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Patent Agency Ranking
公开(公告)号：EP0337503A2
公开(公告)日：1989-10-18
申请号：EP89110702.1
申请日：1984-04-30
Applicant: UNION OIL COMPANY OF CALIFORNIA
Inventor： Young, Donald C. , Green II, James A.
Abstract: The invention is directed to compositions for the fumigation of soils, enclosed spaces, agricultural products and other commodities, etc., using compositions which decompose to form carbon disulfide and certain other biocidal materials. Such fumigation can be used to control bacteria, fungi, insects, nematodes, rodents, and weeds.
A composition is provided which is an aqueous solution of ammonium, alkali metal or alkaline earth metal thiocarbonate or a mixture thereof, comprising an added base, the concentration of the added base being sufficient to produce a pH above 7 in the solution: These "thiocarbonates," include, without limitation, salts of trithiocarbonic acid and tetrathiocarbonic acid, compositions having empirical formulae intermediate to these acid salts (such as MCS 3.7 , wherein M is a divalent metal ion), and compositions containing substances in addition to thiocarbonates [such as a stabilized ammonium tetrathiocarbonate which contains ammonium sulfide, i.e. (NH 4 )- 2 CDS 4 (NH 4 ) 2 S].
The compositions are generally water soluble and can be prepared, stored, and used in aqueous solutions. The thiocarbonate solutions of the invention are stable during prolonged periods of storage in a closed container, exhibit a low vapor pressure, and are not flammable. For soil fumigation, thiocarbonates can be mixed with fertilizers to provide a multi-functional application.Abstract translation: 本发明涉及使用分解形成二硫化碳和某些其它杀生物材料的组合物来熏蒸土壤，封闭空间，农产品和其他商品等的组合物。 这种熏蒸可用于控制细菌，真菌，昆虫，线虫，啮齿动物和杂草。 提供了一种组合物，其是铵，碱金属或碱土金属硫代碳酸盐或其混合物的水溶液，其包含加入的碱，添加的碱的浓度足以在溶液中产生高于7的pH。 这些“硫代碳酸酯”包括但不限于三硫代碳酸和四硫代碳酸的盐，具有中间到这些酸盐的经验式的组合物（例如MCS3.7，其中M是二价金属离子），以及含有除了 硫代碳酸盐[如稳定的含硫化铵的四硫代碳酸铵，即（NH4）2CDS4（NH4）2S]。 组合物通常是水溶性的，可以制备，储存并用于水溶液中。 本发明的硫代碳酸盐溶液在密闭容器中长时间储存期间是稳定的，呈现低蒸气压，并且不易燃。 对于土壤熏蒸，硫代碳酸盐可与肥料混合以提供多功能应用。
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公开(公告)号：EP0337503A3
公开(公告)日：1990-05-02
申请号：EP89110702.1
申请日：1984-04-30
Applicant: UNION OIL COMPANY OF CALIFORNIA
Inventor： Young, Donald C. , Green II, James A.
Abstract: The invention is directed to compositions for the fumigation of soils, enclosed spaces, agricultural products and other commodities, etc., using compositions which decompose to form carbon disulfide and certain other biocidal materials. Such fumigation can be used to control bacteria, fungi, insects, nematodes, rodents, and weeds. A composition is provided which is an aqueous solution of ammonium, alkali metal or alkaline earth metal thiocarbonate or a mixture thereof, comprising an added base, the concentration of the added base being sufficient to produce a pH above 7 in the solution: These "thiocarbonates," include, without limitation, salts of trithiocarbonic acid and tetrathiocarbonic acid, compositions having empirical formulae intermediate to these acid salts (such as MCS 3.7 , wherein M is a divalent metal ion), and compositions containing substances in addition to thiocarbonates [such as a stabilized ammonium tetrathiocarbonate which contains ammonium sulfide, i.e. (NH 4 )- 2 CDS 4 (NH 4 ) 2 S]. The compositions are generally water soluble and can be prepared, stored, and used in aqueous solutions. The thiocarbonate solutions of the invention are stable during prolonged periods of storage in a closed container, exhibit a low vapor pressure, and are not flammable. For soil fumigation, thiocarbonates can be mixed with fertilizers to provide a multi-functional application.
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3.发明授权Stabilized thiocarbonate solutions and the use thereof for controlling soil pests 失效稳定Thiokarbonatlösungen及其对土壤害虫控制使用。
公开(公告)号：EP0366226B1
公开(公告)日：1994-09-14
申请号：EP89306901.3
申请日：1989-07-06
Applicant: UNION OIL COMPANY OF CALIFORNIA
Inventor： Young, Donald C. , Green II, James A.
CPC classification number: C05G3/0005 , A01N25/18 , A01N25/22 , A01N59/02 , A01N59/04 , A01N59/06 , C01D13/00 , A01N2300/00
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公开(公告)号：EP0426292A1
公开(公告)日：1991-05-08
申请号：EP90310221.8
申请日：1990-09-18
Applicant: UNION OIL COMPANY OF CALIFORNIA
Inventor： Young, Donald C. , Green II, James A.
CPC classification number: A01N59/02 , A01N25/18 , A01N47/06 , A01N47/14 , A01N59/04 , A01N59/06 , A01N25/10 , A01N2300/00
Abstract: Viscous fumigant compositions comprise carbon disulfide precursors, such as thiocarbonates, xanthates, and dithiocarbamates, that decompose upon application to release carbon disulfide. The compositions exhibit an improved active life when applied, for example, to soil.
Abstract translation: 粘性熏蒸剂组合物包含二硫化碳前体，例如硫代碳酸盐，黄原酸盐和二硫代氨基甲酸盐，其在施用时分解以释放二硫化碳。 例如当施用于土壤时，组合物表现出改善的活性寿命。
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5.发明公开Stabilized thiocarbonate solutions and the use thereof for controlling soil pests 失效StabilisierteThiokarbonatlösungenund deren Verwendung zurBekämpfungvonBodenschädlingen。
公开(公告)号：EP0366226A1
公开(公告)日：1990-05-02
申请号：EP89306901.3
申请日：1989-07-06
Applicant: UNION OIL COMPANY OF CALIFORNIA
Inventor： Young, Donald C. , Green II, James A.
CPC classification number: C05G3/0005 , A01N25/18 , A01N25/22 , A01N59/02 , A01N59/04 , A01N59/06 , C01D13/00 , A01N2300/00
Abstract: Aqueous thiocarbonate solutions are stabilized by the addition of base, sulfide and/or polysulfide and the stability and safety of the more concentrated solutions containing 1 weight percent or more equivalent CS₂ as a thiocarbonate are achieved as reflected by significant reduction of CS₂ partial pressure in such solutions. Such stabilized thiocarbonate solutions are useful for the control of pests in, e.g. soil, and for inhibiting nitrification.
Abstract translation: 通过添加碱，硫化物和/或多硫化物来稳定硫代碳酸酯水溶液，并且通过CS 2分压的显着降低反映出含有1重量％或更多当量硫代碳酸酯的CS 2的更浓缩溶液的稳定性和安全性 解决方案。 这种稳定的硫代碳酸盐溶液可用于控制例如烟草中的害虫。 土壤和抑制硝化作用。
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