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公开(公告)号:DE2720861A1
公开(公告)日:1977-12-15
申请号:DE2720861
申请日:1977-05-10
Applicant: STANDARD OIL CO OHIO
Inventor: MILLER ARTHUR FRANCIS , ZAGATA ROBERT JOSEPH , GRASSELLI ROBERT KARL
Abstract: The production of acrylates and methacrylates, made by the oxidative esterification of propylene or isobutylene wherein gaseous reactants are contacted with one or more catalysts and ethylene or an alcohol can be advantageously conducted in a single fluid bed reactor to obtain the desired ester.
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公开(公告)号:DE3267980D1
公开(公告)日:1986-01-30
申请号:DE3267980
申请日:1982-04-08
Applicant: STANDARD OIL CO OHIO
IPC: C07C27/14 , B01J21/08 , B01J23/00 , B01J23/18 , B01J23/843 , B01J27/057 , B01J27/14 , B01J32/00 , B01J37/02 , B01J37/04 , C07B61/00 , C07C27/00 , C07C27/12 , C07C45/00 , C07C45/35 , C07C47/22 , C07C67/00 , C07C253/00 , C07C253/18 , C07C255/08 , B01J37/00 , B01J23/84 , B01J23/34 , B01J23/24
Abstract: A slurry process for producing a fluid-bed catalyst comprising an antimonate-based oxide complex supported on a catalyst support in which (1) source compounds containing all of the elements of said oxide complex and said support material are combined to form a pre-catalyst slurry, (2) the liquid removed from said pre-catalyst slurry to form a pre-catalyst, and (3) said pre-catalyst is heated at elevated temperature to form said catalyst, in which the support material combined with the source compounds in step (1) is composed of (a) a fumed catalyst support material, such as fumed silica, and (b) a catalyst support material sol, such as a silica sol. The pro-catalyst slurry is formed without the addition of a slurry-derived solid containing fumed catalyst support material and one or more of the source compounds. The process is preferably a single slurry process. The catalyst produced has improved catalytic properties and attrition resistance.
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公开(公告)号:AT358001B
公开(公告)日:1980-08-11
申请号:AT364277
申请日:1977-05-20
Applicant: STANDARD OIL CO OHIO
Inventor: MILLER ARTHUR FRANCIS , ZAGATA ROBERT JOSEPH , GRASSELLI ROBERT KARL
Abstract: The production of acrylates and methacrylates, made by the oxidative esterification of propylene or isobutylene wherein gaseous reactants are contacted with one or more catalysts and ethylene or an alcohol can be advantageously conducted in a single fluid bed reactor to obtain the desired ester.
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公开(公告)号:NO771875A
公开(公告)日:1977-11-29
申请号:NO771875
申请日:1977-05-27
Applicant: STANDARD OIL CO OHIO
Inventor: MILLER ARTHUR FRANCIS , ZAGATA ROBERT JOSEPH , GRASSELLI ROBERT KARL
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公开(公告)号:IN164483B
公开(公告)日:1989-03-25
申请号:IN576DE1985
申请日:1985-07-18
Applicant: STANDARD OIL CO OHIO
IPC: B01J23/18
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公开(公告)号:BR8203314A
公开(公告)日:1983-05-24
申请号:BR8203314
申请日:1982-06-04
Applicant: STANDARD OIL CO OHIO
IPC: C07C27/14 , B01J21/08 , B01J23/00 , B01J23/18 , B01J23/843 , B01J27/057 , B01J27/14 , B01J32/00 , B01J37/02 , B01J37/04 , C07B61/00 , C07C27/00 , C07C27/12 , C07C45/00 , C07C45/35 , C07C47/22 , C07C67/00 , C07C253/00 , C07C253/18 , C07C255/08
Abstract: A slurry process for producing a fluid-bed catalyst comprising an antimonate-based oxide complex supported on a catalyst support in which (1) source compounds containing all of the elements of said oxide complex and said support material are combined to form a pre-catalyst slurry, (2) the liquid removed from said pre-catalyst slurry to form a pre-catalyst, and (3) said pre-catalyst is heated at elevated temperature to form said catalyst, in which the support material combined with the source compounds in step (1) is composed of (a) a fumed catalyst support material, such as fumed silica, and (b) a catalyst support material sol, such as a silica sol. The pro-catalyst slurry is formed without the addition of a slurry-derived solid containing fumed catalyst support material and one or more of the source compounds. The process is preferably a single slurry process. The catalyst produced has improved catalytic properties and attrition resistance.
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公开(公告)号:PT75207A
公开(公告)日:1982-08-01
申请号:PT7520782
申请日:1982-07-07
Applicant: STANDARD OIL CO OHIO
IPC: C07C27/14 , B01J21/08 , B01J23/00 , B01J23/18 , B01J23/843 , B01J27/057 , B01J27/14 , B01J32/00 , B01J37/02 , B01J37/04 , C07B61/00 , C07C27/00 , C07C27/12 , C07C45/00 , C07C45/35 , C07C47/22 , C07C67/00 , C07C253/00 , C07C253/18 , C07C255/08 , B01J
Abstract: A slurry process for producing a fluid-bed catalyst comprising an antimonate-based oxide complex supported on a catalyst support in which (1) source compounds containing all of the elements of said oxide complex and said support material are combined to form a pre-catalyst slurry, (2) the liquid removed from said pre-catalyst slurry to form a pre-catalyst, and (3) said pre-catalyst is heated at elevated temperature to form said catalyst, in which the support material combined with the source compounds in step (1) is composed of (a) a fumed catalyst support material, such as fumed silica, and (b) a catalyst support material sol, such as a silica sol. The pro-catalyst slurry is formed without the addition of a slurry-derived solid containing fumed catalyst support material and one or more of the source compounds. The process is preferably a single slurry process. The catalyst produced has improved catalytic properties and attrition resistance.
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公开(公告)号:PT75207B
公开(公告)日:1984-06-27
申请号:PT7520782
申请日:1982-07-07
Applicant: STANDARD OIL CO OHIO
IPC: C07C27/14 , B01J21/08 , B01J23/00 , B01J23/18 , B01J23/843 , B01J27/057 , B01J27/14 , B01J32/00 , B01J37/02 , B01J37/04 , C07B61/00 , C07C27/00 , C07C27/12 , C07C45/00 , C07C45/35 , C07C47/22 , C07C67/00 , C07C253/00 , C07C253/18 , C07C255/08 , B01J37/00 , B01J23/84 , B01J23/34 , B01J23/24
Abstract: A slurry process for producing a fluid-bed catalyst comprising an antimonate-based oxide complex supported on a catalyst support in which (1) source compounds containing all of the elements of said oxide complex and said support material are combined to form a pre-catalyst slurry, (2) the liquid removed from said pre-catalyst slurry to form a pre-catalyst, and (3) said pre-catalyst is heated at elevated temperature to form said catalyst, in which the support material combined with the source compounds in step (1) is composed of (a) a fumed catalyst support material, such as fumed silica, and (b) a catalyst support material sol, such as a silica sol. The pro-catalyst slurry is formed without the addition of a slurry-derived solid containing fumed catalyst support material and one or more of the source compounds. The process is preferably a single slurry process. The catalyst produced has improved catalytic properties and attrition resistance.
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公开(公告)号:MX144568A
公开(公告)日:1981-10-27
申请号:MX16912577
申请日:1977-05-13
Applicant: STANDARD OIL CO OHIO
Inventor: MILLER ARTHUR FRANCIS , ZAGATA ROBERT JOSEPH , GRASSELLI ROBERT KARL
Abstract: The production of acrylates and methacrylates, made by the oxidative esterification of propylene or isobutylene wherein gaseous reactants are contacted with one or more catalysts and ethylene or an alcohol can be advantageously conducted in a single fluid bed reactor to obtain the desired ester.
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公开(公告)号:ATA364277A
公开(公告)日:1980-01-15
申请号:AT364277
申请日:1977-05-20
Applicant: STANDARD OIL CO OHIO
Inventor: MILLER ARTHUR FRANCIS , ZAGATA ROBERT JOSEPH , GRASSELLI ROBERT KARL
Abstract: The production of acrylates and methacrylates, made by the oxidative esterification of propylene or isobutylene wherein gaseous reactants are contacted with one or more catalysts and ethylene or an alcohol can be advantageously conducted in a single fluid bed reactor to obtain the desired ester.
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