Abstract:
The invention relates to a method for the production of an ionic compound, comprising at least one cation with a quaternary sp -hybridised nitrogen atom, whereby a compound with a double-bonded nitrogen atom is reacted with a dialkyl sulphate, using both alkyl groups of the dialkyl sulphate and the ionic compound thus obtained with sulphate anions is optionally subjected to an ion-exchange.
Abstract:
The inventive method for producing quaternary ammonium compounds consists in reacting compounds containing an sp 3 hybridised nitrogen atom with dialkyl sulphate or trialkyl phosphate and in exposing the thus obtained ammonium compound to an ion-exchange.
Abstract:
The invention relates to a method for the extraction of phenols, alcohols, amines, phosphines, hydroxylamines, hydrazines, oximes, imines, water, carboxylic acids, amino acids, hydroxamic acids, sulphinic acids, sulphonic acids, peroxycarboxylic acids, phosphonous acids, phosphinous acids, phosphonic acids, phosphinic acids or phosphoric acids from aprotic solvents with the aid of ionic liquids of the formula [K]n +[A] , where n, [K] and A are defined as cited in the description.
Abstract translation:本发明涉及一种用于萃取除去酚的方法,醇,胺,Phoshinen,羟胺,肼,肟,亚胺,水,羧酸,氨基酸,异羟肟酸,亚磺酸,磺酸,过氧酸,亚膦酸,三价膦酸,膦酸,次膦酸或磷酸 apotischen溶剂由下式的离子液体的手段[K] N + [A] - ,其中n,[K]被定义<+>和如说明书中列出的A 。
Abstract:
The invention relates to a method for producing acylphosphine oxide solids consisting in transforming a molten or dispersed acylphosphine oxide into the solid aggregated state thereof by means of mechanical stress, shear force or the internal motion of the melt.
Abstract:
The invention relates to a method for producing N-phosphonomethyl iminodiacetic acid by reacting an alkali metal salt of iminodiacetic acid with phosphorus trichloride in an aqueous solution, forming iminodiacetic acid hydrochloride, phosphoric acid and corresponding alkali metal chloride. A reaction then takes place with a formaldehyde source and the N-phosphonomethyl iminodiacetic acid desired is obtained from the reaction mixture. During and/or after the reaction of the alkali metal salt of the iminodiacetic acid with phosphorus trichloride, water, optionally containing HCl, is removed from the reaction mixture until there is a concentration of iminodiacetic acid hydrochloride of at least 40 wt. %, in relation to the weight of the reaction mixture minus the weight of the alkali metal chloride. The inventive method enables N-phosphonomethyl iminodiacetic acid to be produced simply and in large quantities.
Abstract:
The invention relates to a solution containing cellulose and an ionic liquid containing anions and cations as a solvent, the cations being provided with at least one atom selected among the group comprising nitrogen, oxygen, sulfur, and phosphorus supplied in a protonated form. Also disclosed are methods for the production and use thereof for a physical and chemical treatment.
Abstract:
The invention relates to a solution comprising cellulose, an ionic liquid containing anions and cations as solvent and 6 to 30 wt. % of a nitrogenous base, based on the total weight of the solution, the production thereof and the use thereof for the physical or chemical treatment of cellulose.
Abstract:
The invention relates to a method for producing diphenylphosphine oxide (DPPO) or its nucleus-substituted derivatives, diphenylphosphine (DPP) or its nucleus-substituted derivatives or phosphine (PP) or its nucleus-substituted derivatives, starting from triphenylphosphine oxide (TPPO) or the corresponding nucleus-substituted derivatives, or in the case of the production of DPP and PP, starting from triphenylphosphine (TPP) or the corresponding nucleus-substituted derivatives or DPPO. According to said method, the starting products are reduced electrochemically in the presence of ammonia or an amine.
Abstract:
The invention relates to the acyl- and bisacylphosphine derivatives according to formula (I), wherein Y represents O, S, NR3, N-OR3 or N-NR3R4, Z represents O, S, NR3, N-OR3, N-NR3R4 or a free pair of electrons, and FG represents a leaving group and the remaining groups are defined as in the description. The invention further relates to a method for the production of the inventive derivatives and to their use.
Abstract translation:根据式I,其中Y是酰基和二酰基膦衍生物O,S,NR 3,N-OR 3或N-NR 3 R 4,Z是O,S,NR 3,N-NR 3 R 4,或自由电子对,和FG是指离去基团,并且其它基团如在所描述的 刚才提到的含义,其制备方法及其用途。