公开(公告)号：WO2017029639A1

公开(公告)日：2017-02-23

申请号：PCT/IB2016/054953

申请日：2016-08-18

Applicant: STACKPOLE INTERNATIONAL POWDER METAL, LTD

Inventor： LAWCOCK, Roger

IPC: H01M8/0245 ,  H01M8/0228 ,  H01M8/1246

CPC classification number: H01M8/0228 ,  B22F2998/10 ,  B22F2999/00 ,  C22C1/1078 ,  C22C1/1084 ,  C22C32/0026 ,  H01M8/0206 ,  H01M2008/1293 ,  B22F3/02 ,  B22F3/1017 ,  B22F2003/248 ,  B22F2201/03

Abstract: A solid oxide fuel cell interconnector comprises chromium and at least one conduction enhancing material, the at least one conduction enhancing material comprising MnO, TiO 2 , or MgO. During oxidation or use of the interconnector the conduction enhancing material disperses over the surface of chromium particles (e.g., Cr 2 O 3 ) and enhances the electrical conductivity of the interconnector.

Abstract translation: 固体氧化物燃料电池互连器包括铬和至少一种导电增强材料，所述至少一种导电增强材料包含MnO，TiO 2或MgO。 在氧化或使用互连器期间，导电增强材料分散在铬颗粒（例如Cr 2 O 3）的表面上，并且增强了互连器的导电性。

公开(公告)号：WO2014009788A1

公开(公告)日：2014-01-16

申请号：PCT/IB2013/001476

申请日：2013-07-08

Applicant: STACKPOLE INTERNATIONAL

Inventor： SHIVANATH, Rohith ,  AYRE, Brendan ,  LAWCOCK, Roger

IPC: C23C8/12 ,  H01M8/10 ,  H01M8/12

CPC classification number: H01M8/0232 ,  B22F1/0014 ,  B22F1/0059 ,  B22F3/12 ,  B22F3/24 ,  B22F2003/242 ,  B22F2998/10 ,  B22F2999/00 ,  C22C1/045 ,  C23C8/02 ,  C23C8/10 ,  C23C8/24 ,  H01M8/0243 ,  H01M8/0245 ,  H01M2008/1293 ,  Y02P70/56 ,  B22F3/02 ,  B22F3/1021 ,  B22F3/10 ,  B22F2003/248 ,  B22F2201/02 ,  B22F2201/03 ,  B22F2201/05

Abstract: An interconnector for a solid oxide fuel cell is manufactured by single-press compacting a powder blend to form a green interconnector with a desired shape of a final interconnector. The powder blend includes chromium and iron, and may include an organic lubricant. At least 50 wt% or more of an iron portion of the powder blend comprises iron particles smaller than 45 urn. The green interconnector is then sintered and oxidized to form the final interconnector. The oxidation step occurs in a continuous flow furnace in which a controlled atmosphere (e.g., humidified air) is fed into the furnace in the travel direction of the interconnector. The final interconnector comprises at least 90 wt% chromium, at least 3 wt% iron, and less than 0.2 wt% nitrogen. An average density within a flow field of the final interconnector may be less than 6.75 g/cc.

Abstract translation: 用于固体氧化物燃料电池的互连器通过单压压粉末混合物来制造，以形成具有期望形状的最终互连器的绿色互连器。 粉末混合物包括铬和铁，并且可以包括有机润滑剂。 至少50wt％或更多的粉末共混物的铁部分包含小于45um的铁颗粒。 然后将绿色互连器烧结并氧化形成最终的互连器。 氧化步骤发生在连续流动炉中，其中将受控气氛（例如，加湿空气）沿着互连器的行进方向进料到炉中。 最终的互连器包括至少90wt％的铬，至少3wt％的铁和小于0.2wt％的氮。 最终互连器的流场内的平均密度可以小于6.75g / cc。

公开(公告)号：EP2870270A1

公开(公告)日：2015-05-13

申请号：EP13817229.1

申请日：2013-07-08

Applicant: Stackpole International Powder Metal, ULC

Inventor： SHIVANATH, Rohith ,  AYRE, Brendan ,  LAWCOCK, Roger

IPC: C23C8/12 ,  H01M8/10 ,  H01M8/12

CPC classification number: H01M8/0232 ,  B22F1/0014 ,  B22F1/0059 ,  B22F3/12 ,  B22F3/24 ,  B22F2003/242 ,  B22F2998/10 ,  B22F2999/00 ,  C22C1/045 ,  C23C8/02 ,  C23C8/10 ,  C23C8/24 ,  H01M8/0243 ,  H01M8/0245 ,  H01M2008/1293 ,  Y02P70/56 ,  B22F3/02 ,  B22F3/1021 ,  B22F3/10 ,  B22F2003/248 ,  B22F2201/02 ,  B22F2201/03 ,  B22F2201/05

Abstract: An interconnector for a solid oxide fuel cell is manufactured by single-press compacting a powder blend to form a green interconnector with a desired shape of a final interconnector. The powder blend includes chromium and iron, and may include an organic lubricant. At least 50 wt% or more of an iron portion of the powder blend comprises iron particles smaller than 45 urn. The green interconnector is then sintered and oxidized to form the final interconnector. The oxidation step occurs in a continuous flow furnace in which a controlled atmosphere (e.g., humidified air) is fed into the furnace in the travel direction of the interconnector. The final interconnector comprises at least 90 wt% chromium, at least 3 wt% iron, and less than 0.2 wt% nitrogen. An average density within a flow field of the final interconnector may be less than 6.75 g/cc.

公开(公告)号：EP3056582A3

公开(公告)日：2016-12-28

申请号：EP15197060.5

申请日：2013-07-08

Applicant: Stackpole International Powder Metal, ULC

Inventor： SHIVANATH, Rohith ,  AYRE, Brendan ,  LAWCOCK, Roger

IPC: C23C8/02 ,  C23C8/10 ,  H01M8/0232 ,  H01M8/0245 ,  B22F1/00 ,  C22C1/04 ,  B22F3/12 ,  B22F3/24 ,  C23C8/24 ,  H01M8/124 ,  H01M8/12

CPC classification number: H01M8/0232 ,  B22F1/0014 ,  B22F1/0059 ,  B22F3/12 ,  B22F3/24 ,  B22F2003/242 ,  B22F2998/10 ,  B22F2999/00 ,  C22C1/045 ,  C23C8/02 ,  C23C8/10 ,  C23C8/24 ,  H01M8/0243 ,  H01M8/0245 ,  H01M2008/1293 ,  Y02P70/56 ,  B22F3/02 ,  B22F3/1021 ,  B22F3/10 ,  B22F2003/248 ,  B22F2201/02 ,  B22F2201/03 ,  B22F2201/05

Abstract: An interconnector for a solid oxide fuel cell is manufactured by single-press compacting a powder blend to form a green interconnector with a desired shape of a final interconnector. The powder blend includes chromium and iron, and may include an organic lubricant. At least 50 wt% or more of an iron portion of the powder blend comprises iron particles smaller than 45 um. The green interconnector is then sintered and oxidized to form the final interconnector. The oxidation step occurs in a continuous flow furnace in which a controlled atmosphere (e.g., humidified air) is fed into the furnace in the travel direction of the interconnector. The final interconnector comprises at least 90 wt% chromium, at least 3 wt% iron, and less than 0.2 wt% nitrogen. An average density within a flow field of the final interconnector may be less than 6.75 g/cc.

Abstract translation: 用于固体氧化物燃料电池的互连器通过单压压粉末混合物来制造，以形成具有所需形状的最终互连器的绿色互连器。 粉末混合物包括铬和铁，并且可以包括有机润滑剂。 至少50重量％以上的粉末混合物的铁部分包含小于45μm的铁颗粒。 然后将绿色互连器烧结并氧化形成最终的互连器。 氧化步骤发生在连续流动炉中，其中将受控气氛（例如，加湿空气）沿着互连器的行进方向进料到炉中。 最终的互连器包括至少90wt％的铬，至少3wt％的铁和小于0.2wt％的氮。 最终互连器的流场内的平均密度可以小于6.75g / cc。

公开(公告)号：EP3056582A2

公开(公告)日：2016-08-17

申请号：EP15197060.5

申请日：2013-07-08

Applicant: Stackpole International Powder Metal, ULC

Inventor： SHIVANATH, Rohith ,  AYRE, Brendan ,  LAWCOCK, Roger

IPC: C23C8/02 ,  C23C8/10 ,  H01M8/0232 ,  H01M8/0245 ,  B22F1/00 ,  C22C1/04 ,  B22F3/12 ,  B22F3/24 ,  C23C8/24 ,  H01M8/124 ,  H01M8/12

CPC classification number: H01M8/0232 ,  B22F1/0014 ,  B22F1/0059 ,  B22F3/12 ,  B22F3/24 ,  B22F2003/242 ,  B22F2998/10 ,  B22F2999/00 ,  C22C1/045 ,  C23C8/02 ,  C23C8/10 ,  C23C8/24 ,  H01M8/0243 ,  H01M8/0245 ,  H01M2008/1293 ,  Y02P70/56 ,  B22F3/02 ,  B22F3/1021 ,  B22F3/10 ,  B22F2003/248 ,  B22F2201/02 ,  B22F2201/03 ,  B22F2201/05

Abstract: An interconnector for a solid oxide fuel cell is manufactured by single-press compacting a powder blend to form a green interconnector with a desired shape of a final interconnector. The powder blend includes chromium and iron, and may include an organic lubricant. At least 50 wt% or more of an iron portion of the powder blend comprises iron particles smaller than 45 um. The green interconnector is then sintered and oxidized to form the final interconnector. The oxidation step occurs in a continuous flow furnace in which a controlled atmosphere (e.g., humidified air) is fed into the furnace in the travel direction of the interconnector. The final interconnector comprises at least 90 wt% chromium, at least 3 wt% iron, and less than 0.2 wt% nitrogen. An average density within a flow field of the final interconnector may be less than 6.75 g/cc.

Abstract translation: 用于固体氧化物燃料电池的互连器通过单次压制粉末混合物来制造，以形成具有期望形状的最终互连器的绿色互连器。 粉末混合物包含铬和铁，并且可以包含有机润滑剂。 粉末混合物的至少50重量％或更多的铁部分包含小于45微米的铁粒子。 然后将绿色互连器烧结并氧化以形成最终的互连器。 氧化步骤在连续流动炉中进行，其中受控气氛（例如潮湿的空气）沿着互连器的行进方向被馈送到炉中。 最终的互连器包含至少90重量％的铬，至少3重量％的铁和小于0.2重量％的氮。 最终互连器的流场内的平均密度可小于6.75g / cc。