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公开(公告)号:CA2648225A1
公开(公告)日:2007-10-25
申请号:CA2648225
申请日:2007-04-18
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , MUELLER ULRICH , MARX STEFAN
Abstract: The invention relates to methods for producing a porous metal-organic framework material which contains at least one at least bidentate compound that is coordinately bound to at least one metal ion. Said method comprises the step of reacting at least one metal compound with at least one at least bidentate organic compound which is capable of coordinately binding to the metal. The metal ion of the at least one metal compound is selected from the group of metals including titanium, zirconium, and hafnium. The at least bidentate compound is derived from a di-, tri- or tetracarboxylic acid and t he metal compound is an inorganic salt.
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公开(公告)号:CA2648222A1
公开(公告)日:2007-10-25
申请号:CA2648222
申请日:2007-04-17
Applicant: BASF AG
Inventor: MARX STEFAN , MUELLER ULRICH , SCHUBERT MARKUS
Abstract: The invention relates to a porous metal-organic framework material, containi ng at least one organic bidentate compound that is coordinately bound to at lea st one metal ion, the at least one metal ion being zirconium and the at least o ne at least bidentate organic compound being derived from a di-, tri- or tetracarboxylic acid. The invention also relates to methods for producing sa id materials and to the use thereof.
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公开(公告)号:CA2630035A1
公开(公告)日:2007-05-24
申请号:CA2630035
申请日:2006-11-14
Applicant: BASF AG
Inventor: SENK RAINER , MARX STEFAN , MUELLER ULRICH , SCHUBERT MARKUS
Abstract: The present invention relates to processes for preparing a porous organometallic framework material, comprising the step of reacting at least one metal compound with at least one at least bidentate organic compound which can bond coordinatively to the metal, in the presence of a non-aqueous organic solvent, the metal being ScIII, YIII or a trivalent lanthanide, and the organic compound having at least two atoms each selected independently from the group consisting of oxygen, sulphur and nitrogen, and via which the organic compound can bond coordinatively to the metal, the reaction taking place with stirring and at a pressure of not more than 2 bar (absolute). The invention further relates to porous organometallic framework materials which have been prepared by this process, and also to their use.
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公开(公告)号:CA2666481A1
公开(公告)日:2008-05-08
申请号:CA2666481
申请日:2007-10-24
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , MUELLER ULRICH , MARX STEFAN , KIENER CHRISTOPH , KRENNRICH GERHARD , BROWN JAMES REUBEN
Abstract: The present invention relates to a porous organometallic framework materi al comprising a bidentate organic compound bound coordinatively to a metal i on, where the metal ion is Al3+ and the bidentate compound is 2,6-naphthalen edicarboxylate. The invention further relates to moldings comprising such a framework material, to processes for producing the framework material and to the use of the framework material or of the proposed molding.
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公开(公告)号:DE102005054636A1
公开(公告)日:2007-05-24
申请号:DE102005054636
申请日:2005-11-16
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , MUELLER ULRICH , MARX STEFAN , SENK RAINER
Abstract: The present invention relates to a process for preparing a porous metal organic framework, which comprises the step: Reaction of at least one metal compound with at least one at least bidentate organic compound which can coordinate to the metal, where the metal is ScIII, YIII or a trivalent lanthanide and the organic compound has at least two atoms which are selected independently from the group consisting of oxygen, sulfur and nitrogen and via which the organic compound can coordinate to the metal, in the presence of a nonaqueous organic solvent, with the reaction being carried out with stirring and at a pressure of not more than 2 bar (absolute). The invention further relates to porous metal organic frameworks which have been prepared by this process and their use.
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