Semi-continuous process for the production of 4,4'-dihydroxydiphenylsulfone comprises reaction of phenol with a sulfonating agent and suspension of the resulting crude product in water

    公开(公告)号:DE10018580A1

    公开(公告)日:2001-10-25

    申请号:DE10018580

    申请日:2000-04-14

    Applicant: BASF AG

    Abstract: A semi-continuous process for the production of 4,4'-dihydroxydiphenylsulfone comprises reaction of phenol with a sulfonating agent and suspension of the resulting crude product in water at weight ratio of crude product to water of 85:15-55:45 at least 40 deg C, filtering of the product and recycling of the resulting educt- and/or product containing waste stream to the production process. A semi-continuous process for the production of 4,4'-dihydroxydiphenylsulfone comprises: (A) reaction of phenol with a sulfonating agent, (B) suspension of the resulting crude product in water at least 40 deg C which is free of inert organic solvent and optionally contains residual amounts of unreacted phenol, and filtering of the product and (C) recycling of the resulting educt- and/or product containing waste stream to the production process. In step (B) the weight ratio of crude product to water is 85:15-55:45.

    7.
    发明专利
    未知

    公开(公告)号:DE59405587D1

    公开(公告)日:1998-05-07

    申请号:DE59405587

    申请日:1994-01-12

    Applicant: BASF AG

    Abstract: A process is disclosed for controlling undesirable plant growth and for regulating plant growth, by applying to the plants derivatives of azaanthraquinones and/or azaxanthones having formula (I), in which X, Y, Z and the residues R to R have the following meanings: R is hydrogen, methyl; R -R are (a) hydrogen, (b) halogen, (c) nitro, (d) COOR , in which R stands for C1-C4-alkyl, (e) CONH2 and CONR R , in which R and R stand for C1-C4-alkyl, (f) C1-C8-alkyl, which may bear one to three of the following substituents: halogen, hydroxy, C1-C6-alkoxy, (g) C3-C6-alkenyl, (h) C1-C4-alkoxy, (i) hydroxy, (j) amino or NR R , (k) phenyl, which may bear one to five halogen atoms or one to three of the following substituents: nitro, C1-C4-alkoxy, C1-C4-alkyl or C1-C4alkyl halide; X, Y are N, N -O or CH, with the proviso that only a nitrogen atom or a N-oxide group be contained in the ring; Z is oxygen, sulphur or a C = O group; A is oxygen or sulphur. Also disclosed are new azaanthraquinones and azaxanthones and herbicidal and bioregulatory agents containing the same.

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