DITHIENOBENZO-THIENO[3,2-B]THIOPHENE-COPOLYMER AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER
    1.
    发明申请
    DITHIENOBENZO-THIENO[3,2-B]THIOPHENE-COPOLYMER AND ITS USE AS HIGH PERFORMANCE SOLUTION PROCESSABLE SEMICONDUCTING POLYMER 审中-公开
    二噻吩并噻吩并[3,2-B]噻吩共聚物及其用作高性能溶液处理半导体聚合物

    公开(公告)号:WO2011067192A3

    公开(公告)日:2011-09-15

    申请号:PCT/EP2010068365

    申请日:2010-11-29

    Abstract: Dithienobenzo-thieno[3,2-b]thiophene-copolymers of the formula (I) wherein: pi is a monocyclic or polycyclic moiety optionally substituted with 1-4 Ra groups, wherein Ra, at each occurrence, is independently hydrogen or a) a halogen, b) -CN, c) -NO2, d) oxo, e) -OH, f) =C(Rb)2; g) a C1-20 alkyl group, h) a C2-20 alkenyl group, i) a C2-20 alkynyl group, j) a C1-20 alkoxy group, k) a C1-20 alkylthio group, I) a C1-20 haloalkyl group, m) a -Y- C3-10 cycloalkyl group, n) a -Y- C6-14 aryl group, o) a -Y-3-12 membered cycloheteroalkyl group, or p) a -Y-5-14 membered heteroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl or haloaryl group, the 3-12 membered cycloheteroalkyl group, and the 5- 14 membered heteroaryl group is optionally substituted with 1 -4 Rb groups; Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; and R1, R2, R3, at each occurrence, are independently H, a halogen, CN, a C1-30 alkyl group, a C2-30 alkenyl group, a C1-30 haloalkyl group, a C2-30 alkynyl group, a C1-30 alkoxy group, a C(O)-C1-20 alkyl group, a C(O)-OC1-20 alkyl group, a Y-C3-10 cycloalkyl group, a -Y-3- 12 membered cycloheteroalkyl group, each optionally substituted with 1-5 substituents selected from a halogen, -CN, a C1-6 alkyl group, a C1-6 alkoxy group, and a C1-6 haloalkyl group, -L-Ar1, -L-Ar1 -Ar1, -L-Ar1-R4, or -L-Ar1-Ar1-R4 and Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; n = 0, 1, 2; and o = 1 - 1000.

    Abstract translation: 式(I)的二噻吩并苯并噻吩并[3,2-b]噻吩共聚物其中:p1是任选被1-4个Ra基团取代的单环或多环部分,其中Ra在每次出现时独立地为氢或a) b)-CN,c)-NO 2,d)氧代,e)-OH,f)= C(R b)2; g)C1-20烷基,h)C2-20烯基,i)C2-20炔基,j)C1-20烷氧基,k)C1-20烷硫基,I)C1- 20)卤代烷基,m)-YC 3 -10环烷基,n)-YC 6-14芳基,o)-Y-3-12元环杂烷基,或p)-Y- 14元杂芳基,其中C1-20烷基,C2-20链烯基,C2-20炔基,C3-10环烷基,C6-14芳基或卤代芳基,3-12元 环杂烷基,且所述5-14元杂芳基任选被1-4个Rb基团取代; Y在每次出现时独立地为二价C 1-6烷基,二价C 1-6卤代烷基或共价键; 并且R 1,R 2,R 3每次出现时独立地为H,卤素,CN,C 1-30烷基,C 2-30烯基,C 1-30卤代烷基,C 2-30炔基,C 30的烷氧基,C(O)-C1-20烷基,C(O)-OC1-20烷基,Y-C3-10环烷基,-Y-3-12元环杂烷基 其任选被1-5个选自卤素,-CN,C1-6烷基,C1-6烷氧基和C1-6卤代烷基的取代基取代,-L-Ar1,-L-Ar1-Ar1, - L-Ar1-R4或-L-Ar1-Ar1-R4和Y在每次出现时独立地为二价C1-6烷基,二价C1-6卤代烷基或共价键; n = 0,1,2; 和o = 1 - 1000。

    MICROCAPSULE DISPERSION CONTAINING MICROCAPSULES HAVING A HYDROPHILIC CAPSULE CORE

    公开(公告)号:CA2856785A1

    公开(公告)日:2013-06-27

    申请号:CA2856785

    申请日:2012-11-29

    Applicant: BASF SE

    Abstract: The invention relates to microcapsule dispersions containing microcapsules comprising a hydrophilic capsule core and a capsule wall polymer, which capsule wall polymer can be obtained by polymerizing a monomer composition comprising 25 to 95 wt% of one or more C1-C24 alkyl and/or glycidyl esters of acrylic acid and/or methacrylic acid, up to 75 wt% of one or more hydrophilic monomers selected from acrylic acid esters and/or methacrylic acid esters that bear hydroxy and/or carboxy groups, and allyl gluconamide, 0 to 40 wt% of one or more compounds having two or more ethylenically unsaturated groups, wherein the microcapsules are dispersed in a hydrophobic diluent. The invention further relates to the microcapsules, to a method for producing the microcapsules, and to the use of the microcapsules for the delayed release of active ingredients for construction, cosmetic, or plant-protection applications.

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