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公开(公告)号:DE3260156D1
公开(公告)日:1984-06-20
申请号:DE3260156
申请日:1982-02-17
Applicant: BASF AG
Inventor: HARTMANN HORST , HOCHSTEIN WALDHELM DR , KAIBEL GERD , MUELLER FRANZ-JOSEF DR
IPC: C07C69/14 , C07C27/00 , C07C27/26 , C07C27/34 , C07C45/00 , C07C45/49 , C07C45/80 , C07C47/06 , C07C47/09 , C07C51/00 , C07C51/12 , C07C51/48 , C07C51/56 , C07C51/573 , C07C53/08 , C07C53/12 , C07C67/00 , C07C67/58
Abstract: 1. A process for separating organic iodine compounds from carbonylation products of methanol, methyl acetate and dimethyl ether or from mixtures of such carbonylation products, wherein the iodine compounds are removed by liquid phase extraction with a non-aromatic hydrocarbon.
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公开(公告)号:DE3160936D1
公开(公告)日:1983-10-27
申请号:DE3160936
申请日:1981-05-04
Applicant: BASF AG
Inventor: HOCHSTEIN WALDHELM DR , KAIBEL GERD , MULLER FRANZ-JOSEF DR , HARTMANN HORST
IPC: A01N31/04 , C07C27/00 , C07C27/26 , C07C27/32 , C07C29/80 , C07C29/88 , C07C31/04 , C07C45/00 , C07C45/49 , C07C45/82 , C07C45/85 , C07C47/06 , C07C47/09 , C07C67/00 , C07C69/14
Abstract: A process is provided wherein acetaldehyde and methanol are obtained from reaction mixtures which result from the homologization of methanol and which in addition to acetaldehyde essentially contain acetaldehyde dimethylacetal, methanol, methyl acetate and water.
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公开(公告)号:DE3160558D1
公开(公告)日:1983-08-11
申请号:DE3160558
申请日:1981-05-06
Applicant: BASF AG
Inventor: KAIBEL GERD , HARTMANN HORST , HOCHSTEIN WALDHELM DR , MUELLER FRANZ-JOSEF DR
IPC: B01D3/36 , C07C7/05 , C07C9/15 , C07C27/00 , C07C29/80 , C07C29/84 , C07C31/02 , C07C31/04 , C07C31/08 , C07C67/00 , C07C67/54 , C07C69/14
Abstract: Liquid mixtures containing aliphatic alcohols are separated, by distillation, into a higher-boiling alcohol-containing fraction and a lower-boiling fraction containing the other liquids, by carrying out the fractionation in the presence of water and of an alkanal and, over about 3/4 of the column height, in the presence of a non-volatile or only slightly volatile acid.
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公开(公告)号:DE3464482D1
公开(公告)日:1987-08-06
申请号:DE3464482
申请日:1984-06-25
Applicant: BASF AG
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公开(公告)号:DE3161560D1
公开(公告)日:1984-01-05
申请号:DE3161560
申请日:1981-10-12
Applicant: BASF AG
Inventor: HARTMANN HORST , HOCHSTEIN WALDHELM DR , KAIBEL GERD , MUELLER FRANZ-JOSEF DR
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公开(公告)号:AT70542T
公开(公告)日:1992-01-15
申请号:AT86103107
申请日:1986-03-08
Applicant: BASF AG
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公开(公告)号:DE3336355A1
公开(公告)日:1985-04-18
申请号:DE3336355
申请日:1983-10-06
Applicant: BASF AG
IPC: C08F6/00 , C08F4/12 , C08F4/14 , C08F6/06 , C08F8/00 , C08F10/00 , C08F10/10 , C08F210/10 , C08F6/28 , C08F8/46
Abstract: The processing properties of isobutene polymers when reacted with maleic anhydride are improved by a method in which these polymers are brought into contact, for an effective period, with aluminum oxide and/or a completely or partially hydrated aluminum oxide at 50 DEG -280 DEG C., and/or with boron oxide and/or a completely or partially hydrated boron oxide and/or with titanium dioxide and/or a partially hydrated titanium dioxide and/or with a completely or partially hydrated silicon dioxide at 0 DEG -280 DEG C.
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公开(公告)号:DE3323021A1
公开(公告)日:1985-01-03
申请号:DE3323021
申请日:1983-06-25
Applicant: BASF AG
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公开(公告)号:DE3161250D1
公开(公告)日:1983-11-24
申请号:DE3161250
申请日:1981-10-12
Applicant: BASF AG
Inventor: HARTMANN HORST , HOCHSTEIN WALDHELM DR , KAIBEL GERD , MUELLER FRANZ-JOSEF DR
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公开(公告)号:DE3682923D1
公开(公告)日:1992-01-30
申请号:DE3682923
申请日:1986-03-08
Applicant: BASF AG
Inventor: BRONSTERT KLAUS DR , HOCHSTEIN WALDHELM DR , MOHR HEINRICH DR , SANDROCK GERHARD DR , VOGEL HANS-HENNING DR , RATH HANS PETER DR
Abstract: Isobutylene homo- and copolymers with olefinically unsatd. monomers are produced by polymsn. in liq. phase in a polymsn. zone at a pressure of 0.2-20 bar and at -130 to 60 deg.C, in the presence of (i) 0.01-20m Mole (on monomer) of a boron halide catalyst; (ii) a cocatalyst and opt. a polymsn. accelerator in a molar ratio of 0.5 boron halide:200 cocatalyst and opt. polymerisation accelerator; (iii) 0-90 wt.% inert solvent, and removing heat of polymsn. by cooling. The new feature is the use of a carboxylic acid anhydride or halide as the cocatalyst. Pref. the cocatalyst is a 4-18C aliphatic or aromatic opt. halogen substd. anhydride or a 2-12C carbonyl halide. Esp. trifluoroacetic, trichloroacetic, benzoic, phthalic, succinic, pivalic, maleic or (meth)acrylic anhydrides; acetyl fluoride, acetyl chloride, acetyl bromide, benzoyl chloride pivaloyl chloride or acryloyl chloride are claimed as co-catalyst.
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