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    ARYLESTERS OF PHOSPHONOUS ACID, PROCESS FOR PREPARING THEM AND THEIR USE TO STABILIZE PLASTICS, IN PARTICULAR POLYOLEFIN MOULDING MATERIALS
    1.
    发明申请
    ARYLESTERS OF PHOSPHONOUS ACID, PROCESS FOR PREPARING THEM AND THEIR USE TO STABILIZE PLASTICS, IN PARTICULAR POLYOLEFIN MOULDING MATERIALS 审中-公开
    磷酸三聚体，制备它们的方法及其用于稳定塑料，特别是聚烯烃模塑材料

    公开(公告)号：WO9014349A2

    公开(公告)日：1990-11-29

    申请号：PCT/EP9000787

    申请日：1990-05-16

    Applicant: HOECHST AG

    Inventor： BOEHSHAR MANFRED ,  KLEINER HANS-JERG ,  PFAHLER GERHARD

    IPC: C07F9/48 ,  C07F9/6571 ,  C07F9/6574 ,  C08K5/53 ,  C08K5/5393 ,  C08L23/02 ,  C09K15/32

    CPC classification number: C08K5/5393 ,  C07F9/4841 ,  C07F9/485 ,  C07F9/65719

    Abstract: Process for preparing aryl esters of phosphonous acid of formula (V), where A is non-existent or a direct bond or a divalent hydrocarbon bridge with 1 to 6 carbon atoms, which can be substituted by the groups mentioned below, or a heteroatom, cycloalkylidene with 4 to 8 carbon atoms or phenylalkylidene with 7 to 12 carbon atoms, n is equal to 1 or 2, R as a monovalent residue denotes certain non-aromatic or aromatic hydrocarbon residues, the aromatic residues denoting substituents such as alkyl, alkoxy, alkylthio, dialkylamino, aryl, aryloxy or halogen, and as a divalent residue denotes a phenylene or naththylene residue, which can carry non-aromatic hydrocarbon residues as substituents, R is a non-aromatic hydrocarbon residue with 1 to 18 carbon atoms, aryl, arylmethyl, arylethyl or arylisopropyl, each aryl containing 6 to 10 carbon atoms, and R denotes hydrogen or one of the groups mentioned under R . In a first stage a halogenated hydrocarbon R (-Hal)n, in which R has the above-mentioned meaning, n = 1 or 2, and the halogen has an atomic weight of at least 35, is converted under Grignard conditions with at least molar quantities of magnesium to the corresponding organomagnesium compounds R (MgHal)n. These are reacted in a second stage with phosphoric acid-bis-arylester halides of formula (VI), where R , R and Hal have the above-mentioned meanings, to form the phosphonous acid arylester (V). The invention also relates to a plastics moulding material, in particular a polyolefin moulding material, containing the phosphonous acid arylester of formula (V). The properties of the moulding material are superior to those of materials which contain phosphonites produced by prior art techniques.

    Abstract translation: 制备式（V）的膦酸的芳基酯的方法，其中不存在A或直接键或可被下述基团取代的具有1至6个碳原子的二价烃桥，或杂原子， 具有4至8个碳原子的亚烷基或具有7至12个碳原子的苯基亚烷基，n等于1或2，作为一价残基的R 1表示某些非芳族或芳族烃残基，表示取代基的芳族残基如烷基 ，烷氧基，烷硫基，二烷基氨基，芳基，芳氧基或卤素，二价残基表示可带有非芳香烃残基作为取代基的亚苯基或亚硫杂残基，R 2是非芳族烃残基， 18个碳原子，芳基，芳基甲基，芳基乙基或芳基异丙基，每个芳基含有6至10个碳原子，R 3表示氢或R 2中提及的基团之一。 在第一阶段，卤化烃R 1（ - Hal）n，其中R 1具有上述含义，n = 1或2，卤素原子量至少为35，被转化 在具有至少摩尔量的镁的Grignard条件下，与相应的有机镁化合物R 1（MgHal）n。 这些在第二阶段与式（VI）的磷酸 - 双 - 芳基酯卤化物反应，其中R 2，R 3和Hal具有上述含义，以形成膦酸芳基酯（V）。 本发明还涉及包含式（V）的膦酸芳基酯的塑料模制材料，特别是聚烯烃模塑材料。 成型材料的性能优于通过现有技术制造的含有亚膦酸盐的材料。

    ARYLESTERS OF PHOSPHONOUS ACID, PROCESS FOR PREPARING THEM AND THEIR USE TO STABILIZE PLASTICS, IN PARTICULAR POLYOLEFIN MOULDING MATERIALS
    2.
    发明申请
    ARYLESTERS OF PHOSPHONOUS ACID, PROCESS FOR PREPARING THEM AND THEIR USE TO STABILIZE PLASTICS, IN PARTICULAR POLYOLEFIN MOULDING MATERIALS 审中-公开
    磷酸三聚体，制备它们的方法及其用于稳定塑料，特别是聚烯烃模塑材料

    公开(公告)号：WO9014349A3

    公开(公告)日：1991-02-21

    申请号：PCT/EP9000787

    申请日：1990-05-16

    Applicant: HOECHST AG

    Inventor： BOEHSHAR MANFRED ,  KLEINER HANS-JERG ,  PFAHLER GERHARD

    IPC: C07F9/48 ,  C07F9/6571 ,  C07F9/6574 ,  C08K5/53 ,  C08K5/5393 ,  C08L23/02 ,  C09K15/32

    CPC classification number: C08K5/5393 ,  C07F9/4841 ,  C07F9/485 ,  C07F9/65719

    Abstract: Process for preparing aryl esters of phosphonous acid of formula (V), where A is non-existent or a direct bond or a divalent hydrocarbon bridge with 1 to 6 carbon atoms, which can be substituted by the groups mentioned below, or a heteroatom, cycloalkylidene with 4 to 8 carbon atoms or phenylalkylidene with 7 to 12 carbon atoms, n is equal to 1 or 2, R1 as a monovalent residue denotes certain non-aromatic or aromatic hydrocarbon residues, the aromatic residues denoting substituents such as alkyl, alkoxy, alkylthio, dialkylamino, aryl, aryloxy or halogen, and as a divalent residue denotes a phenylene or naththylene residue, which can carry non-aromatic hydrocarbon residues as substituents, R2 is a non-aromatic hydrocarbon residue with 1 to 18 carbon atoms, aryl, arylmethyl, arylethyl or arylisopropyl, each aryl containing 6 to 10 carbon atoms, and R3 denotes hydrogen or one of the groups mentioned under R2. In a first stage a halogenated hydrocarbon R1(-Hal)¿n?, in which R?1¿ has the above-mentioned meaning, n = 1 or 2, and the halogen has an atomic weight of at least 35, is converted under Grignard conditions with at least molar quantities of magnesium to the corresponding organomagnesium compounds R1(MgHal)¿n?. These are reacted in a second stage with phosphoric acid-bis-arylester halides of formula (VI), where R?2, R3¿ and Hal have the above-mentioned meanings, to form the phosphonous acid arylester (V). The invention also relates to a plastics moulding material, in particular a polyolefin moulding material, containing the phosphonous acid arylester of formula (V). The properties of the moulding material are superior to those of materials which contain phosphonites produced by prior art techniques.

    ARYLESTERS OF PHOSPHONOUS ACID, PROCESS FOR PREPARING THEM AND THEIR USE TO STABILIZE PLASTICS, IN PARTICULAR POLYOLEFIN MOULDING MATERIALS
    3.
    发明专利
    ARYLESTERS OF PHOSPHONOUS ACID, PROCESS FOR PREPARING THEM AND THEIR USE TO STABILIZE PLASTICS, IN PARTICULAR POLYOLEFIN MOULDING MATERIALS 未知

    公开(公告)号：CA2058762C

    公开(公告)日：2001-05-08

    申请号：CA2058762

    申请日：1990-05-16

    Applicant: HOECHST AG

    Inventor： BOEHSHAR MANFRED ,  KLEINER HANS-JERG ,  PFAHLER GERHARD

    IPC: C07F9/48 ,  C07F9/6571 ,  C07F9/6574 ,  C08K5/53 ,  C08K5/5393 ,  C08L23/02 ,  C09K15/32 ,  C08L101/00

    Abstract: A process for the preparation of aryl phosphonites of the formula V (see formula I) in which A is non-existent or a direct bond or a divalent hydrocarbon bridge having 1 to 6 carbon atoms which may be substituted by groups mentioned further below under R1, or is a hetero atom, cycloalkylidene having 4 to 8 carbon atoms or phenylalkylidene having 7 to 12 carbon atoms, n is 1 or 2, R1 as monovalent radical is certain non-aromatic or aromatic hydrocarbon radicals, in which the aromatic radicals are substituents such as alkyl, alkoxy, alkylthio, dialkylamino, aryl, aryloxy or halogen, and as divalent radical a phenylene or naphthylene radical, which may carry non-aromatic hydrocarbon radicals as substituents, R2 is a non-aromatic hydrocarbon radical having 1 to 18 carbon atoms, aryl, arylmethyl, arylethyl or arylisopropyl, in which the aryl in each case contains 6 to carbon atoms, and R3 is hydrogen or a group mentioned under R2, in which process in a first step a hydrocarbon halide R1(-Hal)n, in which R1 has the abovementioned meaning, n is = 1 or 2 and the halogen has an atomic weight of at least 35, is reacted under Grignard conditions with at least molar amounts of magnesium to give the corresponding Grignard compounds R1(MgHal)n and these compounds are reacted in a second step with bisaryl halophosphonites of the formula VI (see formula I) , in which R2, R3 and Hal ha,e the abovementioned meaning, with the formation of the aryl phosphonites V. The invention further relates to a plastic molding composition, in particular a polyolefin molding composition containing aryl phosphonites of the formula V. The molding composition is distinguished by improved properties compared with those molding compositions containing phosphonites prepared by the prior art.

    9.
    发明专利
    未知

    公开(公告)号：FI915352A

    公开(公告)日：1992-05-16

    申请号：FI915352

    申请日：1991-11-13

    Applicant: HOECHST AG

    Inventor： PFAHLER GERHARD ,  SCHMAILZL GEORG

    IPC: C08F6/02 ,  C08K5/04 ,  C08K5/06 ,  C08L101/00 ,  C08F

    Abstract: In synthetic moulding compositions, especially those based on olefin polymers, which contain phenolic stabilisers and metal ions as catalyst residues, the discoloration at the processing temperature is reduced when they contain triglycerol or ditrimethylolpropane as catalyst inactivators.

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