O或NZ <，Y <1>，Y <2>可以相同或unterschliedlich是和各自独立地为式基团（II.1）的： - P（ - ë<3> -R <1>）（ - 电子<4> -R <2>中提供（II.2）），或者其中，e <3>，E <4>中，E <5>电子<6> 可以相同或不同，并且可以是一个化学键或彼此独立地独立地为O或NZ <11>，R <1>，R <2>可以相同或不同，且独立地表示环烷基，芳基，杂环烷基 - 或杂芳基，R <3>与所述系统的所述部分一起-E <5> -PE <6> - 其所键合的，代表一个5-，6-，7-或8-元杂环。