PROCESS FOR PREPARING LIGHT-COLOURED ISOCYANATES OF THE DIPHENYLMETHANE SERIES
    3.
    发明申请
    PROCESS FOR PREPARING LIGHT-COLOURED ISOCYANATES OF THE DIPHENYLMETHANE SERIES 审中-公开
    制备二苯基甲烷系列浅色异氰酸酯的方法

    公开(公告)号:WO2011006807A3

    公开(公告)日:2011-12-22

    申请号:PCT/EP2010059684

    申请日:2010-07-07

    CPC classification number: C07C263/10 C07C2601/14 C07C265/14

    Abstract: The present invention relates to a process for preparing light-coloured polyphenylene-polymethylene-polyisocyanate (PMDI), comprising the steps (a) providing carbon monoxide and chlorine, (b) reacting carbon monoxide with chlorine to form phosgene, (c) reacting the phosgene from step (b) with at least one primary amine with the exception of mono- and polyphenylene-polymethylene polyamines with an excess of phosgene to form an at least one isocyanate containing reaction solution, and hydrogen chloride, (d) separating excess phosgene from the isocyanate-containing reaction solution obtained in step (c), (e) providing at least one polyphenylene-polymethylene polyamine, and (f) reacting at least a portion of the phosgene separated in step (d) with the at least one polyphenylene-polymethylene polyamine to form the light-coloured polyphenylene-polymethylene polyisocyanate.

    Abstract translation: 包括以下步骤:(a)提供一氧化碳和氯,(b)使一氧化碳与氯反应形成光气,(c)使所述轻质多亚甲基多亚甲基多异氰酸酯(PMDI) (b)的光气与至少一种伯胺反应,不同之处在于单和多亚苯基多亚甲基多胺与过量的光气反应形成至少一种含异氰酸酯的反应溶液和氯化氢,(d)将过量的光气从 (c)中获得的含异氰酸酯的反应溶液,(e)提供至少一种聚亚苯基 - 多亚甲基多胺,和(f)使步骤(d)中分离的至少一部分光气与至少一种聚亚苯基 - 多亚甲基多胺以形成浅色聚亚苯基 - 多亚甲基多异氰酸酯。

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