公开(公告)号：NO895141A

公开(公告)日：1990-06-22

申请号：NO895141

申请日：1989-12-20

Applicant: HOECHST AG

Inventor： BOEHSHAR MANFRED ,  KLEINER HANS-JERG ,  WALDMANN KARL ,  PFAHLER GERHARD

IPC: C09K15/32 ,  C07F3/02 ,  C07F9/40 ,  C07F9/48 ,  C08K5/53 ,  C08K5/5393 ,  C08L23/00 ,  C08L23/02

CPC classification number: C07F9/4875 ,  C07F3/02 ,  C07F9/4084 ,  C08K5/5393 ,  C08L23/02

公开(公告)号：NO895141D0

公开(公告)日：1989-12-20

申请号：NO895141

申请日：1989-12-20

Applicant: HOECHST AG

Inventor： BOEHSHAR MANFRED ,  KLEINER HANS-JERG ,  WALDMANN KARL ,  PFAHLER GERHARD

IPC: C09K15/32 ,  C07F3/02 ,  C07F9/40 ,  C07F9/48 ,  C08K5/53 ,  C08K5/5393 ,  C08L23/00 ,  C08L23/02 ,  C07F

Abstract: Process for the preparation of organophosphorus derivatives of 2,4-di-t-butylphenol having a high content of organophosphorus derivatives of biphenyl, characterised in that, in the first step, a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35 is reacted under Grignard conditions with magnesium to give the corresponding Grignard compound, which is further reacted, in a second step, with bis(2,4-di-t-butylphenyl) chlorophosphite of the formula IV … … to form a mixture in which at least 50% by weight of the phosphorus is bound in the form of tetrakis(2,4-di-t-butylphenyl)-4,4'-biphenylene diphosphonite of the formula I … … the bonding of the phosphorus being determined by P-NMR analysis. … The invention furthermore relates to a polyolefin moulding composition which contains tetrakis(2,4-di-t-butylphenyl)- 4,4'-biphenylene diphosphonite of the formula I prepared by reacting a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35, with magnesium to give the Grignard compound and subsequent reaction thereof with bis(2,4-di-t-butylphenyl) chlorophosphite. … The moulding composition has improved properties compared with moulding compositions which contain said phosphonite prepared in accordance with the prior art. … The invention also relates to a process for the preparation of 4,4'-dihalomagnesium compounds of biphenyl by reacting a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35 with magnesium in the absence of an entrainer, in which process a 4,4'-dihalobiphenyl whose halogen has an atomic weight of at least 35 is reacted with finely divided magnesium kept in suspension.

公开(公告)号：AU556140B2

公开(公告)日：1986-10-23

申请号：AU8172482

申请日：1982-03-19

Applicant: HOECHST AG

Inventor： WIEZER HARTMUT ,  PFAHLER GERHARD

IPC: C08K5/00 ,  C07D401/14 ,  C08G18/00 ,  C08G18/30 ,  C08G18/38 ,  C08G63/00 ,  C08G63/68 ,  C08G63/685 ,  C08G63/78 ,  C08K5/34 ,  C08K5/3412 ,  C08K5/3435 ,  C08K5/3477 ,  C08K5/3492 ,  C08L23/00 ,  C08L23/12 ,  C08L101/00

Abstract: New esters and urethanes containing polyalkylpiperidylaminotriazine groups of the formula are prepared from carboxylic acid exters or isocyanates and triazinyl alcohols. The compounds are valuable stabilizers for polymeric materials.

公开(公告)号：AU554795B2

公开(公告)日：1986-09-04

申请号：AU8701682

申请日：1982-08-10

Applicant: HOECHST AG

Inventor： WIEZER HARTMUT ,  PFAHLER GERHARD

IPC: C08G73/00 ,  C07D401/12 ,  C07F7/04 ,  C08G18/38 ,  C08G73/06 ,  C08K5/34 ,  C08K5/3492 ,  C08L23/10 ,  C08L79/04 ,  C08L87/00 ,  C08L101/00 ,  C07D401/14 ,  C07F7/02 ,  C08L23/12

Abstract: Hitherto unknown polyalkylpiperidinylaminotriazines having a structure of the type are obtained from halogenotriazinyl compounds and aminoethylaminoethanols and can be converted into further derivatives with isocyanates, esters and acid chlorides to give new stabilizers for polymers, which stabilizers are distinguished by very good migration resistance.

公开(公告)号：AU554424B2

公开(公告)日：1986-08-21

申请号：AU7827881

申请日：1981-12-04

Applicant: HOECHST AG

Inventor： WIEZER HARTMUT ,  PFAHLER GERHARD

IPC: C08G73/00 ,  C07D251/18 ,  C07D251/50 ,  C07D251/52 ,  C07D251/70 ,  C07D401/12 ,  C07D401/14 ,  C08G73/06 ,  C08K5/34 ,  C08K5/3492 ,  C08L79/04 ,  C08L101/00 ,  D01F1/10 ,  C08J5/18 ,  C08L23/12

公开(公告)号：CA1164865A

公开(公告)日：1984-04-03

申请号：CA391564

申请日：1981-12-04

Applicant: HOECHST AG

Inventor： WIEZER HARTMUT ,  PFAHLER GERHARD

IPC: C08G73/00 ,  C07D251/18 ,  C07D251/50 ,  C07D251/52 ,  C07D251/70 ,  C07D401/12 ,  C07D401/14 ,  C08G73/06 ,  C08K5/34 ,  C08K5/3492 ,  C08L79/04 ,  C08L101/00 ,  D01F1/10 ,  C07D251/40

Abstract: Hitherto unknown poly-bis-triazinylamines which have a linear structure, are not crosslinked and have a degree of polymerization of up to approx. 200, of the formula in which at least one of the radicals R1 to R5 must be a polyalkylpiperidyl group or must contain this group, are obtained by controlled reaction of a cyanuric hallde with diamines in several successive proccss stages. The new compounds can be used as sparingly volatile and particularly migration-resistant light stabilizers for synthetic polymers.

公开(公告)号：AU534133B2

公开(公告)日：1984-01-05

申请号：AU6144980

申请日：1980-08-14

Applicant: HOECHST AG

Inventor： WIEZER HARTMUT ,  PFAHLER GERHARD

IPC: C08K5/00 ,  C07D401/12 ,  C07D401/14 ,  C08G73/00 ,  C08G73/06 ,  C08G73/08 ,  C08K5/34 ,  C08K5/3477 ,  C08K5/3492 ,  C08L23/00 ,  C08L101/00 ,  C08J3/20 ,  C08L23/02 ,  C08L23/12 ,  C08L25/04 ,  C08L27/00 ,  C08L33/08 ,  C08L33/12

Abstract: The invention relates to polymers of triazine compounds containing piperidine groups which may serve as low volatile and migration-resistant light stabilizers for synthetic polymers. They have the structure (I) and are obtained from cyanuric halides, diamines and polyalkylpiperidylamino compounds.

公开(公告)号：BR8204701A

公开(公告)日：1983-08-02

申请号：BR8204701

申请日：1982-08-10

Applicant: HOECHST AG

Inventor： WIEZER HARTMUT ,  PFAHLER GERHARD

IPC: C08G73/00 ,  C07D401/12 ,  C07F7/04 ,  C08G18/38 ,  C08G73/06 ,  C08K5/34 ,  C08K5/3492 ,  C08L23/10 ,  C08L79/04 ,  C08L87/00 ,  C08L101/00

Abstract: Hitherto unknown polyalkylpiperidinylaminotriazines having a structure of the type are obtained from halogenotriazinyl compounds and aminoethylaminoethanols and can be converted into further derivatives with isocyanates, esters and acid chlorides to give new stabilizers for polymers, which stabilizers are distinguished by very good migration resistance.

公开(公告)号：ZA8205768B

公开(公告)日：1983-07-27

申请号：ZA8205768

申请日：1982-08-10

Applicant: HOECHST AG

Inventor： WIEZER HARTMUT ,  PFAHLER GERHARD

IPC: C08G73/00 ,  C07F7/04 ,  C08G18/38 ,  C08G73/06 ,  C08K5/3492 ,  C08L23/10 ,  C08L79/04 ,  C08L87/00 ,  C08L101/00 ,  C08G ,  C07D ,  C08K

CPC classification number: C08K5/34926 ,  C07F7/045 ,  C08G18/3851 ,  C08G73/0644

公开(公告)号：CA1149383A

公开(公告)日：1983-07-05

申请号：CA381951

申请日：1981-07-17

Applicant: HOECHST AG

Inventor： WEIZER HARTMUT ,  PFAHLER GERHARD

IPC: C08K5/00 ,  C07D401/12 ,  C07D401/14 ,  C08K5/34 ,  C08K5/3477 ,  C08K5/3492 ,  C08L23/00 ,  C08L101/00 ,  C25D11/22

Abstract: : Triazinylaminotriazines of the general formula which are used as stabilizers for polymers, are prepared by reacting a cyanuric halide with amines containing triazinyl and polyalkylpiperidylamino groups.