公开(公告)号：IN149044B

公开(公告)日：1981-08-22

申请号：IN164DE1978

申请日：1978-03-01

Applicant: STANDARD OIL CO

Inventor： WONG EUNICE KIE TENG ,  MILBERGER E

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J31/00 ,  C07B61/00 ,  C07C51/25 ,  C07C51/31 ,  C07C53/26

Abstract: Maleic anhydride is produced by the oxidation of 1,3-butadiene, n-butylenes, crotonaldehyde and furan with molecular oxygen in the vapor phase in the presence of catalytic oxides of antimony, molybdenum, at least one element selected from the group consisting of niobium, zirconium, titanium and tantalum and optionally a reducing agent capable of reducing at least part of the molybdenum in the catalyst to a valence state below +6 selected from the group consisting of hydrazine hydrate, molybdenum, tungsten, magnesium, aluminum, and nickel. This catalyst may optionally contain one or more elements selected from the group consisting of Li, Ag, Ce, Cd, Co, As, Si, Zn, Ge, Bi, Ru, Pt, U, Al and Ni. Especially desirable yields of maleic anhydride are obtained from 1,3-butadiene in the presence of a catalyst wherein molybdenum metal is used as a reducing agent.

公开(公告)号：BR8206638A

公开(公告)日：1983-10-04

申请号：BR8206638

申请日：1982-11-17

Applicant: STANDARD OIL CO

Inventor： MILBERGER ERNEST CARL ,  WONG EUNICE KIE TENG

IPC: B01J21/00 ,  B01J23/00 ,  B01J27/00 ,  C07B61/00 ,  C07D207/44 ,  C07D207/448 ,  C07D207/452 ,  C07C121/30 ,  C07C121/32 ,  C07D307/60 ,  B01J23/88

Abstract: A process for the nitrogenation of hydrocarbons, which results in the production of cyclic imides and nitriles comprises contacting hydrocarbons with molecular oxygen and a nitrogenating agent, including ammonia or primary amines, in the presence of an oxidation catalyst containing variable valency metal oxides, in the vapor phase at elevated temperature.

公开(公告)号：IN148300B

公开(公告)日：1981-01-10

申请号：IN166DE1978

申请日：1978-03-03

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER N ,  MILBERGER E ,  WONG EUNICE KIE TENG

IPC: C07D307/60 ,  B01J21/06 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  C07C57/145

Abstract: Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.

公开(公告)号：AT375642B

公开(公告)日：1984-08-27

申请号：AT454282

申请日：1982-12-14

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST CARL ,  WONG EUNICE KIE TENG

IPC: B01J21/00 ,  B01J23/00 ,  B01J27/00 ,  C07B61/00 ,  C07D207/44 ,  C07D207/448 ,  C07D207/452

Abstract: A process for the nitrogenation of hydrocarbons, which results in the production of cyclic imides and nitriles comprises contacting hydrocarbons with molecular oxygen and a nitrogenating agent, including ammonia or primary amines, in the presence of an oxidation catalyst containing variable valency metal oxides, in the vapor phase at elevated temperature.

公开(公告)号：ATA454282A

公开(公告)日：1984-01-15

申请号：AT454282

申请日：1982-12-14

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST CARL ,  WONG EUNICE KIE TENG

IPC: B01J21/00 ,  B01J23/00 ,  B01J27/00 ,  C07B61/00 ,  C07D207/44 ,  C07D207/448 ,  C07D207/452

Abstract: A process for the nitrogenation of hydrocarbons, which results in the production of cyclic imides and nitriles comprises contacting hydrocarbons with molecular oxygen and a nitrogenating agent, including ammonia or primary amines, in the presence of an oxidation catalyst containing variable valency metal oxides, in the vapor phase at elevated temperature.