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1.发明公开
公开(公告)号：EP2872252A4
公开(公告)日：2016-02-17
申请号：EP13816862
申请日：2013-07-11
Applicant: STC UNM
Inventor： SEROV ALEXEY , ATANASSOV PLAMEN B
IPC: B01J37/08 , B01J23/745 , C07D235/30 , C07D235/32 , H01M4/90 , H01M8/10
CPC classification number: H01M4/9075 , B01J23/745 , B01J37/084 , C07D235/30 , C07D235/32 , H01M4/90 , H01M4/9041 , H01M2008/1095 , Y02E60/50
Abstract: A method of preparation of M-N—C catalytic material utilizing a sacrificial support approach and using inexpensive and readily available metal precursors and carbendazim (CBDZ) as the carbon source is described.
Abstract translation: 描述了使用牺牲支撑方法并使用廉价且容易获得的金属前体和多菌灵（CBDZ）作为碳源制备M-N-C催化材料的方法。
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2.发明申请NON-PGM CATHODE CATALYSTS FOR FUEL CELL APPLICATION DERIVED FROM HEAT TREATED HETEROATOMIC AMINES PRECURSORS 审中-公开用于从热处理的异辛烯前体得到的燃料电池应用的非PGM阴极催化剂
公开(公告)号：WO2012174344A3
公开(公告)日：2013-05-02
申请号：PCT/US2012042609
申请日：2012-06-15
Applicant: STC UNM , SEROV ALEXEY , HALEVI BARR , ARTYUSHKOVA KATERYNA , ATANASSOV PLAMEN B
Inventor： SEROV ALEXEY , HALEVI BARR , ARTYUSHKOVA KATERYNA , ATANASSOV PLAMEN B
CPC classification number: H01M4/8652 , B01J23/70 , B01J23/8892 , B01J35/0033 , B01J37/084 , H01M4/8621 , H01M4/8885 , H01M4/9041 , H01M4/9083 , H01M4/9091 , H01M2004/8689
Abstract: A method of preparing M-N-C catalysts utilizing a sacrificial support approach and inexpensive and readily available polymer precursors as the source of nitrogen and carbon is disclosed. Exemplary polymer precursors include non-porphyrin precursors with no initial catalytic activity. Examples of suitable non-catalytic non-porphyrin precursors include, but are not necessarily limited to low molecular weight precursors that form complexes with iron such as 4-aminoantipirine, phenylenediamine, hydroxysuccinimide, ethanolamine, and the like.
Abstract translation: 公开了一种使用牺牲支撑方法制备M-N-C催化剂的方法，并且公开了廉价且容易获得的聚合物前体作为氮和碳的来源。 示例性聚合物前体包括没有初始催化活性的非卟啉前体。 合适的非催化非卟啉前体的实例包括但不一定限于与铁形成络合物的低分子量前体，例如4-氨基安替比林，苯二胺，羟基琥珀酰亚胺，乙醇胺等。
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3.发明申请CATHODE CATALYSTS FOR FUEL CELL APPLICATION DERIVED FROM POLYMER PRECURSORS 审中-公开用于从聚合物前驱体得到的燃料电池应用的阴极催化剂
公开(公告)号：WO2012174335A3
公开(公告)日：2013-04-04
申请号：PCT/US2012042593
申请日：2012-06-15
Applicant: STC UNM , SEROV ALEXEY , HALEVI BARR , ROBSON MICHAEL , PATTERSON WENDY , ARTYUSHKOVA KATERYNA , ATANASSOV PLAMEN B
Inventor： SEROV ALEXEY , HALEVI BARR , ROBSON MICHAEL , PATTERSON WENDY , ARTYUSHKOVA KATERYNA , ATANASSOV PLAMEN B
CPC classification number: H01M4/9091 , H01M4/90 , H01M2004/8689 , Y02E60/50
Abstract: A method of preparing M-N-C catalysts utilizing a sacrificial support approach and inexpensive and readily available polymer precursors as the source of nitrogen and carbon is disclosed. Exemplary polymer precursors include those that do not form complexes with iron, but which do complex with silica, for example, polyetheleneimine (PEI), Poly(2-ethyl-2-oxazoline), Poly(acrylamide-co-diallyldimethylammonium chloride), Poly(melamine-co-formaldehyde), Poly[[6-[(l,l,3,3-tetramethylbutyl)amino]-s-triazine-2,4-diyl]-[(2,2,6,6-tetramethyl-4-piperidyl)imino] -hexamethylene- [(2,2,6,6-tetramethyl-4-piperidyl)imino] and the like.
Abstract translation: 公开了一种使用牺牲支撑方法制备M-N-C催化剂的方法，并且公开了廉价且容易获得的聚合物前体作为氮和碳的来源。 示例性聚合物前体包括不与铁形成络合物但与二氧化硅络合的那些，例如聚乙烯亚胺（PEI），聚（2-乙基-2-恶唑啉），聚（丙烯酰胺 - 共二烯丙基二甲基氯化铵），聚 （三聚氰胺 - 共 - 甲醛），聚[[6 - [（1,1,3,3-四甲基丁基）氨基] -s-三嗪-2,4-二基] - [（2,2,6,6-四甲基 -4-哌啶基）亚氨基] - 六亚甲基 - [（2,2,6,6-四甲基-4-哌啶基）亚氨基]等。
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4.发明申请STRUCTURED CATHODE CATALYSTS FOR FUEL CELL APPLICATION DERIVED FROM METAL-NITROGEN-CARBON PRECURSORS, USING HIERARCHICALLY STRUCTURED SILICA AS A SACRIFICIAL SUPPORT 审中-公开结构化阴极催化剂用于衍生自金属氮碳前体的燃料电池应用，使用分层结构的二氧化硅作为牺牲品支持
公开(公告)号：WO2013040567A2
公开(公告)日：2013-03-21
申请号：PCT/US2012055774
申请日：2012-09-17
Applicant: STC UNM , PATTERSON WENDY , ROBSON MICHAEL , WALKER CANDACE , SEROV ALEXEY , HALEVI BARR , ARTYUSHKOVA KATERYNA , ATANASSOV PLAMEN B
Inventor： PATTERSON WENDY , ROBSON MICHAEL , WALKER CANDACE , SEROV ALEXEY , HALEVI BARR , ARTYUSHKOVA KATERYNA , ATANASSOV PLAMEN B
CPC classification number: H01M4/9041 , H01M4/9016 , H01M4/9091
Abstract: Methods for forming novel fuel cell catalysts are described. The catalyst has a physical structure that is the inverse image of a plurality of hierarchically structured sacrificial support particles. The particles may be formed independently and then infused with one or more transitional metallic salts and nitrogen carbon precursors, or the sacrificial support precursors, transitional metallic salts, and nitrogen carbon precursors may all be combined in such a way that a hierarchically structured sacrificial support with the infused transitional metallic salts and nitrogen carbon precursors is formed in a single step. The infused sacrificial support is then pyrolized, at least once, and the sacrificial support is removed, resulting in the catalyst.
Abstract translation: 描述了形成新型燃料电池催化剂的方法。 该催化剂具有物理结构，该物理结构是多个分层结构的牺牲载体颗粒的反转图像。 颗粒可以独立形成，然后灌注一种或多种过渡金属盐和氮碳前体，或者牺牲载体前体，过渡金属盐和氮碳前体都可以这样的方式组合，使得分层结构的牺牲载体与 注入的过渡金属盐和氮碳前体在一个步骤中形成。 然后将注入的牺牲性支持物热解，至少一次，并且牺牲性支持物被去除，导致催化剂。
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公开(公告)号：AU2013290185B2
公开(公告)日：2016-06-30
申请号：AU2013290185
申请日：2013-07-11
Applicant: STC UNM
Inventor： SEROV ALEXEY , ATANASSOV PLAMEN B
IPC: B01J37/08 , B01J23/745 , C07D235/30
Abstract: A method of preparation of M-N-C catalytic material utilizing a sacrificial support approach and using inexpensive and readily available metal precursors and carbendazim (CBDZ) as the carbon source is described.
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Patent Agency Ranking
公开(公告)号：AU2012271494A1
公开(公告)日：2013-12-19
申请号：AU2012271494
申请日：2012-06-15
Applicant: STC UNM
Inventor： SEROV ALEXEY , HALEVI BARR , ARTYUSHKOVA KATERYNA , ATANASSOV PLAMEN B
Abstract: A method of preparing M-N-C catalysts utilizing a sacrificial support approach and inexpensive and readily available polymer precursors as the source of nitrogen and carbon is disclosed. Exemplary polymer precursors include non-porphyrin precursors with no initial catalytic activity. Examples of suitable non-catalytic non-porphyrin precursors include, but are not necessarily limited to low molecular weight precursors that form complexes with iron such as 4-aminoantipirine, phenylenediamine, hydroxysuccinimide, ethanolamine, and the like.
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7.发明公开NON-PGM CATALYSTS FOR ORR BASED ON CHARGE TRANSFER ORGANIC COMPLEXES 有权非PGM-KATALYSATORENFÜRORR AUF DER BASIS VON ORGANISCHENLADUNGSÜBERTRAGUNGSKOMPLEXEN
公开(公告)号：EP2945735A4
公开(公告)日：2016-06-22
申请号：EP14740852
申请日：2014-01-16
Applicant: STC UNM
Inventor： SEROV ALEXEY , ATANASSOV PLAMEN B
CPC classification number: H01M4/9041 , B01J27/24 , B01J35/0033 , B01J35/10 , B01J37/0036 , B01J37/06 , B01J37/086 , H01M4/9091
Abstract: A sacrificial support-based method, a mechanosynthesis-based method, and a combined sacrificial support/mechanosynthesis support based method that enables the production of supported or unsupported catalytic materials and/or the synthesis of catalytic materials from both soluble and insoluble transition metal and charge transfer salt materials.
Abstract translation: 基于牺牲支持的方法，基于机械合成的方法和基于组合的牺牲支持/机械合成支持的方法，其能够从可溶性和不溶性过渡金属和电荷中产生负载或未负载的催化材料和/或催化材料的合成 转盐材料。
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公开(公告)号：WO2014011831A8
公开(公告)日：2015-02-19
申请号：PCT/US2013050006
申请日：2013-07-11
Applicant: STC UNM , SEROV ALEXEY , ATANASSOV PLAMEN B
Inventor： SEROV ALEXEY , ATANASSOV PLAMEN B
IPC: B01J37/08 , B01J23/745 , C07D235/30
CPC classification number: H01M4/9075 , B01J23/745 , B01J37/084 , C07D235/30 , C07D235/32 , H01M4/90 , H01M4/9041 , H01M2008/1095 , Y02E60/50
Abstract: A method of preparation of M-N-C catalytic material utilizing a sacrificial support approach and using inexpensive and readily available metal precursors and carbendazim (CBDZ) as the carbon source is described.
Abstract translation: 描述了使用牺牲支持方法并使用廉价且容易获得的金属前体和多菌灵（CBDZ）作为碳源制备M-N-C催化材料的方法。
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9.发明申请
公开(公告)号：WO2007001334A3
公开(公告)日：2007-11-29
申请号：PCT/US2005028552
申请日：2005-08-11
Applicant: STC UNM , BREVNOV DMITRI A , OLSON TIM S , LOPEZ GABRIEL P , ATANASSOV PLAMEN B
Inventor： BREVNOV DMITRI A , OLSON TIM S , LOPEZ GABRIEL P , ATANASSOV PLAMEN B
CPC classification number: C25D5/44 , C23C18/1844 , C23C18/54 , C23F1/20 , C25D11/18
Abstract: Method for treating an aluminum alloy surface for electrodeposition or electroless deposition of a metal or alloy on the surface, the surface is oxidized (e.g. anodized) to form aluminum oxide, and then the oxidized surface is chemically etched to render the surface amenable for electrodeposition or electroless deposition of the metal or alloy thereon. A metallic coating can be electrodeposited or electroless deposited on the treated surface.
Abstract translation: 用于处理铝合金表面以在表面上电沉积或无电沉积金属或合金的方法，表面被氧化（例如阳极氧化）以形成氧化铝，然后氧化表面被化学蚀刻以使表面适于电沉积或 在其上无电沉积金属或合金。 金属涂层可以被电沉积或无电沉积在经处理的表面上。
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10.发明公开
公开(公告)号：EP2906347A4
公开(公告)日：2016-05-18
申请号：EP13847996
申请日：2013-10-15
Applicant: STC UNM
Inventor： SEROV ALEXEY , ATANASSOV PLAMEN B , HALEVI BARR , SHORT PAUL
IPC: H01M4/86 , B01J31/18 , H01M4/88 , H01M4/90 , H01M8/1011 , H01M8/1018
CPC classification number: H01M4/9091 , B01J31/1805 , H01M4/8652 , H01M4/8814 , H01M4/8846 , H01M4/8885 , H01M4/9008 , H01M8/1011 , H01M2008/1095 , Y02E60/50 , Y02E60/523
Abstract: Novel catalytic materials and novel methods of preparing M-N—C catalytic materials utilizing a sacrificial support approach and using inexpensive active polymers as the carbon and nitrogen source and readily available metal precursors are described.
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