N-ACRYLIMINO HETEROCYCLIC COMPOUNDS
    1.
    发明申请
    N-ACRYLIMINO HETEROCYCLIC COMPOUNDS 审中-公开
    N-丙烯酰胺杂环化合物

    公开(公告)号:US20160235069A1

    公开(公告)日:2016-08-18

    申请号:US15023176

    申请日:2014-09-19

    Applicant: BASF SE

    Abstract: The present invention relates to N-acrylimino compound of formula (I): wherein X is O or S, in particular O; Het is a 5- or 6-membered carbon-bound or nitrogen-bound heterocyclic ring, W1-W2-W3-W4 represents a carbon chain group connected to N and C═N, and thus forming a saturated, unsaturated, or partially unsaturated 5 or 6 membered nitrogen containing heterocycle, wherein W1, W2, W3 and W4 each individually represent CRvRw, R1, R2 may be hydrogen, halogen, etc. R3 is selected from the group consisting of hydrogen, halogen, CN, C1-C6-alkyl, etc. R4 is selected from the group consisting of hydrogen, halogen, CN, C1-C10-alkyl, etc. R5 is selected from the group consisting of hydrogen CN, C1-C10-alkyl, C2-C10-alkenyl C3-C8-cycloalkyl, S(O)nNR9aR9b, O—NR9aR9b, NR9aR9b, NR9a NR9aR9b, NR9aC(═O)R7a, NR9aC(═S)R7a, NR9aC(═O)NR9aR9b, NR9aC(═S)NR9aR9b, C(═O)OR8, C(═O)NR9aR9b, C(═S)NR9aR9b, C(═O)R7a, C(═S)R7a, a moitey Q-phenyl, where the phenyl ring is optionally substituted with 1, 2, 3, 4 or 5 identical or different substituents R10, and a moiety Q-Het# where Het# represents a 3- to 10-membered saturated, partly saturated or unsaturated aromatic heterocyclic ring. The invention also relates to the use of the N-acrylimino heterocyclic compounds, their stereoisomers, their tautomers and their salts, for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.

    Abstract translation: 本发明涉及式(I)的N-丙烯酰亚氨基化合物:其中X是O或S,特别是O; Het是5或6元碳键或氮键合的杂环,W1-W2-W3-W4表示与N和C = N连接的碳链基团,因此形成饱和的,不饱和的或部分不饱和的 5或6元含氮杂环,其中W1,W2,W3和W4各自独立地表示CRvRw,R1,R2可以是氢,卤素等。R3选自氢,卤素,CN,C1-C6- 烷基等.R 4选自氢,卤素,CN,C 1 -C 10 - 烷基等。R 5选自氢CN,C 1 -C 10 - 烷基,C 2 -C 10 - 烯基C3- C 9 - 环烷基,S(O)n NR 9 a R 9 b,O-NR 9 a R 9 b,NR 9 a R 9 b,NR 9 a NR 9 a R 9 b,NR 9 a C(= O)R 7a,NR 9 a C(≡S)R 7a,NR 9 a C(≡O)NR 9 a R 9 b,NR 9 a C(≡S)NR 9 a R 9 b,C O)OR 8,C(= O)NR 9 a R 9 b,C(= S)NR 9 a R 9 b,C(= O)R 7a,C(= O)R 7a,其中苯环任选被1,2, 3,4或5个相同或不同的取代基R10,和其中Het#表示a的部分Q-Het# 3-至10-元饱和,部分饱和或不饱和的芳族杂环。 本发明还涉及N-丙烯酰胺杂环化合物,其立体异构体,其互变异构体及其盐的用途,用于对抗无脊椎动物害虫。 此外,本发明还涉及防治无脊椎害虫的方法,其包括施用这样的化合物。

    N-ACYLIMINO HETEROCYCLIC COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS

    公开(公告)号:US20180179177A1

    公开(公告)日:2018-06-28

    申请号:US15128625

    申请日:2015-03-26

    Applicant: BASF SE

    Abstract: The present invention relates to N-acylimino compound of formula (I): wherein X is O or S, in particular O; m is an integer selected from 0, 1, 2, 3, 4, 5 or 6; Het is a 5 or 6 membered carbon-bound or nitrogen-bound heterocyclic ring, W1—W2—W3—W4 represents a carbon chain group connected to N and C═N, and thus forming a saturated, unsaturated, or partially unsaturated 5 or 6 membered nitrogen containing heterocycle, wherein W1, W2, W3 and W4 each individually represent CRvRw, R1, R2 may be hydrogen, halogen, etc. R3 may be hydrogen, halogen, CN, C1-C6-alkyl, etc. R4a, R4b if present, may be hydrogen, halogen, C1-C6-alkyl, etc. or R3 and R4a may also form a double bound, R5 may be hydrogen, halogen, CN, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C2-C6-alkenyl, C2-C6-alkynyl, C2-C6-alkenylthio, C2-C6-alkenylsulfinyl, C2-C6-alkenylsulfonyl, C2-C6-alkynyl, C2-C6-alkynylthio, C2-C6-alkynylsulfinyl, C2-C6-alkynylsulfonyl, etc. R3 and R5 together may also form with the carbon atom they are bound to, a 3-, 4-, 5- or 6-membered saturated partially unsaturated carbocycle or heterocycle. The invention also relates to the use of the N-acylimino heterocyclic compounds, their stereoisomers, their tautomers and their salts, for combating invertebrate pests. Furthermore the invention relates also to methods of combating invertebrate pests, which comprises applying such compounds.

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