PROCESS FOR END FUNCTIONALIZED ACRYLIC OLIGOMERS VIA HIGH TEMPERATURE POLYMERIZATION AND EFFICIENT ADDITION REACTIONS

    公开(公告)号:US20210340295A1

    公开(公告)日:2021-11-04

    申请号:US17259854

    申请日:2019-07-12

    Applicant: BASF SE

    Abstract: An oligomeric resin adduct, compositions comprising the oligomeric resinadduct, and process for making oligomeric resin adduct, wherein the the process includes charging into a reactor a mixture including a vinylic monomer that includes a styrenic monomer, a (meth)acrylic monomer, or a mixture thereof; a polymerization initiator; and optionally a reaction solvent; maintaining the reactor at a temperature sufficient to produce an oligomeric resin from the vinylic monomer; maintaining the vinylic monomer, the polymerization initiator, and optionally the reaction solvent at a sufficient amount to produce the oligomeric resin, wherein the oligomeric resin contains at least one terminal olefinic unsaturation; and reacting the oligomeric resin with a compound of Formula I, Formula II, or a mixture thereof as defined herein.

    FLUORINATED ACRYLATE BLOCK COPOLYMERS WITH LOW DYNAMIC SURFACE TENSION
    3.
    发明申请
    FLUORINATED ACRYLATE BLOCK COPOLYMERS WITH LOW DYNAMIC SURFACE TENSION 审中-公开
    具有低动态表面张力的氟化丙烯酸酯嵌段共聚物

    公开(公告)号:US20170009096A1

    公开(公告)日:2017-01-12

    申请号:US15210748

    申请日:2016-07-14

    Applicant: BASF SE

    Abstract: The present invention relates to a composition, comprising a binder resin, a block copolymer which comprises at least a block A and a block B, wherein the block A comprises monomer units derived from a compound selected from (meth)acrylic acid, a (meth)acrylic acid ester, a (meth)acrylamide, a vinyl aromatic compound, or any mixture thereof, the block B comprises monomer units derived from a compound selected from a fluorinated (meth)acrylic ester having the following formula (I): H2C═C(R1)(C(O)ORF−1)  (I) wherein R1 is H or methyl; and RF−1 is an organic residue containing a perfluorinated C4-6 alkyl group, a fluorinated alpha-olefin having the following formula (II): H2C═CH(RF−2)  (II) wherein RF−2 is an organic residue containing a perfluorinated C4-6 alkyl group, i.e., —(CF2)3-5—CF3 or any mixture thereof.

    Abstract translation: 本发明涉及包含粘合剂树脂,至少包含嵌段A和嵌段B的嵌段共聚物的组合物,其中嵌段A包含衍生自选自(甲基)丙烯酸,(甲基)丙烯酸, )丙烯酸酯,(甲基)丙烯酰胺,乙烯基芳族化合物或其任何混合物,嵌段B包含衍生自选自具有下式(I)的氟化(甲基)丙烯酸酯的化合物的单体单元:H 2 C = C(R 1)(C(O)ORF-1),其中R 1为H或甲基; 并且RF-1是含有全氟化C 4-6烷基的有机残基,具有下式(II)的氟化α-烯烃:H 2 C = CH(RF-2)(II)其中RF-2是含有 全氟化C 4-6烷基,即 - (CF 2)3-5-CF 3或其任何混合物。

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