公开(公告)号：CA980665A

公开(公告)日：1975-12-30

申请号：CA166915

申请日：1973-03-13

Applicant: IBM

Inventor： FITZGIBBONS WILLIAM A ,  MICHAUD RONALD A ,  KENNEY DONALD M

IPC: C30B31/02 ,  H01L21/22 ,  H01L21/225 ,  H01L21/306

Abstract: 1397684 Diffusion in semi-conductors INTERNATIONAL BUSINESS MACHINES CORP 8 March 1973 [6 April 1972] 11389/73 Heading H1K In a semi-conductor diffusion process an oxide layer containing the dopant is first vapour deposited on the semi-conductor body under conditions such that a dopant-rich interface layer of a material containing both the semiconductor and the dopant forms beneath the oxide layer and an initial concentration of the dopant enters a shallow layer of the semiconductor beneath the interface layer. The atmosphere around the body is then altered to an oxidizing state, the other conditions preferably remaining unchanged, so that the interface layer is converted to a soluble oxide which is subsequently removed by etching together with the dopant-containing oxide layer thereon. A drive-in diffusion is then carried out, preferably in an oxidizing atmosphere, to redistribute the initial dopant concentration from the shallow layer. For a Si body with B as the dopant the dopant-containing oxide is B 2 O 3 deposited, in an aperture in an oxide mask, from a vapour whose source is boron nitride slices having their outer surfaces oxidized to form B 2 O 3 . An inert carrier gas such as nitrogen is used. The Si body is maintained at 800-1300‹ C. during the oxide deposition process. The interface layer formed in these conditions is believed to be SiB 6 , which converts to a soluble borosilicate glass on the addition of oxygen and/or steam to the atmosphere. As, as a dopant, and Ge, as a semiconductor material, are also mentioned.