公开(公告)号：DE502006005122D1

公开(公告)日：2009-11-26

申请号：DE502006005122

申请日：2006-06-01

Applicant: BASF SE

Inventor： SCHNEIDER JOERG ,  SCHERR GUENTER ,  ERHARDT RAINER ,  EICHFELDER ANDREAS ,  REIF MARTIN ,  HIRSCH STEFAN ,  SIEDER GEORG ,  HOLTMANN THOMAS ,  CIPRIAN JUERGEN ,  ASCHERL HERMANN

IPC: C07D251/70

Abstract: The invention relates to a process for removing salts from an alkanolic reaction mixture which is obtained in the preparation of alkoxycarbonylaminotriazines and comprises at least one alkoxycarbonylaminotriazine, at least one cyclic and/or acyclic carbonic ester, at least one C 1 -C 13 -alkanol which optionally comprises one or two oxygen atoms as ether bonds and is optionally substituted by C 1 -C 4 -alkyl and/or hydroxyl, and also at least one alkali metal alkoxide or alkaline earth metal alkoxide, with or without melamine and with or without catalyst, in which salts are removed from the reaction mixture by ion exchange over a cation exchanger and/or anion exchanger.

公开(公告)号：ES2890939T3

公开(公告)日：2022-01-25

申请号：ES18758898

申请日：2018-08-30

Applicant: BASF SE ,  EXXONMOBIL RES & ENG CO

Inventor： ERNST MARTIN ,  VORBERG GERALD ,  INGRAM THOMAS ,  SIEDER GEORG ,  PEREIRA CARLA

IPC: B01D53/14

Abstract: Un proceso para la remoción selectiva de sulfuro de hidrógeno sobre dióxido de carbono de una corriente de fluido que comprende dióxido de carbono y sulfuro de hidrógeno, en que la corriente de fluido hace contacto con un absorbente, cuyo absorbente contiene una solución acuosa, que comprende una amina de fórmula (I) y opcionalmente una amina de fórmula (II) **(Ver fórmula)* en donde U-V-W es CH-O-CHR5, N-CO-CHR5 o N-CO-NR5; U'-V'-W' es C-O-CR5; R1 es independientemente alquilo de C1-C5; R2 se selecciona de hidrógeno y alquilo de C1-C5; R3 se selecciona independientemente de hidrógeno y alquilo de C1-C5; R4 se selecciona independientemente de hidrógeno y alquilo de C1-C5; R5 se selecciona de hidrógeno, alquilo de C1-C5, alquilo de C1-C5 (alcoxi de C1-C5), y alquilo de hidroxi-C1-C5; y x es un entero de 1 a 10, en donde el absorbente comprende una cantidad total de 15 % a 70 % en peso de la amina de fórmula (I) y (II), con base en el peso total del absorbente, en donde se obtienen un absorbente de carga y una corriente de fluido tratado.

公开(公告)号：EA036848B1

公开(公告)日：2020-12-28

申请号：EA201890823

申请日：2016-09-07

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  SIEDER GEORG ,  KATZ TORSTEN ,  VORBERG GERALD ,  NOTZ RALF

IPC: B01D53/14 ,  C10L3/10

Abstract: Изобретениекасаетсяспособаселективногоудалениясероводородапоотношениюк диоксидууглеродаизпотокатекучейсреды, прикоторомпотоктекучейсредыобъединяютв абсорберес абсорбентом, которыйсодержитаминформулы (I)где R5 выбраниз NR6R7 и OR10; R6 выбранизводорода, C1-C5-алкилаи C2-C5-гидроксиалкила, R7 выбраниз C1-C5-алкилаи C2-C5-гидроксиалкилаи R10 выбранизводорода, C1-C5-алкилаи C2-C5-гидроксиалкила; причемполучаюточищенныйпотоктекучейсредыи насыщенныйабсорбент; причемТакженастоящееизобретениекасаетсяпримененияуказанногоаминаформулы (I) дляселективногоудалениясероводородапоотношениюк диоксидууглеродаизпотокатекучейсредыи абсорбентадляселективногоудалениясероводородаизпотокатекучейсреды, содержащегодиоксидуглеродаи сероводород.

公开(公告)号：CA3130537A1

公开(公告)日：2020-08-27

申请号：CA3130537

申请日：2020-02-14

Applicant: BASF SE

Inventor： ERNST MARTIN ,  INGRAM THOMAS ,  VORBERG GERALD ,  SIEDER GEORG

IPC: B01D53/14 ,  C10L3/10

Abstract: A process for removal of acid gases from fluid stream, wherein the fluid stream is brought into contact with an absorbent to obtain a treated fluid stream and a laden absorbent, the absorbent comprising a diluent and a compound of the general formula (I) wherein R1 is selected from C1-C8-alkyl and C2-C8-hydroxyalkyl; R2 is selected from hydrogen and C1-C8-alkyl; R3 is selected from hydrogen and C1-C8-alkyl; R4 is selected from hydrogen and C1-C8-alkyl; R5 is C1-C8-alkyl; with the proviso that at least one of the following conditions (i) and (ii) is met: (i) R5 is C3-C8-alkyl bound to the nitrogen atom via a secondary or tertiary carbon atom; (ii) when R4 is hydrogen, R3 is C1-C8-alkyl; or when R4 is C1-C8-alkyl, at least one of R2 and R3 is C1-C8-alkyl; and n is an integer from 0 to 6. Further provided is an absorbent for the absorption of acid gases from a fluid stream, comprising a diluent and a compound of the general formula (I) as defined above, as well as the use of a compound of the general formula (I) as defined above for removal of acid gases from a fluid stream. The absorbents are useful for the selective removal of hydrogen sulfide from fluid streams and have high acid gas loading capacity, high stability, and low volatility.

公开(公告)号：AU2015309015B2

公开(公告)日：2019-12-19

申请号：AU2015309015

申请日：2015-08-20

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  NOTZ RALF ,  VORBERG GERALD ,  SIEDER GEORG

IPC: B01D53/14

Abstract: The invention relates to a method for removing hydrogen sulphide and carbon dioxide from a stream of fluid, the method comprising: a) an absorption step, in which the stream of fluid is brought into contact with an absorption agent comprising an aqueous solution (i) of an amine of general formula (I), where R

公开(公告)号：ES2690087T3

公开(公告)日：2018-11-19

申请号：ES13706012

申请日：2013-02-26

Applicant: BASF SE

Inventor： KATZ TORSTEN ,  RIEMANN CHRISTIAN ,  SIEDER GEORG

IPC: B01D53/14

Abstract: Un proceso para eliminar gases ácidos de una corriente de fluido que contiene vapor de agua, cuyos gases ácidos comprenden al menos CO2, el proceso que comprende a) proporcionar un líquido de absorción que no es completamente miscible con agua, líquido de absorción que comprende una base nitrogenada y un ácido débil; b) tratar la corriente de fluido en una zona de absorción con el líquido de absorción para obtener una corriente de fluido tratada empobrecida en gas ácido y un líquido de absorción cargado con gas ácido; c) dirigir la corriente de fluido tratada a una zona de rehidratación y tratar la corriente de fluido con un líquido acuoso para volatilizar al menos parte del líquido acuoso; d) regenerar el líquido de absorción cargado para expulsar los gases ácidos al menos en parte y obtener un líquido de absorción regenerado, y dirigir el líquido de absorción regenerado a la etapa b); y e) separar, del líquido de absorción, un líquido acuoso que se ha condensado en la zona de absorción, y dirigir el líquido acuoso a la etapa c), donde separar el líquido acuoso comprende someter el líquido de absorción cargado a separación de fase líquido-líquido para separar el líquido acuoso del mismo.

公开(公告)号：CA2761895C

公开(公告)日：2018-08-28

申请号：CA2761895

申请日：2010-05-25

Applicant: BASF SE ,  JGC CORP

Inventor： KATZ TORSTEN ,  SIEDER GEORG ,  TANAKA KOJI

IPC: C10K1/08 ,  C01B32/50

Abstract: A process for removing carbon dioxide from a fluid comprising the steps of: treating the fluid by contacting it with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone depressurizing the absorbent (3 to 1 bar (absolute)) to release a first stream of CO2 and yield a partially regenerated absorbent; which is recycled in a first stream into the first absorption zone; heating (at 3.5 to 10 bar (absolute))a second stream of the partially regenerated absorbent to release a second stream of CO2 and yield a regenerated absorbent; which is recycled into the second absorption zone; condensing water vapour entrained in the second stream of CO2 by cooling the second stream of CO2 and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange; and introducing the second stream of CO2 into a CO2 pressurizing unit.

公开(公告)号：AU2016333399A1

公开(公告)日：2018-03-29

申请号：AU2016333399

申请日：2016-09-14

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  SIEDER GEORG ,  PREIBISCH IMKE

IPC: B01D53/14 ,  C10L3/10

Abstract: The invention relates to an absorption agent for selectively removing hydrogen sulphide from a fluid flow containing carbon dioxide and hydrogen sulphide, containing a) 10 to 70 wt.% of at least one sterically-hindered secondary amine that has at least one ether group and/or at least one hydroxyl group in the molecule; b) at least one non-aqueous solvent that has at least two functional groups, selected from ether groups and hydroxyl groups, in the molecule, and c) a cosolvent where appropriate; wherein the hydroxyl group density of the absorption agent ρ

公开(公告)号：AU2016330648A1

公开(公告)日：2018-03-29

申请号：AU2016330648

申请日：2016-09-26

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  SIEDER GEORG

IPC: B01D53/14 ,  C10L3/10

Abstract: An absorbent for the selective removal of hydrogen sulfide from a fluid stream containing carbon dioxide and hydrogen sulfide contains: a) an amine compound of formula (I), where X, R

公开(公告)号：CA3007965A1

公开(公告)日：2017-06-15

申请号：CA3007965

申请日：2016-12-07

Applicant: BASF SE

Inventor： INGRAM THOMAS ,  VORBERG GERALD ,  SIEDER GEORG

IPC: B01D53/14 ,  B01D53/86 ,  C01B17/04 ,  C10L3/10

Abstract: The invention relates to a method for treating an H2S and CO2-containing fluid flow, wherein a) the fluid flow is treated with a first sub-flow (3.01) of a regenerated H2S-selective absorbent in a first absorber (A1) at a pressure of 10 to 150 bar, and a treated fluid flow (3.03) and an H2S-loaded absorbent (3.04) are obtained; b) the H2S-loaded absorbent is heated by means of an indirect heat exchange (3.07) with a regenerated H2S-selective absorbent (3.08); c) the heated H2S-loaded absorbent (3.09) is expanded to a pressure of 1.2 to 10 bar in a low-pressure expansion container (LPF), and a first CO2-enriched exhaust gas and a partially regenerated absorbent (3.11) are obtained; d) the partially regenerated absorbent (3.11) is regenerated in a desorption column (D), and an H2S-enriched exhaust gas (3.23) and a regenerated absorbent (3.08) are obtained; e) the H2S-enriched exhaust gas (3.23) is supplied to a Claus unit (CL), the exhaust gas of the Claus unit is supplied to a hydrogenation unit (HY), and a hydrogenated Claus final gas is obtained; f) the hydrogenated Claus final gas and the first CO2-enriched exhaust gas are treated with a second sub-flow (3.18) of the regenerated H2S-selective absorbent (3.17) in a second absorber (TGA) at a pressure of 1 to 4 bar, and a second CO2-enriched exhaust gas (3.25) and a second H2S-loaded absorbent (3.02) are obtained; and g) the second H2S-loaded absorbent is conducted into the first absorber (A1). The invention further relates to a system which is suitable for carrying out the method. The invention is characterized by a low energy requirement.