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公开(公告)号:WO2013159090A3
公开(公告)日:2014-01-23
申请号:PCT/US2013037574
申请日:2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor: BOOTH KARL A , KORENKIEWICZ STEPHEN M , HARRIS LAURA E , KIPPING ALEXIS R , TAYLOR JEFFREY F
IPC: C09C1/36
CPC classification number: C09D17/008 , B82Y30/00 , C01P2004/62 , C01P2004/64 , C01P2006/22 , C01P2006/62 , C09C1/36 , C09C1/3676 , C09D7/62
Abstract: A pigment grind dispersion of titanium dioxide pigment-polymer composite particles is made by mixing titanium dioxide particles with an aqueous emulsion containing (i) less than a saturation level amount of water-insoluble film-forming first polymer particles that adsorb to the titanium dioxide particles, and (ii) an inhibiting or interfering amount of water-insoluble film-forming second polymer particles that do not adsorb to the titanium dioxide particles, wherein the pigment grind dispersion has a titanium dioxide pigment volume concentration of about 25 to about 50 and a titania composite ratio of about 32 to about 60. The resulting titanium dioxide pigment-polymer composite particles can provide improved coating composition opacity compared to a coating composition that does not contain such composite particles, can employ reduced titanium dioxide amounts and less than a saturation level of the first polymer, and can provide improved storage stability.
Abstract translation: 二氧化钛颜料 - 聚合物复合颗粒的颜料研磨分散体是通过将二氧化钛颗粒与含有(i)小于饱和水平量的吸附于二氧化钛颗粒的不溶于水的成膜的第一聚合物颗粒的水性乳液混合而制备的 ,和(ii)抑制或干扰量的不吸附到二氧化钛颗粒上的水不溶性成膜的第二聚合物颗粒,其中颜料研磨分散体的二氧化钛颜料体积浓度为约25至约50,并且 二氧化钛复合比为约32至约60.与不含这种复合颗粒的涂料组合物相比,所得二氧化钛颜料 - 聚合物复合颗粒可提供改进的涂料组合物不透明度,可以使用还原二氧化钛量并且小于饱和水平 的第一聚合物,并且可以提供改善的储存稳定性。
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公开(公告)号:CA2867904A1
公开(公告)日:2013-10-24
申请号:CA2867904
申请日:2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor: KORENKIEWICZ STEPHEN M , BOOTH KARL A
Abstract: Titanium dioxide may be more efficiently used in a coating composition containing a composite pigment particle-forming polymer if during composite formation, the polymer is initially present in a low concentration and the titanium dioxide particles and newly- formed composite particles are dispersed in a waterborne emulsion polymer that does not form such a composite. A pigment grind dispersion of titanium dioxide pigment-polymer composite particles may be made by mixing titanium dioxide particles with the waterborne emulsion polymer. The composite-forming polymer is then added to the waterborne emulsion polymer, or is added independently and concurrently with the titanium dioxide particles. The resulting titanium dioxide pigment-polymer composite particles provide improved coating composition opacity compared to a coating composition that does not contain such composite particles. The coating compositions can contain reduced titanium dioxide amounts and less than a saturation level of the composite-forming polymer.
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公开(公告)号:NZ589184A
公开(公告)日:2012-01-12
申请号:NZ58918409
申请日:2009-06-16
Applicant: VALSPAR SOURCING INC
Inventor: KORENKIEWICZ STEPHEN M , COWARD MARK R , LEE DAVID Y
Abstract: A retail point of sale expanded color space white-pigmented paint and non-pigmented stain custom tinting dispenser system with an automated colorant or pigment dye dispenser having a minimum liquid dispensing quantity less than 0.01 fluid ounce or 0.3 cm3 typically less than 0.005 fluid ounce or 0.15 cm3. No more than twelve colorants are used, typically ten or less. The colorants used include white; black; yellow hued; green-hued colorant having a colour strength greater than 12 wt. % PG7 pigment and typically 20-48% PG7 pigment; blue-hued colorant containing at least 7 wt. % PB 15:2 pigment and typically 12-28% PB15:2 pigment; and red-hued colorant at least containing 17 wt. % PR209 pigment and typically 29-68% PR209 pigment.
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公开(公告)号:CA2785785A1
公开(公告)日:2011-07-14
申请号:CA2785785
申请日:2010-01-11
Applicant: VALSPAR SOURCING INC
Inventor: KORENKIEWICZ STEPHEN M , CORNELL WILLARD REID
Abstract: Custom-tinted paints and stains are made using an array of low VOC concentrated liquid colorants including at least at least white colorant; black colorant; and green-hued, blue- hued and red-hued primary colorants at least one of which primary colorants comprises polyalkylene glycol humectant, ethoxylated surfactant and extender pigment. For colorants in the array containing polyalkylene glycol humectant, the humectant and ethoxylated surfactant amounts are sufficiently high and extender pigment amount is sufficiently low so that the colorants will not problematically plug colorant dispenser orifices if left in the dispenser without an orifice cap for a full day. The polyalkylene glycol humectant is also present in an amount sufficiently low so that dried paint films made by mixing the colorants with a clear waterborne base paint will resist blocking.
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公开(公告)号:CA2984150C
公开(公告)日:2020-04-28
申请号:CA2984150
申请日:2016-04-25
Applicant: VALSPAR SOURCING INC
Inventor: HU RONGHAI , DUAN GANG , XIONG RONG , KORENKIEWICZ STEPHEN M , KOU HUI
IPC: C09D7/40 , C09D5/16 , C09D133/00
Abstract: The present disclosure refers to an aqueous stain resistant coating composition, comprising, one or more aqueous dispersions of self-crosslinkable polymeric particles; and one or more particulate solids, wherein the polymeric particles have a Tg of 10°C or less; and wherein the particulate solids comprise a combination of sheet-like particulate solids and sphere-like particulate solids in a weight ratio of 1 : 1 or more; and wherein the coating composition has a pigment volume concentration of 45% or more; and the coating composition is substantially free of volatile organic compounds.
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公开(公告)号:CA2723971C
公开(公告)日:2016-09-06
申请号:CA2723971
申请日:2009-06-16
Applicant: VALSPAR SOURCING INC
Inventor: KORENKIEWICZ STEPHEN M , COWARD MARK R , LEE DAVID Y
Abstract: White-pigmented and unpigmented base paints and stains are custom-tinted using an automated colorant dispenser having a minimum fluid dispensing quantity less than 0.01 fluid ounce (
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公开(公告)号:CA2723971A1
公开(公告)日:2009-12-23
申请号:CA2723971
申请日:2009-06-16
Applicant: VALSPAR SOURCING INC
Inventor: KORENKIEWICZ STEPHEN M , COWARD MARK R , LEE DAVID Y
Abstract: White-pigmented and unpigmented base paints and stains are custom-tinted using an automated colorant dispenser having a minimum fluid dispensing quantity less than 0.01 fluid ounce (
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公开(公告)号:CA2601856A1
公开(公告)日:2006-09-28
申请号:CA2601856
申请日:2006-03-17
Applicant: VALSPAR SOURCING INC
Inventor: KORENKIEWICZ STEPHEN M , WALLACE DAVID R , COWARD MARK R
Abstract: A universal colorant system for both solvent- and water-based paints and coatings is contained in a closed sealed pouch or cartridge-style container, and includes a colorant component, a surfactant package including at least one alkyd-compatible surfactant and at least one latex-compatible surfactant, and a carrier. When the colorant system is added to a base paint it desirably provides a mixture having a drop in viscosity of less than about 50%.
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公开(公告)号:CA2867904C
公开(公告)日:2020-04-14
申请号:CA2867904
申请日:2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor: KORENKIEWICZ STEPHEN M , BOOTH KARL A
Abstract: Titanium dioxide may be more efficiently used in a coating composition containing a composite pigment particle-forming polymer if during composite formation, the polymer is initially present in a low concentration and the titanium dioxide particles and newly- formed composite particles are dispersed in a waterborne emulsion polymer that does not form such a composite. A pigment grind dispersion of titanium dioxide pigment-polymer composite particles may be made by mixing titanium dioxide particles with the waterborne emulsion polymer. The composite-forming polymer is then added to the waterborne emulsion polymer, or is added independently and concurrently with the titanium dioxide particles. The resulting titanium dioxide pigment-polymer composite particles provide improved coating composition opacity compared to a coating composition that does not contain such composite particles. The coating compositions can contain reduced titanium dioxide amounts and less than a saturation level of the composite-forming polymer.
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公开(公告)号:CA2984150A1
公开(公告)日:2016-11-03
申请号:CA2984150
申请日:2016-04-25
Applicant: VALSPAR SOURCING INC
Inventor: HU RONGHAI , DUAN GANG , XIONG RONG , KORENKIEWICZ STEPHEN M , KOU HUI
IPC: C09D4/02 , C09D5/00 , C09D5/16 , C09D109/00
Abstract: The present disclosure refers to an aqueous stain resistant coating composition, comprising, one or more aqueous dispersions of self-crosslinkable polymeric particles; and one or more particulate solids, wherein the polymeric particles have a Tg of 10°C or less; and wherein the particulate solids comprise a combination of sheet-like particulate solids and sphere-like particulate solids in a weight ratio of 1 : 1 or more; and wherein the coating composition has a pigment volume concentration of 45% or more; and the coating composition is substantially free of volatile organic compounds.
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