公开(公告)号：DE59002050D1

公开(公告)日：1993-09-02

申请号：DE59002050

申请日：1990-01-30

Applicant: BASF AG

Inventor： WEYER HANS-JUERGEN DR ,  FISCHER ROLF DR ,  MUELLER FRANZ-JOSEF DR ,  ZIMMERMANN HORST DR

IPC: B01J27/187 ,  C07B61/00 ,  C07C29/136 ,  C07C29/149 ,  C07C29/56 ,  C07C31/20 ,  C07C31/22 ,  C07C41/26 ,  C07C43/13

公开(公告)号：DE3427138A1

公开(公告)日：1986-02-06

申请号：DE3427138

申请日：1984-07-24

Applicant: BASF AG

Inventor： BERTLEFF WERNER DR ,  MUELLER FRANZ-JOSEF DR ,  KUMMER RUDOLF DR ,  HARDER WOLFGANG DR

IPC: C07C27/06 ,  B01J23/00 ,  B01J23/89 ,  C07B61/00 ,  C07C27/00 ,  C07C29/15 ,  C07C29/158 ,  C07C31/20 ,  C07C67/00

Abstract: Ethylene glycol is prepared from carbon monoxide and hydrogen under superatmospheric pressure and at an elevated temperature in the presence of a rhodium-containing catalyst together with a cobalt catalyst, the molar ratio of rhodium to cobalt being from about 20:1 to 60:1.

公开(公告)号：DE3260156D1

公开(公告)日：1984-06-20

申请号：DE3260156

申请日：1982-02-17

Applicant: BASF AG

Inventor： HARTMANN HORST ,  HOCHSTEIN WALDHELM DR ,  KAIBEL GERD ,  MUELLER FRANZ-JOSEF DR

IPC: C07C69/14 ,  C07C27/00 ,  C07C27/26 ,  C07C27/34 ,  C07C45/00 ,  C07C45/49 ,  C07C45/80 ,  C07C47/06 ,  C07C47/09 ,  C07C51/00 ,  C07C51/12 ,  C07C51/48 ,  C07C51/56 ,  C07C51/573 ,  C07C53/08 ,  C07C53/12 ,  C07C67/00 ,  C07C67/58

Abstract: 1. A process for separating organic iodine compounds from carbonylation products of methanol, methyl acetate and dimethyl ether or from mixtures of such carbonylation products, wherein the iodine compounds are removed by liquid phase extraction with a non-aromatic hydrocarbon.

公开(公告)号：DE3160558D1

公开(公告)日：1983-08-11

申请号：DE3160558

申请日：1981-05-06

Applicant: BASF AG

Inventor： KAIBEL GERD ,  HARTMANN HORST ,  HOCHSTEIN WALDHELM DR ,  MUELLER FRANZ-JOSEF DR

IPC: B01D3/36 ,  C07C7/05 ,  C07C9/15 ,  C07C27/00 ,  C07C29/80 ,  C07C29/84 ,  C07C31/02 ,  C07C31/04 ,  C07C31/08 ,  C07C67/00 ,  C07C67/54 ,  C07C69/14

Abstract: Liquid mixtures containing aliphatic alcohols are separated, by distillation, into a higher-boiling alcohol-containing fraction and a lower-boiling fraction containing the other liquids, by carrying out the fractionation in the presence of water and of an alkanal and, over about 3/4 of the column height, in the presence of a non-volatile or only slightly volatile acid.

公开(公告)号：DE3926709A1

公开(公告)日：1991-02-14

申请号：DE3926709

申请日：1989-08-12

Applicant: BASF AG

Inventor： JOERG KLAUS DR ,  MUELLER FRANZ-JOSEF DR ,  HARDER WOLFGANG DR ,  KUMMER RUDOLF DR

IPC: B01J27/122 ,  B01J31/02 ,  C07B61/00 ,  C07C68/00 ,  C07C69/96

Abstract: A process for the continuous synthesis of dialkyl carbonates of the general formula I (I) in which R denotes C1-C4-alkyl, by reaction of C1-C4-alkanols with carbon monoxide and oxygen at elevated temperature and pressure and in the presence of a copper-containing catalyst dissolved or suspended in the reaction medium, wherein a) a gas stream containing carbon monoxide and oxygen is bubbled through the alkanol/catalyst mixture present in the reactor at a rate of from 1 to 100 liters per hours per gram of copper present in the reactor, part of which gas stream reacts with the alkanol to form dialkyl carbonate and water, which components are continuously entrained, together with alkanol, as a gaseous mixture, from the reaction mixture by means of the remaining, unreacted portion of the carbon monoxide/oxygen gas stream, whereupon b) the resulting gaseous mixture is separated, in a separator, into gaseous and liquid phases, the gaseous phase being recycled to the reactor if desired, and c) the liquid phase, which essentially consists of dialkyl carbonate, water and alkanol, is separated into its components, the dialkyl carbonate being isolated and the alkanol, if desired, recycled to the reactor, and d) the liquid in the reactor is replenished by adding fresh or recycled alkanol at the rate at which the alkanol is consumed and discharged.

公开(公告)号：DE3560079D1

公开(公告)日：1987-04-09

申请号：DE3560079

申请日：1985-07-16

Applicant: BASF AG

Inventor： BERTLEFF WERNER DR ,  MUELLER FRANZ-JOSEF DR ,  KUMMER RUDOLF DR ,  HARDER WOLFGANG DR

IPC: C07C27/06 ,  B01J23/00 ,  B01J23/89 ,  C07B61/00 ,  C07C27/00 ,  C07C29/15 ,  C07C29/158 ,  C07C31/20 ,  C07C67/00

Abstract: Ethylene glycol is prepared from carbon monoxide and hydrogen under superatmospheric pressure and at an elevated temperature in the presence of a rhodium-containing catalyst together with a cobalt catalyst, the molar ratio of rhodium to cobalt being from about 20:1 to 60:1.

公开(公告)号：DE3323654A1

公开(公告)日：1985-01-03

申请号：DE3323654

申请日：1983-07-01

Applicant: BASF AG

Inventor： MUELLER FRANZ-JOSEF DR ,  MATT DOMINIQUE DR

IPC: C07C51/12 ,  C07C53/08 ,  C07C67/36 ,  C07C69/14 ,  B01J23/89 ,  B01J31/28

Abstract: 1. A process for the preparation of acetic and methyl acetate by gas-phase carbonylation of methanol in the presence of a nickel-containing catalyst and in the presence of chlorine, bromine or iodine or a volatile compound of one of these halogens as promoter, wherein the catalyst used is one whose active material consists of at least 40% by weight of nickel, and the catalyst contains from 0,001 to 1 part by weight of palladium per part by weight of nickel.

公开(公告)号：DE3221077A1

公开(公告)日：1983-12-08

申请号：DE3221077

申请日：1982-06-04

Applicant: BASF AG

Inventor： SCHUSTER LUDWIG DR ,  MUELLER FRANZ-JOSEF DR ,  ANDERLOHR AXEL DR ,  BLEI PETER ,  EIGENBERGER GERHART DR ,  HOEPPNER BERND DR ,  KAIBEL GERD ,  STEINER WOLFGANG DR

IPC: C07C29/136 ,  C07C29/149 ,  C07C31/08

Abstract: Ethanol is prepared by hydrogenating acetic acid under superatmospheric pressure and at elevated temperatures by a process wherein a predominantly cobalt-containing catalyst is used and acetic acid and hydrogen are passed through the reactor, at from 210 DEG to 330 DEG C. and under from 10 to 350 bar, under conditions such that a liquid phase in not formed during this procedure.

公开(公告)号：DE2142105A1

公开(公告)日：1973-03-01

申请号：DE2142105

申请日：1971-08-23

Applicant: BASF AG

Inventor： BARZYNSKI HELMUT DR ,  MUELLER FRANZ-JOSEF DR ,  JUN MONG-JON DR ,  VELIC MILAN DR

IPC: C08F2/50 ,  G03F7/029 ,  C08F1/20

Abstract: The polymsn of the unsatd, cpds (e.g. vinyl cpds) is effected in the presence of coloured transition metal carbonyls as photoinitiators and polyhalo-org cpds as co-catalysts. Prefd carbonyl is biscylcopentadienyl iron dicarbonyl and co-catalyst is 7 5-dichloro-1,4-bis-dichloromethyl benzene.

公开(公告)号：DE59006008D1

公开(公告)日：1994-07-14

申请号：DE59006008

申请日：1990-08-03

Applicant: BASF AG

Inventor： JOERG KLAUS DR ,  KUMMER RUDOLF DR ,  MUELLER FRANZ-JOSEF DR

IPC: B01J27/122 ,  B01J31/02 ,  C07B61/00 ,  C07C68/00 ,  C07C69/96

Abstract: Process for the preparation of dialkyl carbonates of the general formula I in which R represents a C1- to C10-alkyl group, by reacting the alcohols R OH with a gaseous carbon monoxide/oxygen mixture in the presence of a copper catalyst and of a cosolvent, at increased temperature and under increased pressure, in which the cosolvent used is a cyclic urea of the general formula II in which n is the number 2, 3 or 4 and R represents hydrogen or a C1- to C4-alkyl group.