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公开(公告)号：WO2013159090A3
公开(公告)日：2014-01-23
申请号：PCT/US2013037574
申请日：2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor： BOOTH KARL A , KORENKIEWICZ STEPHEN M , HARRIS LAURA E , KIPPING ALEXIS R , TAYLOR JEFFREY F
IPC: C09C1/36
CPC classification number: C09D17/008 , B82Y30/00 , C01P2004/62 , C01P2004/64 , C01P2006/22 , C01P2006/62 , C09C1/36 , C09C1/3676 , C09D7/62
Abstract: A pigment grind dispersion of titanium dioxide pigment-polymer composite particles is made by mixing titanium dioxide particles with an aqueous emulsion containing (i) less than a saturation level amount of water-insoluble film-forming first polymer particles that adsorb to the titanium dioxide particles, and (ii) an inhibiting or interfering amount of water-insoluble film-forming second polymer particles that do not adsorb to the titanium dioxide particles, wherein the pigment grind dispersion has a titanium dioxide pigment volume concentration of about 25 to about 50 and a titania composite ratio of about 32 to about 60. The resulting titanium dioxide pigment-polymer composite particles can provide improved coating composition opacity compared to a coating composition that does not contain such composite particles, can employ reduced titanium dioxide amounts and less than a saturation level of the first polymer, and can provide improved storage stability.
Abstract translation: 二氧化钛颜料 - 聚合物复合颗粒的颜料研磨分散体是通过将二氧化钛颗粒与含有（i）小于饱和水平量的吸附于二氧化钛颗粒的不溶于水的成膜的第一聚合物颗粒的水性乳液混合而制备的 ，和（ii）抑制或干扰量的不吸附到二氧化钛颗粒上的水不溶性成膜的第二聚合物颗粒，其中颜料研磨分散体的二氧化钛颜料体积浓度为约25至约50，并且 二氧化钛复合比为约32至约60.与不含这种复合颗粒的涂料组合物相比，所得二氧化钛颜料 - 聚合物复合颗粒可提供改进的涂料组合物不透明度，可以使用还原二氧化钛量并且小于饱和水平 的第一聚合物，并且可以提供改善的储存稳定性。
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公开(公告)号：CA2867904A1
公开(公告)日：2013-10-24
申请号：CA2867904
申请日：2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor： KORENKIEWICZ STEPHEN M , BOOTH KARL A
Abstract: Titanium dioxide may be more efficiently used in a coating composition containing a composite pigment particle-forming polymer if during composite formation, the polymer is initially present in a low concentration and the titanium dioxide particles and newly- formed composite particles are dispersed in a waterborne emulsion polymer that does not form such a composite. A pigment grind dispersion of titanium dioxide pigment-polymer composite particles may be made by mixing titanium dioxide particles with the waterborne emulsion polymer. The composite-forming polymer is then added to the waterborne emulsion polymer, or is added independently and concurrently with the titanium dioxide particles. The resulting titanium dioxide pigment-polymer composite particles provide improved coating composition opacity compared to a coating composition that does not contain such composite particles. The coating compositions can contain reduced titanium dioxide amounts and less than a saturation level of the composite-forming polymer.
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公开(公告)号：CA2867164C
公开(公告)日：2020-04-14
申请号：CA2867164
申请日：2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor： BOOTH KARL A , KORENKIEWICZ STEPHEN M , HARRIS LAURA E , KIPPING ALEXIS R , TAYLOR JEFFREY F
IPC: C09C1/36
Abstract: A pigment grind dispersion of titanium dioxide pigment-polymer composite particles is made by mixing titanium dioxide particles with an aqueous emulsion containing (i) less than a saturation level amount of water-insoluble film-forming first polymer particles that adsorb to the titanium dioxide particles, and (ii) an inhibiting or interfering amount of water-insoluble film-forming second polymer particles that do not adsorb to the titanium dioxide particles, wherein the pigment grind dispersion has a titanium dioxide pigment volume concentration of about 25 to about 50 and a titania composite ratio of about 32 to about 60. The resulting titanium dioxide pigment-polymer composite particles can provide improved coating composition opacity compared to a coating composition that does not contain such composite particles, can employ reduced titanium dioxide amounts and less than a saturation level of the first polymer, and can provide improved storage stability.
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公开(公告)号：AU2013248980A1
公开(公告)日：2014-10-02
申请号：AU2013248980
申请日：2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor： BOOTH KARL A , KORENKIEWICZ STEPHEN M , HARRIS LAURA E , KIPPING ALEXIS R , TAYLOR JEFFREY F
IPC: C09C1/36
Abstract: A pigment grind dispersion of titanium dioxide pigment-polymer composite particles is made by mixing titanium dioxide particles with an aqueous emulsion containing (i) less than a saturation level amount of water-insoluble film-forming first polymer particles that adsorb to the titanium dioxide particles, and (ii) an inhibiting or interfering amount of water-insoluble film-forming second polymer particles that do not adsorb to the titanium dioxide particles, wherein the pigment grind dispersion has a titanium dioxide pigment volume concentration of about 25 to about 50 and a titania composite ratio of about 32 to about 60. The resulting titanium dioxide pigment-polymer composite particles can provide improved coating composition opacity compared to a coating composition that does not contain such composite particles, can employ reduced titanium dioxide amounts and less than a saturation level of the first polymer, and can provide improved storage stability.
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Patent Agency Ranking
公开(公告)号：CA2867904C
公开(公告)日：2020-04-14
申请号：CA2867904
申请日：2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor： KORENKIEWICZ STEPHEN M , BOOTH KARL A
Abstract: Titanium dioxide may be more efficiently used in a coating composition containing a composite pigment particle-forming polymer if during composite formation, the polymer is initially present in a low concentration and the titanium dioxide particles and newly- formed composite particles are dispersed in a waterborne emulsion polymer that does not form such a composite. A pigment grind dispersion of titanium dioxide pigment-polymer composite particles may be made by mixing titanium dioxide particles with the waterborne emulsion polymer. The composite-forming polymer is then added to the waterborne emulsion polymer, or is added independently and concurrently with the titanium dioxide particles. The resulting titanium dioxide pigment-polymer composite particles provide improved coating composition opacity compared to a coating composition that does not contain such composite particles. The coating compositions can contain reduced titanium dioxide amounts and less than a saturation level of the composite-forming polymer.
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公开(公告)号：AU2013248988A1
公开(公告)日：2014-10-09
申请号：AU2013248988
申请日：2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor： KORENKIEWICZ STEPHEN M , BOOTH KARL A
Abstract: Titanium dioxide may be more efficiently used in a coating composition containing a composite pigment particle-forming polymer if during composite formation, the polymer is initially present in a low concentration and the titanium dioxide particles and newly- formed composite particles are dispersed in a waterborne emulsion polymer that does not form such a composite. A pigment grind dispersion of titanium dioxide pigment-polymer composite particles may be made by mixing titanium dioxide particles with the waterborne emulsion polymer. The composite-forming polymer is then added to the waterborne emulsion polymer, or is added independently and concurrently with the titanium dioxide particles. The resulting titanium dioxide pigment-polymer composite particles provide improved coating composition opacity compared to a coating composition that does not contain such composite particles. The coating compositions can contain reduced titanium dioxide amounts and less than a saturation level of the composite-forming polymer.
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公开(公告)号：CA2968012A1
公开(公告)日：2016-06-23
申请号：CA2968012
申请日：2015-12-18
Applicant: VALSPAR SOURCING INC
Inventor： BOOTH KARL A , CZAPLEWSKI KENNETH F , KORENKIEWICZ STEPHEN M , TAYLOR JEFFREY F
IPC: C08L75/04 , C09D7/00 , C09D7/47 , C09D175/08
Abstract: A coating composition including a rheology modifier is described. The rheology modifier is a water-soluble polyurethane made by the condensation of a poly(alkylene glycol), a polyisocyanate and a compound including a polyalkoxylated chain and a hydrophobic end group. The composition demonstrates Leneta sag resistance of greater than about 14 and a Leneta flow and leveling of at least about 9, and a Stormer viscosity of less than about 120 Krebs units.
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公开(公告)号：CA2867164A1
公开(公告)日：2013-10-24
申请号：CA2867164
申请日：2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor： BOOTH KARL A , KORENKIEWICZ STEPHEN M , HARRIS LAURA E , KIPPING ALEXIS R , TAYLOR JEFFREY F
IPC: C09C1/36
Abstract: A pigment grind dispersion of titanium dioxide pigment-polymer composite particles is made by mixing titanium dioxide particles with an aqueous emulsion containing (i) less than a saturation level amount of water-insoluble film-forming first polymer particles that adsorb to the titanium dioxide particles, and (ii) an inhibiting or interfering amount of water-insoluble film-forming second polymer particles that do not adsorb to the titanium dioxide particles, wherein the pigment grind dispersion has a titanium dioxide pigment volume concentration of about 25 to about 50 and a titania composite ratio of about 32 to about 60. The resulting titanium dioxide pigment-polymer composite particles can provide improved coating composition opacity compared to a coating composition that does not contain such composite particles, can employ reduced titanium dioxide amounts and less than a saturation level of the first polymer, and can provide improved storage stability.
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9.发明公开
公开(公告)号：EP2838959A4
公开(公告)日：2016-01-20
申请号：EP13778819
申请日：2013-04-22
Applicant: VALSPAR SOURCING INC
Inventor： KORENKIEWICZ STEPHEN M , BOOTH KARL A
CPC classification number: C09D133/08 , C01P2006/22 , C01P2006/62 , C08K3/22 , C08K9/08 , C08K2003/2237 , C08K2003/2241 , C09C1/3676 , C09C3/10 , C09D7/62 , C09D7/80 , C09D133/06
Abstract: Titanium dioxide may be more efficiently used in a coating composition containing a composite pigment particle-forming polymer if during composite formation, the polymer is initially present in a low concentration and the titanium dioxide particles and newly-formed composite particles are dispersed in a waterborne emulsion polymer that does not form such a composite. A pigment grind dispersion of titanium dioxide pigment-polymer composite particles may be made by mixing titanium dioxide particles with the waterborne emulsion polymer. The composite-forming polymer is then added to the waterborne emulsion polymer, or is added independently and concurrently with the titanium dioxide particles. The resulting titanium dioxide pigment-polymer composite particles provide improved coating composition opacity compared to a coating composition that does not contain such composite particles. The coating compositions can contain reduced titanium dioxide amounts and less than a saturation level of the composite-forming polymer.
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