公开(公告)号：JP2012150180A

公开(公告)日：2012-08-09

申请号：JP2011007265

申请日：2011-01-17

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： YONEDA EIJI ,  ICHINOHE DAIGO

IPC: G03F7/038 ,  C08G59/40 ,  G03F7/004 ,  G03F7/40

Abstract: PROBLEM TO BE SOLVED: To provide a radiation sensitive resin composition in which preservation stability and hardening by low temperature firing of a short time period are both achieved and which has sufficient sensitivity; and a cured film excellent in heat resistance, transmittance, and voltage retaining ratio.SOLUTION: The radiation sensitive resin composition contains [A] a polymer having a structural unit comprising an epoxy group, [B] a polymeric compound including an ethylenically unsaturated bond, [C] a radiation-sensitive polymerization initiator, and [D] a compound including a cyanate group. Preferably, the [A] polymer further includes a structural unit comprising a carboxyl group.

Abstract translation: 要解决的问题：提供一种通过短时间段的低温烧制实现保存稳定性和硬化并且具有足够灵敏度的辐射敏感性树脂组合物; 以及耐热性，透射率和电压保持率优异的固化膜。 解决方案：辐射敏感性树脂组合物含有[A]具有包含环氧基的结构单元的聚合物，[B]包含烯键式不饱和键的聚合化合物，[C]辐射敏感聚合引发剂和[D ]包含氰酸酯基团的化合物。 优选地，[A]聚合物还包括包含羧基的结构单元。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2012088459A

公开(公告)日：2012-05-10

申请号：JP2010234063

申请日：2010-10-18

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： YONEDA EIJI ,  NISHI NOBUHIRO ,  KODAMA SEIICHIRO ,  INOMATA KATSUMI

IPC: G03F7/023 ,  C08F220/32 ,  C08G59/32 ,  C08K5/18 ,  C08K5/28 ,  C08L63/00 ,  G03F7/004 ,  G03F7/40

Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition which simultaneously achieves low temperature calcination and storage stability and has high radiation sensitivity, and to provide a cured film as an interlayer dielectric film, a protection film or a spacer, which is suitable for flexible display applications and is excellent in surface hardness, solvent resistance and dielectric constant.SOLUTION: A radiation-sensitive resin composition comprises: [A] an alkali-soluble resin obtained by copolymerizing (A1)at least one monomer selected from the group consisting of an unsaturated carboxylic acid and an unsaturated carboxylic acid anhydride with (A2) an epoxy group-containing unsaturated compound; [B] a quinonediazide compound; and [C] at least one curing agent selected from the group consisting of a benzene compound having an electron-attracting group and an amino group, a compound containing two benzene rings having an electron-attracting group and an amino group, a tertiary amino compound, an amine salt, a phosphonium salt, an amidine salt, an amide compound, a ketimine compound, a block isocyanate compound, an imidazole ring-containing compound and a clathrate compound.

Abstract translation: 要解决的问题：提供一种同时实现低温煅烧和储存稳定性并且具有高辐射灵敏度的辐射敏感性树脂组合物，并且提供作为层间电介质膜，保护膜或间隔物的固化膜， 适用于柔性显示应用，表面硬度，耐溶剂性和介电常数优异。 解决方案：辐射敏感性树脂组合物包含：[A]将（A1）至少一种选自不饱和羧酸和不饱和羧酸酐的单体与（A2 ）含环氧基的不饱和化合物; [B]醌二叠氮化合物; 和[C]选自由具有吸电子基团和氨基的苯化合物组成的组中的至少一种固化剂，含有两个具有吸电子基团和氨基的苯环的化合物，叔氨基化合物 胺盐，鏻盐，脒盐，酰胺化合物，酮亚胺化合物，嵌段异氰酸酯化合物，咪唑环化合物和包合物化合物。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2012063747A

公开(公告)日：2012-03-29

申请号：JP2011148926

申请日：2011-07-05

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： YONEDA EIJI ,  NISHI NOBUHIRO ,  MARUYAMA HIROYUKI

IPC: G03F7/004 ,  C08F220/06 ,  G02B5/20 ,  G03F7/033 ,  G03F7/40

Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition simultaneously achieving storage stability and low temperature calcination with sufficient sensitivity; a cured film as an interlayer insulating film, a protective film, or a spacer, excellent in solvent resistance, relative dielectric constant and hardness; a method for forming the cured film; a color filter excellent in heat resistance, solvent resistance, voltage holding ratio, or the like; and a method for forming the color filter.SOLUTION: A radiation-sensitive resin composition of the present invention contains an alkali-soluble resin [A] obtained by copolymerizing at least one compound (A1) selected from a group consisting of an unsaturated carboxylic acid and an unsaturated carboxylic acid anhydride and a hydroxyl group-containing unsaturated compound (A2), a polymerizable compound [B] having an ethylenically unsaturated bond, a radiation-sensitive polymerization initiator [C], and a blocked isocyanate compound [D].

Abstract translation: 要解决的问题：提供一种能够以足够的灵敏度同时实现储存稳定性和低温煅烧的辐射敏感性树脂组合物; 作为层间绝缘膜的固化膜，保护膜或间隔物，耐溶剂性，相对介电常数和硬度优异; 形成固化膜的方法; 耐热性，耐溶剂性，电压保持率等优异的滤色器; 以及形成滤色器的方法。 解决方案：本发明的辐射敏感性树脂组合物含有通过共聚合至少一种选自不饱和羧酸和不饱和羧酸酐的化合物（A1）而获得的碱溶性树脂[A] 和含羟基的不饱和化合物（A2），具有烯键式不饱和键的聚合性化合物[B]，辐射敏感性聚合引发剂[C]和封端异氰酸酯化合物[D]。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2012037814A

公开(公告)日：2012-02-23

申请号：JP2010179735

申请日：2010-08-10

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： YONEDA EIJI ,  NISHI NOBUHIRO ,  KODAMA SEIICHIRO ,  INOMATA KATSUMI

IPC: G03F7/004 ,  G03F7/033 ,  G03F7/40 ,  H01L21/027

Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition (with sufficient radiation sensitivity and developability) which can easily form a microscopic and sophisticated pattern, and satisfies both storage stability and short-time low-temperature firing, and to provide a cured film excellent in required characteristics such as heat resistance and compression characteristics as well as to provide a method of forming the cured film.SOLUTION: The invention includes: [A] an alkali-soluble resin formed by copolymerizing monomers containing (A1) multiple kinds selected from a set composed of unsaturated carboxylic acids and unsaturated carboxylic acid anhydrides and (A2) an epoxy group-containing unsaturated compound; [B] a polymerizable compound with ethylenically unsaturated bonds; [C] a radiation-sensitive polymerization initiator; and [D] a radiation-sensitive resin composition containing a compound represented by the following formula (1).

Abstract translation: 要解决的问题：提供能够容易地形成微观和复杂图案的辐射敏感性树脂组合物（具有足够的辐射敏感性和显影性），并且满足储存稳定性和短时低温烧制，以及 提供了耐热性和压缩特性等所需特性优异的固化膜，并提供了形成固化膜的方法。 解决方案：本发明包括：[A]通过使选自由不饱和羧酸和不饱和羧酸酐组成的组中的（A1）多种的单体和（A2）含环氧基的单体共聚形成的碱溶性树脂 不饱和化合物; [B]具有烯属不饱和键的聚合性化合物; [C]辐射敏感聚合引发剂; 和[D]含有由下式（1）表示的化合物的辐射敏感性树脂组合物。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2012008537A

公开(公告)日：2012-01-12

申请号：JP2011104760

申请日：2011-05-09

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： YONEDA EIJI ,  NISHI NOBUHIRO ,  KODAMA SEIICHIRO ,  INOMATA KATSUMI

IPC: G03F7/004 ,  C08F220/32 ,  G03F7/031 ,  G03F7/033 ,  G03F7/40 ,  H01L21/027

Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition for forming a cured film, which achieves both of storage stability and low temperature baking property and has sufficient sensitivity to radiation, to provide a cured film excellent in heat resistance, chemical resistance, transmittance, flatness and resistance against linear thermal expansion, and to provide a display element excellent in a voltage retention rate.SOLUTION: The radiation-sensitive resin composition for forming a cured film contains: [A] a copolymer having (a1) a structural unit containing a carboxyl group and (a2) a structural unit containing an epoxy group; [B] a polymerizable compound having an ethylenically unsaturated bond; [C] a radiation-sensitive polymerization initiator; [D] a compound having a hydroxyl group or a carboxyl group; and [E] an amine compound. The composition shows a viscosity of 1.0 mPa s or more and 50 mPa s or less at 25°C.

Abstract translation: 要解决的问题：为了提供一种形成固化膜的辐射敏感性树脂组合物，其具有保存稳定性和低温烘烤性能，并且具有足够的辐射敏感性，以提供耐热性优异的固化膜， 耐化学性，透光率，平坦度和抗线性热膨胀性，并且提供一种电压保持率优异的显示元件。 解决方案：用于形成固化膜的辐射敏感性树脂组合物包含：[A]具有（a1）含有羧基的结构单元的共聚物和（a2）含有环氧基的结构单元; [B]具有烯属不饱和键的聚合性化合物; [C]辐射敏感聚合引发剂; [D]具有羟基或羧基的化合物; 和[E]胺化合物。 该组合物在25℃下的粘度为1.0mPa·s以上且50mPa·s以下。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2011237668A

公开(公告)日：2011-11-24

申请号：JP2010110102

申请日：2010-05-12

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： YONEDA EIJI ,  ICHINOHE DAIGO ,  KOMATSU HIROYUKI ,  KURIYAMA KEISUKE

IPC: G03F7/004 ,  C08G59/40 ,  C08K5/07 ,  C08K5/10 ,  C08K5/29 ,  C08K5/33 ,  C08L63/00 ,  G02F1/1333 ,  G02F1/1339 ,  G03F7/033 ,  G03F7/40 ,  H01L21/027

Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition which can be heated and sintered at a low temperature and in a short time and has a high sensitivity with respect to radiation and the curing film obtained from which has a heat resistance, transparency and solvent resistance, is therefore suitably used for forming a spacer, a protection film, and an interlayer dielectric film of a flexible display and is excellent in terms of storage stability.SOLUTION: A radiation-sensitive resin composition includes (A) a compound containing epoxy groups, (B) a polymer compound having ethylenic unsaturated bonds, (C) a radiation-sensitive polymerization initiator and (D) at least one substance selected from the group of ketimine and aldimine.

Abstract translation: 要解决的问题：提供一种辐射敏感性树脂组合物，其可以在低温和短时间内被加热和烧结，并且相对于辐射具有高灵敏度，并且由此得到的固化膜具有热 电阻，透明性和耐溶剂性，因此适合用于形成柔性显示器的间隔物，保护膜和层间电介质膜，并且在储存稳定性方面是优异的。 解决方案：辐射敏感性树脂组合物包括（A）含环氧基的化合物，（B）具有烯键式不饱和键的高分子化合物，（C）辐射敏感聚合引发剂和（D）至少一种选择的物质 来自酮亚胺和醛二胺的组。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2011232659A

公开(公告)日：2011-11-17

申请号：JP2010104583

申请日：2010-04-28

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： YONEDA EIJI ,  NISHI NOBUHIRO ,  KODAMA SEIICHIRO ,  INOMATA KATSUMI

IPC: G03F7/004 ,  C08G59/20 ,  C08K5/07 ,  C08K5/10 ,  C08K5/33 ,  C08K5/3447 ,  C08L63/00 ,  G02F1/1368 ,  G03F7/031 ,  G03F7/38

Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition which can be suitably used for forming a spacer, protection film and interlayer dielectric, etc. of a flexible display which are capable of rapid and low-temperature heating and calcination, and have a high radiation sensitivity and a low linear thermal expansion coefficient.SOLUTION: This radiation-sensitive resin composition for display elements includes; (A)a copolymer which has (a1) a structure unit containing a carboxyl group and (a2) a structure unit containing an epoxy group; (B) a polymerizable compound having an ethylenically unsaturated bond; (C) a radiation-sensitive polymerization initiator; and (D) at least either one selected from compounds represented by formulas (1) and (2).

Abstract translation: 要解决的问题：提供一种适用于形成能够进行快速和低温加热和煅烧的柔性显示器的间隔物，保护膜和层间电介质等的辐射敏感性树脂组合物 ，具有高的辐射灵敏度和低的线性热膨胀系数。 该解决方案：用于显示元件的该辐射敏感性树脂组合物包括： （A）具有（a1）含有羧基的结构单元和（a2）含有环氧基的结构单元的共聚物; （B）具有烯属不饱和键的聚合性化合物; （C）辐射敏感聚合引发剂; 和（D）选自由式（1）和（2）表示的化合物中的至少一种。 版权所有（C）2012，JPO＆INPIT

公开(公告)号：JP2011169976A

公开(公告)日：2011-09-01

申请号：JP2010031492

申请日：2010-02-16

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： YONEDA EIJI ,  MARUYAMA TAKUYUKI ,  NISHI NOBUHIRO ,  IIDA MASAFUMI ,  HAMADA KENICHI

IPC: G03F7/004 ,  C08K5/28 ,  C08K5/3445 ,  C08K5/37 ,  C08L33/00 ,  G03F7/023 ,  G03F7/40

Abstract: PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition which has high radiation sensitivity and can be baked by heating at a low temperature in a short period of time so that it is suitably used in the formation of an interlayer insulating film of a flexible display.
SOLUTION: The radiation-sensitive resin composition for forming an interlayer insulating film contains [A] an alkali-soluble resin of a copolymer formed by copolymerizing a monomer containing (a1) unsaturated carboxylic acid and/or unsaturated carboxylic anhydride, and (a2) an epoxy group-containing unsaturated compound, [B] a 1,2-quinonediazide compound, and [C] a compound including two or more mercapto groups in one molecule. The compound including two or more mercapto groups in one molecule as the component [C] is preferably a compound represented by formula (1), wherein R
1 is methylene, 2-10C alkylene or alkylmethylene; Y is a single bond, -CO- or -O-CO-* (provided that a bond to which "*" is attached bonds to R
1 ); n is an integer of 2-10; and X is a 2-70C n-valent hydrocarbon group which may have one or more ether bonds, or in the case of n=3, X is a group represented by formula (2), wherein three symbols R
2 are each independently methylene or 2-6C alkylene; and three marks "*" are each a bond.
COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：提供一种辐射敏感性高的辐射敏感性树脂组合物，并且可以在短时间内在低温下加热而烘烤，从而适合用于形成层间绝缘 电影的灵活显示。 解决方案：用于形成层间绝缘膜的辐射敏感性树脂组合物含有[A]通过共聚含有（a1）不饱和羧酸和/或不饱和羧酸酐的单体和（ a2）含环氧基的不饱和化合物，[B] 1,2-醌二叠氮化合物，[C]一分子中含有2个以上巯基的化合物。 作为成分[C]的1分子中含有2个以上的巯基的化合物优选为式（1）表示的化合物，其中R 1为亚甲基，2-10C亚烷基或烷基亚甲基; Y是单键，-CO-或-O-CO- *（条件是连接有“*”的键与R 1键合）; n为2-10的整数; X是可以具有一个或多个醚键的2-70C n价烃基，或者在n = 3的情况下，X是由式（2）表示的基团，其中三个符号R / SP>各自独立地为亚甲基或2-6C亚烷基; 和三个标记“*”各自是一个债券。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2011133699A

公开(公告)日：2011-07-07

申请号：JP2009293697

申请日：2009-12-25

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： NISHI NOBUHIRO ,  YONEDA EIJI ,  ICHINOHE DAIGO

IPC: G03F7/023 ,  C08G73/10 ,  G02B1/04 ,  G03F7/40 ,  H01L21/027

Abstract: PROBLEM TO BE SOLVED: To provide a radiation sensitive resin composition which can be heated and baked at low-temperature and in a short-time, has high radiation sensitivity and is suitably used for forming an interlayer dielectric of a flexible display; and to also provide a positive radiation sensitive resin composition excellent in relative dielectric constant, solvent resistance, film hardness, resolution in patterning and electrical properties.
SOLUTION: The positive radiation sensitive resin composition comprises: [A] a polymer selected from the group consisting of a polyamic acid obtained by reacting a tetracarboxylic acid dianhydride with a diamine compound and a polyimide obtained by dehydration ring closure of the polyamic acid; [B] a 1,2-quinonediazide compound; and [C] a compound having at least one epoxy group in the molecule thereof.
COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：为了提供可以在低温和短时间内加热和烘烤的辐射敏感性树脂组合物，具有高的辐射灵敏度，并且适合用于形成柔性显示器的层间电介质; 并且还提供相对介电常数，耐溶剂性，膜硬度，图案化分辨率和电性能优异的正辐射敏感性树脂组合物。 阳离子敏感性树脂组合物包含：[A]选自由四羧酸二酐与二胺化合物反应得到的聚酰胺酸的聚合物和通过聚酰胺酸脱水闭环获得的聚酰亚胺 ; [B] 1,2-醌二叠氮化合物; 和[C]在其分子中具有至少一个环氧基的化合物。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2010277990A

公开(公告)日：2010-12-09

申请号：JP2010072868

申请日：2010-03-26

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： YONEDA EIJI ,  TAKASE HIDEAKI ,  ICHINOHE DAIGO

IPC: H01M14/00 ,  H01L31/04

CPC classification number: Y02E10/542 ,  Y02P70/521

Abstract: PROBLEM TO BE SOLVED: To provide a resin composition capable of precisely coating it on a substrate having a step difference of a metal wiring and of forming a shield film having superior corrosion resistance while maintaining high photoelectric conversion efficiency, and furthermore, of forming the shield film at a reduced cost only by a comparatively easy process of a coating process and a heating process, and to provide an electrode for a dye-sensitized solar cell superior in the photoelectric conversion efficiency which is equipped with this shield film having this corrosion resistance. SOLUTION: The electrode for the dye-sensitized solar cell is equipped with the shield film composed of a cured material of the resin composition. The resin composition contains a co-polymer having at least one kind of reactive functional group selected from a group consisting of [A] a carboxyl group, an epoxy group, and a (meth)acryloyl group. COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 解决的问题：提供一种树脂组合物，其能够精确地将其涂布在具有金属布线的阶梯差的基板上，并且在保持高的光电转换效率的同时形成具有优异的耐腐蚀性的屏蔽膜，此外， 仅通过比较容易的涂布工艺和加热工艺的方法以降低的成本形成屏蔽膜，并且提供具有优异的光电转换效率的染料敏化太阳能电池的电极，该电极装备有具有该屏蔽膜的该屏蔽膜 耐腐蚀性能。 解决方案：用于染料敏化太阳能电池的电极装备有由树脂组合物的固化材料构成的屏蔽膜。 树脂组合物含有具有选自由[A]羧基，环氧基和（甲基）丙烯酰基组成的组中的至少一种反应性官能团的共聚物。 版权所有（C）2011，JPO＆INPIT