Light degradable thermoplastic molding composition based on polyacetals
    1.
    发明授权
    Light degradable thermoplastic molding composition based on polyacetals 失效
    基于聚合物的光可降解热塑性成型组合物

    公开(公告)号:US3835096A

    公开(公告)日:1974-09-10

    申请号:US28918272

    申请日:1972-09-14

    Applicant: HOECHST AG

    CPC classification number: C08K5/00 Y10S260/43 C08L59/02

    Abstract: POLYACETALS. I.E. HOMOPOLYMERS OF FORMALDEHYDE OR OF TRIOXANE OR COPOLYMERS OF TRIOXANE WITH MONOFUNCTIONALLY REACTING COMPOUNDS SUCH AS CYCLIC ETHERS OR CYCLIC ACETALS AND POSSIBLY POLYFUNCTIONALLY REACTING COMPOUNDS CAN BE PROTECTED BY ADDITION OF STABILIZERS AGAINST THE ACTION OF HEAT AND OXYGEN. THEY CAN, HOWEVER, BE DEGRADED BY THE ACTION OF ULTRA-VIOLET LIGHT IF THEY CONTAIN LIGHT SENSITIZERS, FOR EXAMPLE ANTHRONE. THE POLYACETALS ARE SUITABLE FOR THE MANUFACTURE OF SHAPED ARTICLES, ESPECIALLY SHEETS.

    LIGHT DEGRADABLE THERMOPLASTIC MOLDING COMPOSITION BASED ON POLYACETALS

    公开(公告)号:ZA726091B

    公开(公告)日:1973-06-27

    申请号:ZA726091

    申请日:1972-09-06

    Applicant: HOECHST AG

    Abstract: 1410641 Light sensitized oxymethylene polymer composition HOECHST AG 14 Sept 1972 [16 Sept 1971] 42709/72 Heading C3P A composition comprises (a) an oxymethylene polymer, (b) a heat stabilizer and (c) a light sensitizer which is anthrone. Oxidation stabilizers, e.g. bisphenols, may also be present. The compositions are degradable in ultra-violet light and may thus be useful for bags, sheets and sacks. They may be prepared by homogenizing the components in granular or powder form at 150‹ to 250‹ C. In examples, polyformaldehyde and trioxan-ethylene oxide, trioxan-dioxolan and trioxan-ethylene oxide-butanedioldiglycidyl ether copolymers are stabilized with calcium ricinoleate or dicyanodiamide and sensitized with anthrone or (for comparison) with benzophenone or fluorenone.

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