Process for making a two layer thermal negative plate
    93.
    发明申请
    Process for making a two layer thermal negative plate 失效
    制造双层热负极板的工艺

    公开(公告)号:US20030118949A1

    公开(公告)日:2003-06-26

    申请号:US10016173

    申请日:2001-12-13

    Abstract: A negative-working image forming process which comprises the steps of: (1) flood exposing with actinic radiation a photosensitive assembly that comprises: (a) a hydrophilic support which can be used as a lithographic base and having thereon; (b) a first layer comprising: (i) at least one polymer that is soluble or dispersible in an aqueous alkaline solution; (c) a second layer on top of the first layer, the second layer comprising at least one o-quinonediazide compound; whereby the flood exposure causes the at least one o-quinonediazide compound to be converted to the corresponding indenecarboxylic acid compound; and (d) at least one photothermal conversion material in either the first layer or the second layer or both; (2) imagewise exposing the flood exposed photosensitive assembly with infrared radiation to thereby convert the indenecarboxylic acid compound in the second layer in the imagewise exposed areas to the corresponding indene compound; and (3) developing the imagewise exposed photosensitive assembly with an alkaline developing solution to dissolve out the imagewise unexposed areas of the second layer and the areas of the first layer underlying the imagewise unexposed areas of the second layer and thereby produce a negative working image.

    Abstract translation: 一种负型图像形成方法,其包括以下步骤:(1)用光化辐射曝光光敏组件,其包含:(a)可用作平版印刷基底并具有其上的亲水载体; (b)第一层,其包含:(i)至少一种可溶于或可分散在碱性水溶液中的聚合物; (c)在第一层顶部的第二层,第二层包含至少一种邻醌二叠氮化合物; 由此泛滥暴露导致至少一种邻醌二叠氮化合物转化为相应的茚羧酸化合物; 和(d)在第一层或第二层或两者中的至少一种光热转换材料; (2)用红外辐射成像地暴露暴露的感光组件,从而将图像曝光区域中的第二层中的茚酸羧酸化合物转化成相应的茚化合物; 和(3)用碱性显影液显影图像曝光的感光组件,以溶解第二层的成像未曝光区域和第二层的成像未曝光区域下方的第一层的区域,从而产生负作用图像。

    High speed negative working thermal printing plates
    94.
    发明申请
    High speed negative working thermal printing plates 审中-公开
    高速负片热敏印版

    公开(公告)号:US20030118939A1

    公开(公告)日:2003-06-26

    申请号:US10040241

    申请日:2001-11-09

    Abstract: The present invention provides an IR-sensitive composition, which includes: a polymeric binder; and a free radical polymerizable system consisting of: at least one component selected from unsaturated free radical polymerizable monomers, oligomers which are free radical polymerizable and polymers containing CnullC bonds in the backbone and/or in the side chain groups; and an initiator system, which includes: (a) at least one compound capable of absorbing IR radiation; (b) at least one compound capable of producing radicals; and (c) at least one carboxylic co-initiator, provided that the total acid number of the polymeric binder is 70 mg KOH/g or less. The present invention further provides a printing plate precursor, a process for preparing the printing plate and a method of producing an image.

    Abstract translation: 本发明提供了一种IR敏感组合物,其包括:聚合物粘合剂; 和由以下组成的自由基可聚合体系:至少一种选自不饱和自由基可聚合单体的组分,可自由基聚合的低聚物和在主链和/或侧链基团中含有C = C键的聚合物; 和引发剂体系,其包括:(a)至少一种能够吸收IR辐射的化合物; (b)至少一种能够产生自由基的化合物; 和(c)至少一种羧酸共引发剂,条件是聚合物粘合剂的总酸值为70mg KOH / g或更低。 本发明还提供一种印版前体,一种制备印版的方法和一种制作图象的方法。

    Photosensitive compositions having mixtures of alkoxy and non-alkoxy diazonium salt containing compounds

    公开(公告)号:US20030013035A1

    公开(公告)日:2003-01-16

    申请号:US09904205

    申请日:2001-07-12

    CPC classification number: G03F7/016 G03F7/021 G03F7/0215 G03F7/0217

    Abstract: The present invention includes an imageable element, which can be: (a) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; a polyvinyl acetal binder; and a sheet substrate; or (b) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; and a sheet substrate. The imaging layer includes a total aromatic diazonium salt containing compound content of at least 10 weight percent. The molar ratio of the aromatic diazonium salt containing compound having an alkoxy substituent to the aromatic diazonium salt containing compound that is free of an alkoxy substituent is from about 1.0:1 to 70:1. Upon imagewise exposure and development, an imaged element is obtained, which is mounted on a dry printing press containing lithographic ink and used to produce printed stock.

    Substrate improvements for thermally imageable composition and methods of preparation
    96.
    发明申请
    Substrate improvements for thermally imageable composition and methods of preparation 失效
    可热成像组合物的基材改进和制备方法

    公开(公告)号:US20020172888A1

    公开(公告)日:2002-11-21

    申请号:US09826315

    申请日:2001-04-04

    Abstract: The present invention includes a radiation-imageable element for lithographic printing having a hydrophilic anodized aluminum base with a surface having pores and a image-forming layer having polymer particles coated on the aluminum base. The ratio of the average pore diameter to the average particle diameter is from 0.4:1 to 10:1. The present invention further includes a method of producing the imaged element. The method includes the steps of imagewise exposing the radiation-imageable element to radiation to produce exposed and unexposed regions and contacting the imagewise exposed radiation-imageable element and a developer to remove the exposed or the unexposed regions.

    Abstract translation: 本发明包括用于平版印刷的可辐射成像元件,其具有具有孔的表面的亲水阳极化铝基底和具有涂覆在铝基底上的聚合物颗粒的图像形成层。 平均孔径与平均粒径之比为0.4:1〜10:1。 本发明还包括一种制造成像元件的方法。 该方法包括以下步骤:将可辐射成像元件成像曝光到辐射以产生曝光和未曝光区域,并使图像曝光的可辐射成像元件和显影剂接触以去除曝光或未曝光区域。

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