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公开(公告)号：US4842800A
公开(公告)日：1989-06-27
申请号：US103153
申请日：1987-10-01
Applicant: Erik W. Walles , James V. Crivello , John H. Lupinski
Inventor： Erik W. Walles , James V. Crivello , John H. Lupinski
CPC classification number: H01L23/295 , C08G59/68 , C08K3/36 , H01L21/56 , H01L2924/0002
Abstract: A method for encapsulating microelectronic devices is provided using a heat curable epoxy composition having a monomeric or polymeric diaryliodonium hexafluoroantimonate salt. Curable compositions are also provided as well as encapsulated microelectronic devices.
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公开(公告)号：US4450360A
公开(公告)日：1984-05-22
申请号：US357435
申请日：1982-03-12
Applicant: James V. Crivello , Julia L. Lee
Inventor： James V. Crivello , Julia L. Lee
IPC: C07C45/67 , C07C49/248 , C07C49/255 , C07C49/747 , C07C49/753 , C07C49/835 , C07D239/60 , C07D319/06 , C08F2/50 , C08G59/68 , C08G85/00 , C08L61/00 , G03F7/029 , C07F9/66
CPC classification number: G03F7/029 , C07C45/673 , C07C49/248 , C07C49/255 , C07C49/747 , C07C49/753 , C07C49/835 , C07D239/60 , C07D319/06 , C08G59/68 , C08G85/00 , C08L61/00 , Y10S430/118
Abstract: Arylalkyliodonium salts are provided which can be used as thermal or photoinitiators for polymerization of a wide variety of cationically polymerizable organic materials. Reaction is effected between an aryliodonium tosylate and an active hydrogen aliphatic organic compound, such as dimedone, to produce an intermediate arylalkyliodonium tosylate salt which is thereafter reacted with a polyfluoro metal or metalloid salt of an alkali or alkaline earth metal to produce the desired arylalkyliodonium polyfluoro metal or metalloid salt, such as dimedonylphenyliodonium hexafluoroarsenate.
Abstract translation: 提供芳基烷基碘鎓盐，其可用作多种阳离子可聚合有机材料的聚合的热引发剂或光引发剂。 反应在芳基碘甲苯磺酸酯和活性氢脂肪族有机化合物如二酮之间进行，以产生中间芳基烷基碘甲磺酸盐，然后与碱金属或碱土金属的多氟金属或准金属盐反应以产生所需的芳基烷基碘多氟 金属或准金属盐，例如六氟砷酸二芳基苯基碘鎓。
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93.发明授权Method of coating a conducting substrate and coated substrates obtained thereby 失效涂布导电基材的方法和由此得到的涂布基材
公开(公告)号：US4416752A
公开(公告)日：1983-11-22
申请号：US338826
申请日：1982-01-11
Applicant: James V. Crivello
Inventor： James V. Crivello
CPC classification number: C09D5/4476 , Y10T428/31529
Abstract: A method is provided for electroinitiating cationic polymerization on the surface of a metal substrate or a metallized nonconducting substrate. The conducting substrate is used as the anode in an electrolyzed bath of a cationically polymerizable organic material, and an effective amount of an arylonium salt, such as diphenyliodonium hexafluorophosphate. An organic solvent also can be used.
Abstract translation: 提供了一种用于在金属衬底或金属化非导电衬底的表面上电泳引发阳离子聚合的方法。 在阳离子聚合性有机材料的电解浴中使用导电性基材作为阳极，使用有效量的芳基盐，如二苯基碘鎓六氟磷酸盐。 也可以使用有机溶剂。
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公开(公告)号：US4374066A
公开(公告)日：1983-02-15
申请号：US200769
申请日：1980-10-27
Applicant: James V. Crivello , Julia L. Lee
Inventor： James V. Crivello , Julia L. Lee
IPC: C07C381/12 , C07F9/68 , C08G85/00 , C07F5/02 , C07F9/90
CPC classification number: C07C381/12 , C08G85/00
Abstract: A method for making triarylsulfonium salts is provided based on the reaction of an aromatic hydrocarbon, a sulfur chloride, and chlorine in the presence of a Friedel Crafts catalyst. The triarylsulfonium salts can be used as cationic photoinitiators to effect the deep section cure of a variety of organic resin compositions.
Abstract translation: 在Friedel Crafts催化剂存在下，基于芳族烃，氯化亚硫和氯的反应，提供了制备三芳基锍盐的方法。 三芳基锍盐可以用作阳离子光引发剂以实现各种有机树脂组合物的深部分固化。
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公开(公告)号：US4329306A
公开(公告)日：1982-05-11
申请号：US152424
申请日：1980-05-22
Applicant: James V. Crivello
Inventor： James V. Crivello
CPC classification number: C08G65/105 , C08G59/68 , C08G85/00
Abstract: Aromatic onium salts, such as diaryliodonium salts, have been found to be effective thermal initiators for the polymerization of epoxy resins having a viscosity of up to about 100,000 centipoises at 25.degree. C. when used in combination with copper salts. The processable epoxy resin composition can be used in filament winding and pultrusion applications.
Abstract translation: 已经发现，芳族鎓盐如二芳基碘鎓盐是当与铜盐组合使用时，在25℃下粘度高达约100,000厘泊的环氧树脂的聚合是有效的热引发剂。 可加工的环氧树脂组合物可用于纤维缠绕和拉挤成型应用。
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Patent Agency Ranking
公开(公告)号：US4319974A
公开(公告)日：1982-03-16
申请号：US142100
申请日：1980-04-21
Applicant: James V. Crivello
Inventor： James V. Crivello
IPC: C08L71/02 , C08G59/00 , C08G59/14 , C08G59/18 , C08G59/20 , C08G59/36 , C08G59/40 , C08G59/68 , C08G65/00 , C08G65/02 , C08G65/10 , C08L63/00 , C09J7/02 , C09J163/00 , C09J171/00 , C09J171/02 , D21H19/16 , D21H19/24 , D21H27/00 , D21H27/30
CPC classification number: C09J7/0228 , C08G59/145 , C08G59/36 , C08G59/68 , C08G65/105 , D21H19/16 , D21H27/001 , C09J2400/283 , C09J2463/005
Abstract: UV curable mixtures of C.sub.(8-28) .alpha.-olefin oxides and certain onium salt photoinitiators, for example, certain diaryliodonium salts, or triarylsulfonium salts, and optionally polyfunctional epoxy resin, have been found useful in paper release coating applications.
Abstract translation: 已经发现C（8-28）α-烯烃氧化物和某些鎓盐光引发剂的可UV固化混合物，例如某些二芳基碘鎓盐或三芳基锍盐，以及任选的多官能环氧树脂可用于纸张脱模涂布应用。
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公开(公告)号：US4245029A
公开(公告)日：1981-01-13
申请号：US67613
申请日：1979-08-20
Applicant: James V. Crivello
Inventor： James V. Crivello
CPC classification number: G03F7/029
Abstract: Photocurable compositions are provided based on the use of particular triarylsulfonium salts as photoinitiators for certain oxirane containing aliphatically unsaturated organic resins, such as acrylics, or mixtures of vinyl aromatic and unsaturated polyesters. A simultaneous free-radical cure and cationic cure of the aforesaid organic resins are achieved, which provides improved results, such as metal coatings having improved solvent resistance.
Abstract translation: 基于特定的三芳基锍盐作为光引发剂用于某些含有脂族不饱和有机树脂（例如丙烯酸类）或乙烯基芳族和不饱和聚酯的混合物的环氧乙烷的提供，提供了光固化性组合物。 实现了上述有机树脂的同时自由基固化和阳离子固化，其提供改进的结果，例如具有改善的耐溶剂性的金属涂层。
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公开(公告)号：US4238587A
公开(公告)日：1980-12-09
申请号：US098096
申请日：1979-11-28
Applicant: James V. Crivello
Inventor： James V. Crivello
Abstract: Diaryliodonium salts have been found to be effective thermal initiators for the polymerization of a variety of cationically polymerizable materials including epoxides, cyclic ethers, phenol formaldehyde resins, etc., when used in combination with various cocatalysts. Among the cocatalysts which have been found to be effective are, for example, copper chelates and mixtures of such copper chelates with various reducing agents such as ascorbic acid, tin.sup.+2 salts, etc.
Abstract translation: 已经发现，当与各种助催化剂组合使用时，已经发现二芳基碘鎓盐是用于聚合各种阳离子可聚合材料（包括环氧化物，环醚，酚醛树脂等）的有效热引发剂。 已经发现有效的助催化剂是例如铜螯合物和这种铜螯合物与各种还原剂如抗坏血酸，锡+2盐等的混合物。
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公开(公告)号：US4192924A
公开(公告)日：1980-03-11
申请号：US34372
申请日：1979-04-30
Applicant: James V. Crivello
Inventor： James V. Crivello
Abstract: Curable organic resin compositions, such as epoxy resins, are provided, based on the use of a diaryliodonium salt-redox catalyst curing system. The curable compositions can provide flexible or rigid organic resin foam when used with a volatile organic solvent as a result of exothermic heat of cure.
Abstract translation: 基于使用二芳基碘盐 - 氧化还原催化剂固化体系提供可固化的有机树脂组合物，例如环氧树脂。 当固化的放热热量与挥发性有机溶剂一起使用时，可固化组合物可以提供柔性或刚性的有机树脂泡沫。
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公开(公告)号：US4161478A
公开(公告)日：1979-07-17
申请号：US833146
申请日：1977-09-14
Applicant: James V. Crivello
Inventor： James V. Crivello
IPC: C07F9/68 , C07F9/90 , C08F236/16 , C08G59/68 , C08G65/10 , C07C149/00 , C07D335/10
CPC classification number: C08G65/105 , C07F9/68 , C07F9/902 , C08F236/16 , C08G59/68
Abstract: Onium salts of Group VIa elements having an MF.sub.6 -anion, where M is selected from P, As and Sb, have been found to be photo active under ultraviolet light. These onium salts can be employed as cationic photoinitiators when used with a variety of organic resins and cyclic organic compounds.
Abstract translation: 已经发现在紫外光下，具有M 6选自P，As和Sb的具有MF6-阴离子的VIa族元素的鎓盐是光活性的。 当与各种有机树脂和环状有机化合物一起使用时，这些鎓盐可用作阳离子光引发剂。
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