98.
    发明专利
    未知

    公开(公告)号:DE3638489A1

    公开(公告)日:1988-05-19

    申请号:DE3638489

    申请日:1986-11-11

    Applicant: BASF AG

    Abstract: Vinylglyoxal derivatives of the general formula I (I) where R is straight-chain or branched alkyl or alkenyl, cycloalkyl or unsubstituted or substituted phenyl, are prepared by a process in which bicyclo[2.2.1]hept-5-enecarbaldehyde of the formula V (V) is either (a) subjected to autocondensation with formation of a compound of the formula VII (VII) or (b) reacted with a compound of the general formula II R-CH=O (II) where R has the above meanings, with formation of a mixture of the compounds of the general formulae VIII (a) and (b) (VIIIa) (VIIIb) where R is as defined above, in the presence of a catalyst, and the compound of the formula VII or the compounds of the formulae VIII (a) and (b) is or are oxidized to the corresponding dicarbonyl compounds, after which gas-phase pyrolysis is carried out at from 500 DEG to 700 DEG C. and under reduced pressure, in particular less than 10-1 mbar, and, if desired, the resulting compound of the general formula I is further purified. These compounds can be used, for example, as monomer components in polymeric systems.

    99.
    发明专利
    未知

    公开(公告)号:DE3619606A1

    公开(公告)日:1987-12-17

    申请号:DE3619606

    申请日:1986-06-11

    Applicant: BASF AG

    Abstract: Production of an electrically conductive surface layer on moulded articles consisting of plastics which are soluble or can be swelled in organic solvents, the conductivity of which surface layer is based on a system embedded therein of… - organic electron acceptors (I) on the one hand and… - organic electron donors (II), iodides (III) or mixtures of (II) and (III) as electron donors on the other hand,… in that the moulded articles are treated with organic solutions of these components. … The products of the process have a surface resistance between 10 and 10 ohms and have the advantage that the other characteristics of the moulded articles are virtually uninfluenced by the means (I) to (III).

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