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    HERBICIDES CONTAINING 3-AMINOBENZO(B)THIOPHENES AS AN ANTIDOTE
    1.
    发明申请
    HERBICIDES CONTAINING 3-AMINOBENZO(B)THIOPHENES AS AN ANTIDOTE 审中-公开
    含有3-氨基苯并（B）噻吩作为抗凝血剂的除草剂

    公开(公告)号：WO9304057A3

    公开(公告)日：1993-07-22

    申请号：PCT/EP9201798

    申请日：1992-08-07

    Applicant: BASF AG

    Inventor： HAGEN HELMUT ,  NILZ GERHARD ,  ROETSCH THOMAS ,  WALTER HELMUT ,  LANDES ANDREAS

    IPC: A01N25/32 ,  A01N31/06 ,  A01N31/16 ,  A01N43/40 ,  A01N43/54 ,  A01N43/72 ,  A01N43/76 ,  C07D207/335 ,  C07D213/53 ,  C07D231/12 ,  C07D261/08 ,  C07D275/04 ,  C07D309/06 ,  C07D309/08 ,  C07D319/06 ,  C07D333/22 ,  C07D333/66 ,  C07D333/68 ,  C07D333/70 ,  C07D335/02 ,  C07D405/12 ,  C07D407/12 ,  C07D409/12 ,  C07D411/12 ,  C07D417/04 ,  C07D275/02

    CPC classification number: A01N25/32 ,  C07D333/66 ,  C07D333/68

    Abstract: Disclosed are herbicides containing at least one 3-aminobenzo[b]thiophene (I) with an antagonistic action (in which R1 = -COX or -COOX; X = H, halogen, optionally substituted amino, optionally substituted C¿1?-C10 alkyl, optionally sustituted C1-C8 alkenyl, optionally substituted C3-C10 cycloalkyl, optionally substituted C3-C10 cycloalkenyl, a 5/6-membered heterocyclic aromatic, optionally substituted phenyl or optionally substituted naphthyl; R?2 and R3¿ = H, CN, NO¿2?, SH, halogen, optionally substituted amino, optionally substituted C1-C10 alkyl, optionally substituted C1-C6 alkoxy, optionally substituted C2-C8 alkenyl, optionally substituted C3-C10 cycloalkyl, optionally substituted C3-C10 cycloalkenyl, optionally substituted phenyl, optionally substituted naphthyl or a 5/6-membered heterocyclic aromatic; R?4 to R7¿ = H, optionally substituted C¿1?-C10 alkyl, optionally substituted C2-C8 alkenyl, optionally substituted C3-C10 cycloalkyl, optionally substituted C3-C10 cycloalkenyl, an optionally substituted 5/6-membered heterocyclic aromatic, optionally substituted phenyl or optionally substituted naphthyl or R?4 + R5¿ and/or R6 + R7 form, together with the N-atom to which they are bound, a 5- to 7-membered ring), plus the basic salts of those compounds of formula (I) which carry at least one carboxyl, hydroxythiocarbonyl or sulphonic acid group and the acid salts of those compounds of formula (I) which contain a basic nitrogen atom, and at least one herbicidal substance selected (A) from the group comprising the cyclohexenone derivatives or (B) from the group comprising the 4-(hetero)aryloxyphenoxyacetic acid derivatives.

    Abstract translation: 公开了含有至少一种具有拮抗作用的3-氨基苯并[b]噻吩（I）的除草剂（其中R1 = -COX或-COOX; X = H，卤素，任选取代的氨基，任选取代的取代基; 1'-C10 烷基，任选取代的C 1 -C 8烯基，任选取代的C 3 -C 10环烷基，任选取代的C 3 -C 10环烯基，5/6元杂环芳族，任选取代的苯基或任选取代的萘基; R 2和R 3' NO 2，SH，卤素，任选取代的氨基，任选取代的C 1 -C 10烷基，任选取代的C 1 -C 6烷氧基，任选取代的C 2 -C 8烯基，任选取代的C 3 -C 10环烷基， 任选取代的苯基，任选取代的萘基或5元/ 6元杂环芳基; R 4至R 7任选; = H，任选取代的C 1 -C 10烷基;任选取代的C 2 -C 8烯基;任选取代的C 3 -C 10环烷基; 取代的C 3 -C 10环烯基，任选取代的5/6元杂环芳族，任选取代的苯基或任选取代的萘基或R 4'+ R 5' 和/或R 6 + R 7与它们所连接的N原子一起形成5至7元环），加上那些带有至少一个羧基的羟基硫代羰基的式（I）化合物的碱性盐 或磺酸基团和含有碱性氮原子的那些式（I）化合物的酸式盐，和至少一种选自（A）选自（A）包含环己烯酮衍生物或（B）选自下组的化合物的除草剂物质 - （杂）芳氧基苯氧乙酸衍生物。

    HERBICIDES CONTAINING SUBSTITUTED 2-AMINOTHIOPHENES
    4.
    发明专利
    HERBICIDES CONTAINING SUBSTITUTED 2-AMINOTHIOPHENES 未知

    公开(公告)号：CA2098016A1

    公开(公告)日：1992-06-14

    申请号：CA2098016

    申请日：1991-12-03

    Applicant: BASF AG

    Inventor： HAGEN HELMUT ,  NILZ GERHARD ,  WALTER HELMUT ,  LANDES ANDREAS

    IPC: A01N25/32 ,  A01N35/06 ,  A01N39/02 ,  A01N43/10 ,  C07D333/26 ,  C07D333/38 ,  C07D333/62 ,  C07D333/68 ,  C07D333/70 ,  C07D409/04 ,  C07D409/12 ,  C07D417/12 ,  A01N43/18

    Abstract: 2098016 9210094 PCTABS00013 Herbicidal agents contain as antagonistic compound at least one substituted 2-aminothiophene having formula (I), in which R1, R2 stand for H, CN, alkyl, halogen alkyl, if necessary substituted phenyl, CO-R6 or R1 + R2 stand for a C3-C6 alkylene chain, upon which a benzene ring, if necessary substituted, may be annulated, a C2-C3 alkylene chain broken by -O- or -N(R7)-, which may also carry 1-4 alkenyl residues or a group CO-N(R7)-CO; R3 stands for CN, if necessary substituted -C(NH2)=N-C6H5, -C(NH3+Hal-)=N-C6H5, CX-R6; Hal stands for halogen; R4 stands for H, alkyl, alkenyl, if necessary substituted phenyl, if necessary substituted triazin, -PX(OR8)2, -CX-R9, -SO2R10, -SO2-NHR10, -CX-N(R7)-CY-R8, -CX-N(R7)-SO2-R11 or R3=R4 stand for CO-O-CO; R5 stands for H, alkyl, -CX-R9, -SO2-R10; X, Y stand for O, S; R7 stands for H, phenyl, alkyl; R8 stands for H, alkyl, if necessary substituted phenyl; R9 stands for alkyl, halogen alkyl, alkenyl, halogen alkenyl, if necessary substituted cycloalkyl or cycloalkenyl, NH2, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted phenyl or phenylamino; R10 stands for alkyl, if necessary substituted phenyl; R11 stands for NH2, alkylamino, dialkylamino, if necessary substituted pyrrolidinyl, piperidinyl, morpholinyl, piperazinyl; R4 + R5 stand for =CR12R13 or -CO-W-CO-; R12 stands for H, NH2, alkylamino, cycloalkylamino; R13 stands for NH2, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted thienylamino, pyrrolidinyl, piperidinyl, morpholinyl, if necessary substituted phenyl or pyridyl; W stands for an ethylene or ethenylene bridge, if necessary substituted, or for an aromatic or heteroaromatic 5/6 membered cycloalkylene or cycloalkenylene bridge, if necessary substituted. Also disclosed are a basic salt of compound (I), in which R3 stands for hydroxycarbonyl, hydroxythiocarbonyl, or an acid salt of compound (I) which contains a basic hydrogen atom, and at least one herbicidal active substance from (A) the group of 4-aryloxy- and 4-heteroaryloxy-phenoxyacetic acid derivates or from (B) the group of cyclohexan-1,3-dione derivates.

    7.
    发明专利
    未知

    公开(公告)号：DE59104913D1

    公开(公告)日：1995-04-13

    申请号：DE59104913

    申请日：1991-11-29

    Applicant: BASF AG

    Inventor： HAGEN HELMUT ,  NILZ GERHARD ,  WALTER HELMUT ,  LANDES ANDREAS

    IPC: A01N25/32 ,  A01N43/40 ,  C07D491/04 ,  C07D491/052

    Abstract: Pyrido-fused 4-oxo-4H-benzopyrans I I (m=0, 1 or 2; R1, R6 and R7 have the meanings stated in the description) and the salts of I, and herbicides which contain 2-(4-hetaryloxy)- and 2-(4-aryloxy)-phenoxyacetic acid derivatives or cyclohexenone derivatives as herbicidal active ingredients and pyrido-fused 4-oxo-4H-benzopyrans I' as antidotes.

    HERBICIDAL PREPARATIVES CONTAINING SUBSTITUTED 5-AMINO-PYRAZOLES AS ACTIVE SUBSTANCE AND METHOD FOR PRODUCING SAID COMPOUNDS
    9.
    发明专利
    HERBICIDAL PREPARATIVES CONTAINING SUBSTITUTED 5-AMINO-PYRAZOLES AS ACTIVE SUBSTANCE AND METHOD FOR PRODUCING SAID COMPOUNDS 未知

    公开(公告)号：HU9301720D0

    公开(公告)日：1993-09-28

    申请号：HU172093

    申请日：1991-12-03

    Applicant: BASF AG

    Inventor： HAGEN HELMUT ,  NILZ GERHARD ,  WALTER HELMUT ,  LANDES ANDREAS

    IPC: A01N43/56 ,  A01N25/32 ,  C07D231/38 ,  C07D231/40 ,  C07D309/12 ,  C07D335/02 ,  C07D403/04

    Abstract: PCT No. PCT/EP91/02286 Sec. 371 Date Jun. 7, 1993 Sec. 102(e) Date Jun. 7, 1993 PCT Filed Dec. 3, 1991 PCT Pub. No. WO92/10480 PCT Pub. Date Jun. 25, 1992.Substituted 5-aminopyrazoles I I where R1 is C1-C8-alkyl, C1-C8-hydroxyalkyl, phenyl which may carry 1-3 of the following radicals: halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or -NR6R7, and which may additionally carry a number of halogen atoms so that the total number of radicals is 5, R6 and R7 are each H or C1-C4-alkyl, R2 is H, C1-C4-alkyl or C1-C4-haloalkyl, R3 is CN, -CO-R8 or -CS-R8, R8 is OH, C1-C4-alkoxy, NH2, C1-C4-alkylamino or di-C1-C4-alkylamino, R4 and R5 are each H, C1-C4-alkyl, PX(OR9)2, -SO2-R9, -CX-R10, -CX-NH-CY-R9 or CX-NH-SO2-R11, X and Y are each O or S, R9 is one of the substituents R1, R10 is C1-C20-alkyl, C1-C4-alkoxy, unsubstituted or substituted phenyl or unsubstituted or substituted NH2, R11 is NH2, C1-C4-alkylamino, di-C1-C4-alkylamino, pyrrolidinyl, piperidinyl or morpholinyl, R4 and R5 together form a group =CR12R13 or -CO-W-CO-, R12 is H, NH2, C1-C4-alkylamino or C3-C8-cycloalkylamino, R13 is NH2, C1-C4-alkylamino, di-C1-C4-alkylamino, C3-C8-cycloalkylamino, pyrrolidin-1-yl, piperidin-1-yl, morpholin-4-yl, unsubstituted or substituted phenyl or unsubstituted or substituted pyridyl and W is an unsubstituted or substituted ethylene or ethenylene bridge, an unsubstituted or substituted 5-membered or 6-membered 1,2-C-bonded aromatic or heteroaromatic bridge, or an unsubstituted or substituted 5-membered or 6-membered 1,2-C-bonded cycloalkylene or cycloalkenylene bridge, and the basic salts of the compounds I in which R3 is hydroxycarbonyl or hydroxythiocarbonyl, and the acidic salts of the compounds I which contain a basic nitrogen atom, with the exception of 1-phenyl- and 1-methyl-4-cyano-5-acylaminopyrazole, 1-methyl-4-cyano-5-(chloromethylcarbonylamino)-pyrazole, 1-methyl-4-cyano-5-(phenylcarbonylamino)-pyrazole, 1-methyl-4-cyano-5-(p-chlorophenylcarbonylamino)-pyrazole and the compounds I in which R1 is methyl, phenyl, 4-chlorophenyl or 4-nitrophenyl, R2 is hydrogen, methyl or trifluoromethyl, R3 is cyano and R4 and R5 are simultaneously hydrogen, and herbicides which contain 2-(4-hetaryloxy)- and 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives and/or cyclohexenone derivatives as herbicidal active ingredients and substituted 5-aminopyrazoles I' or, in the case of acidic terminal groups or basic nitrogen atoms, the salts of I' as antidotes.

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