公开(公告)号：DE2911467A1

公开(公告)日：1980-10-02

申请号：DE2911467

申请日：1979-03-23

Applicant: BASF AG

Inventor： HIMMELE WALTER DIPL CHEM DR ,  NAARMANN HERBERT DIPL CHEM DR ,  PENZIEN KLAUS DIPL CHEM DR ,  VIEHE HEINZ GUENTER PROF DIPL ,  BEAUJEAN MICHEL

IPC: C08K5/20 ,  C08L101/00 ,  C07C103/82 ,  C07C103/44 ,  C07C127/15 ,  D06M13/20

Abstract: N-Alkylamides of formula R-CO-NR1R2 (I) (where R is opt. substd. aryl, -NR1R2, -(CH2)n-CONR1R2, -CH=CH-CO-NR1R2; n is 1-4; x is 1-3; Y is 1-4 and R1 and R2 are opt. identical, linear or branched 1-4C alkyl) are dimerised and/or oligomerised by heating with organic peroxides at 130-200 degrees C in a protective gas atmos. The dimers and oligomers are new. The prods. can be used as high-boiling solvents and as oligomeric C-C labile synergetic cpds. for the flame-retarding and antistatic finishing of fibres and plastic foils. The prods. do not "sweat" out of plastics and have a high complex bonding capacity for metal salts.

公开(公告)号：DE2934131A1

公开(公告)日：1981-03-12

申请号：DE2934131

申请日：1979-08-23

Applicant: BASF AG

Inventor： NAARMANN HERBERT DIPL CHEM DR ,  ZDENEK JANONSEK DR ,  VIEHE HEINZ GUENTER PROF DIPL ,  BEAUJEAN MICHEL ,  MERENYI ROBERT DR

IPC: C07D207/06 ,  C07D207/09 ,  C07D207/26 ,  C07D207/27 ,  C07D207/32 ,  C07D207/323 ,  C07D209/08 ,  C07D211/12 ,  C07D211/14 ,  C07D213/69 ,  C07D241/04 ,  C07D265/30 ,  C07D277/04 ,  C07D295/02 ,  C07D295/067 ,  C07D295/096 ,  C07D295/185 ,  C07D453/02 ,  C08G61/12 ,  C09K3/16 ,  C07D227/02 ,  C07D247/00 ,  C07D277/02 ,  C07D295/00 ,  C08K5/34

公开(公告)号：DE2942645A1

公开(公告)日：1981-04-30

申请号：DE2942645

申请日：1979-10-22

Applicant: BASF AG

Inventor： NAARMANN HERBERT DIPL CHEM DR ,  JANONSEK JAN ,  VIEHE HEINZ GUENTER PROF DIPL ,  BEAUJEAN MICHEL ,  MERENYI ROBERT DIPL ING

IPC: C07F9/22 ,  C07F9/36 ,  C08K5/42 ,  C08K5/5399 ,  C07C143/78 ,  C08K5/53

Abstract: Dimerisation and/or aligomerisation of inorganic acid N-alkyl amides comprises heating cpds. of formula (I) (R)2P(:O)N(R1)(R2) or (II) R-X-N(R1)(R2) at 130-200 deg.C in the presence of an organic peroxide. R is aryl, alk(ar)yl or N(R1R2); where R1 is H or (m)ethyl and R2 is (m)ethyl. X is SO, SO2 or SeO. Reaction is conducted in an inert gas atmos. The new cpds. are useful as antistatic and flame retarding finishes for plastics and fibres.

公开(公告)号：DE2911466A1

公开(公告)日：1980-10-02

申请号：DE2911466

申请日：1979-03-23

Applicant: BASF AG

Inventor： NAARMANN HERBERT DIPL CHEM DR ,  VIEHE HEINZ GUENTER PROF DIPL ,  BEAUJEAN MICHEL

IPC: C07C41/30 ,  C07C43/11 ,  C07C43/225 ,  C08K5/06 ,  C08L101/00 ,  C07C41/00 ,  C07C43/205 ,  C07C49/84 ,  C08G65/34 ,  D06M13/18

Abstract: Me ethers having formula R-O-Me (I) or Me-O-R'-O-Me (II) (where R is satd. or unsatd., linear or branched aliphatic hydrocarbyl, cycloaliphatic or opt. substd. aromatic hydrocarbyl and R1 is linear or branched alkylene, alkylene oxide, cycloalkylene or arylene) are dimerised and/or oligomerised by heating with organic peroxides at 120-200 degrees C in a protective gas atmos. The Me ether dimers and oligomers are new. The prods. are used as high-boiling solvents and as oligomeric C-C-labile synergetic cpds. for the flame-protective and antistatic finishing of fibres and foils. The prods. do not "sweat" out of plastics and have high complex bonding capacity for metal salts.

公开(公告)号：DE2815250A1

公开(公告)日：1979-10-18

申请号：DE2815250

申请日：1978-04-08

Applicant: BASF AG

Inventor： NAARMANN HERBERT DIPL CHEM DR ,  WITTMER PAUL DIPL CHEM DR ,  STELLA LUCIEN DIPL CHEM DR ,  JANOUSEK ZDENEK DIPL CHEM DR ,  MERENYI ROBERT DIPL ING ,  VIEHE HEINZ GUENTER PROF DIPL

IPC: C08F28/04 ,  C08F28/02 ,  C08F20/38

公开(公告)号：DE2933523A1

公开(公告)日：1981-03-26

申请号：DE2933523

申请日：1979-08-18

Applicant: BASF AG

Inventor： NAARMANN HERBERT DIPL CHEM DR ,  PENZIEN KLAUS DIPL CHEM DR ,  VIEHE HEINZ GUENTER PROF DIPL

IPC: C08F238/00 ,  C08F238/02

Abstract: Copolymers of acetylene are prepared by catalytic polymerization of mixtures of acetylene and heteroalkynes with Ziegler catalysts. The polymers may be used as pigments or as colored coatings on metal, glass or plastic.

公开(公告)号：DE2929950A1

公开(公告)日：1981-02-26

申请号：DE2929950

申请日：1979-07-24

Applicant: BASF AG

Inventor： NAARMANN HERBERT DIPL CHEM DR ,  ZDENEK JANONSEK DR ,  VIEHE HEINZ GUENTER PROF DIPL ,  BEAUJEAN MICHEL ,  MERENYI ROBERT DR

IPC: C07D307/06 ,  C07D307/08 ,  C07D319/12 ,  C07D323/00 ,  C07D325/00 ,  C07D307/12

公开(公告)号：DE2928097A1

公开(公告)日：1981-02-05

申请号：DE2928097

申请日：1979-07-12

Applicant: BASF AG

Inventor： NAARMANN HERBERT DIPL CHEM DR ,  ZDENEK JANONSEK DR ,  VIEHE HEINZ GUENTER PROF DIPL ,  BEAUJEAN MICHEL ,  MERENYI ROBERT DR

IPC: C07C255/32 ,  C07C255/53 ,  C07C317/44 ,  C07C121/20 ,  C07C121/28 ,  C07C121/66 ,  C07C121/75 ,  C07C147/107

Abstract: Nitriles having formula R-CN, (I), or dinitriles having formula NC-R3-CN, (II), (where R is -CHR1R2 or -C(R1)2R2; R3 is -CHR1-R4-CHR1-; R1, R2 are H, opt. unsatd. opt. branched aliphatic hydrocarbyl, aryl, cycloaliphatic or opt. substd. aromatic hydrocarbyl and R4 is opt. branched alkylene, alkylene oxide, cycloalkylene or opt. substd. arylene, arylene oxide or arylene sulphone) are dimerised and/or oligomerised with organic peroxides, at 120-200 deg.C, in a protective gas atmos. The dimers and/or oligomers are new. Dimer and/or oligomer use as antistatic finishes and/or as flame-retardants for plastics and fibres is claimed. The prods. can also be used as high-boiling solvents and as starting materials for the corresp. acids, their derivs. and, after redn., for prim. amines. The dimers and/or oligomers do not sweat out of plastics and have high complex-forming capacity for metal salts.