New di:alkynyl malonate cpds. and polymers for photochromic materials - prepd. by reacting malonyl di:chloride with unsatd. alcohol pref. prop-2-yn-ol and knoevenagel condensation

    公开(公告)号:DE4109262A1

    公开(公告)日:1991-10-02

    申请号:DE4109262

    申请日:1991-03-21

    Applicant: BASF AG

    Abstract: New dialkynyl malonate derivs (I); and new unsatd polymers (II) are claimed. A = organic gp contg aromatic ring(s), which intrinsically (A1) cannot form liq crystalline (LC) phases and/or (A1) has nonlinear optical properties and/or (A3) has photochromic properties or which (A4) can form calamitic LC and/or (A5) discotic LC phase(s) or which (A6) can form calamitic LC and/or discotic LC phase(s) and also has nonlinear optical and/or photochromic properties; n = an integer from 1 to 6; B = a bifunctional -X-(Y)m-X- gp; X = -MRR1- or -M1-R- with M = Si, Ge or Sn, M1 = B, Al or P and R and R1 independently = alkyl(aryl) or (alkyl)-cycloalkyl; Y = a bifunctional organic or organometallic, low mol, oligomeric or polymeric linking gp, 0 or S, which has a metal-metal bond if m = 0 and M = Si, Ge or Sn or a polycentred bond if m = 0 and M1 = B or Al; m = 0 or 1. (I) are prepd by reacting malonyl dichloride with the relevant unsatd alcohol, esp prop-2-yn-l-ol, and Knoevenagel condensation with suitable low mol cpds, using piperidine acetate as catalyst. (II) are prepd (claimed) by reacting (I) and cpd(s) having negatively polarised H atoms of formula H-X-(Y)m-X-H (III). USE/ADVANTAGE - (I) are claimed for use as starting materials for (II); and both (I) and (II) are claimed for producing materials and equipment with photochromic, LC and/or nonlinear optical properties, which are claimed for use in holography, laser optical data recording, reprography, nonlinear optics and information displays. (I) and (II) can be prepd easily.

    4.
    发明专利
    未知

    公开(公告)号:DE3585248D1

    公开(公告)日:1992-03-05

    申请号:DE3585248

    申请日:1985-08-12

    Applicant: BASF AG

    Abstract: Polymers contg. mesogenic gps. are made up of polymer chairs contg. mesogenic gps., to which are bound side chains which each contain a mesogenic gp.. Pref. the mesogenic gps. in the polymer chain are bonded together via aliphatic or araliphatic gps. contg. hetero atoms in the chain, or by aromatic gps., and the side chains contg. mesogenic gps. are bound to the aliphatic, araliphatic or aromatic gps. in the polymer chain or to the mesogenic gps. in the polymer chain, pref. where the mesogenic gps. in the side chains are each bound to the polymer chain via an aliphatic gp. with hetero atoms in the chain with up to 12 chain members.

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