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1.发明授权公开(公告)号：US06593388B2
公开(公告)日：2003-07-15
申请号：US09826330
申请日：2001-04-04
Applicant: James V. Crivello
Inventor： James V. Crivello
IPC: C08F250
CPC classification number: C08F2/50 , C07F7/0838 , C08G59/68
Abstract: Enhancement of the rates of cationic polymerizations initiated by onium salts has been achieved through the use of oligomeric and polymeric electron-transfer photosensitizers derived from a polymerizable compound substituted with a polynuclear aromatic group, including epoxides, oxetanes, and ethylenically unsaturated compounds. The polymerizable compound is substituted with residues derived from anthracene, naphthalene, perylene, pyrene, fluorene, carbazole, indole, benzocarbazole, acridone, phenothiazine, and thianthrene, particularly carbazole.
Abstract translation: 通过使用衍生自被多环芳族基团（包括环氧化物，氧杂环丁烷和烯键式不饱和化合物）取代的可聚合化合物的低聚和聚合电子转移光敏剂，已经实现了由鎓盐引发的阳离子聚合速率的提高。 可聚合化合物被衍生自蒽，萘，苝，芘，芴，咔唑，吲哚，苯并咔唑，吖啶酮，吩噻嗪和噻蒽，特别是咔唑的残基取代。
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公开(公告)号：US5583194A
公开(公告)日：1996-12-10
申请号：US195792
申请日：1994-02-14
Applicant: James V. Crivello , Mingxin Fan
Inventor： James V. Crivello , Mingxin Fan
CPC classification number: C07F7/0829 , C07F7/0879 , C07F7/1876 , C08G77/38
Abstract: The invention provides a method for making a curable epoxysilicone composition through the hydrosilation reaction between an ethylenically unsaturated epoxide and an SiH-containing silicone to produce an epoxysilicone product, and catalyzed by a quaternary ammonium, phosphonium or arsonium hexahaloplatinate which does not promote the oxirane ring-opening reaction of either the ethylenically unsaturated epoxide starting material or the epoxysilicone product. The invention also provides for a curable epoxysilicone composition made by the above method.
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3.发明授权Process for selective monoaddition to silanes containing two silicon-hydrogen bonds and products thereof 失效用于选择性加成含有两个硅氢键的硅烷及其产物的方法
公开(公告)号：US5484950A
公开(公告)日：1996-01-16
申请号：US993689
申请日：1992-12-21
Applicant: James V. Crivello
Inventor： James V. Crivello
IPC: C07F7/08 , C08G77/38 , C07D303/02 , C07F7/10 , C07F7/18
CPC classification number: C07F7/0896 , C07F7/0852 , C07F7/0879 , C08G77/38
Abstract: A process for the selective monoadditon of an olefin or acetylene to a siloxane which contains two reactive Si--H bonds to produce a product in which only one of the two Si--H functions has added across the olefin or acetylene is disclosed. A process for making unsymmetrical siloxanes from symmetrical dihydrosiloxanes and products of both of these processes are also disclosed. Products are represented by the formula I in which R.sup.1 and R.sup.4 are different: ##STR1##
Abstract translation: 公开了一种烯烃或乙炔对含有两个反应性Si-H键的硅氧烷的选择性单加成方法，以产生其中仅两种Si-H官能团中仅有一种加入到烯烃或乙炔中的产物。 还公开了从对称二氢硅氧烷制造不对称硅氧烷和这两种方法的产物的方法。 产品由式I表示，其中R1和R4不同：
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4.发明授权Cobalt catalyst for ring-opening polymerization of exopides and other heterocycles 失效钴催化剂用于外嵌剂和其它杂环的开环聚合
公开(公告)号：US5412054A
公开(公告)日：1995-05-02
申请号：US159760
申请日：1993-11-30
Applicant: James V. Crivello , Ming-Xin Fan
Inventor： James V. Crivello , Ming-Xin Fan
CPC classification number: B01J31/1608 , B01J31/20 , C08G65/12 , B01J2231/14 , B01J2231/323 , B01J2531/0211 , B01J2531/845
Abstract: A catalyst: mixture for ring-opening polymerization of heterocyclic monomers and polymers includes a catalyst composed of a cobalt carbonyl complex; and a cocatalyst composed of at least one Si-H-containing compound. A curable composition, which may be a two-part kit, is also disclosed and includes the catalyst; the cocatalyst; and at least one polymerizable compound which is a monomer or polymer containing a heterocyclic ring. A method of producing a polymeric product by ring-opening polymerization of heterocyclic monomers and polymers is also disclosed which includes the steps of preparing a mixture including a catalyst composed of a cobalt carbonyl complex, a cocatalyst composed of at least one Si-H-containing compound, and at least one polymerizable compound which is a monomer or polymer containing a heterocyclic ring; and reacting the mixture, preferably at about room temperature, to promote ring-opening polymerization of the at least one polymerizable compound to produce the polymeric product.
Abstract translation: 催化剂：用于杂环单体和聚合物的开环聚合的混合物包括由羰基钴络合物组成的催化剂; 和由至少一种含Si-H的化合物组成的助催化剂。 还公开了可以是两部分试剂盒的可固化组合物，并且包括催化剂; 助催化剂; 以及作为含有杂环的单体或聚合物的至少一种聚合性化合物。 还公开了通过杂环单体和聚合物的开环聚合制备聚合物的方法，其包括以下步骤：制备包含由羰基钴配合物组成的催化剂的催化剂，由至少一种含Si-H 化合物和至少一种可聚合化合物，其是含有杂环的单体或聚合物; 并使混合物优选在约室温下反应，以促进至少一种可聚合化合物的开环聚合以产生聚合产物。
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公开(公告)号：US5247044A
公开(公告)日：1993-09-21
申请号：US904350
申请日：1992-06-25
Applicant: James V. Crivello , Mingxin Fan
Inventor： James V. Crivello , Mingxin Fan
IPC: C08G65/26 , C08G59/68 , C08G65/16 , C08G77/46 , C08G81/00 , C08K5/5419 , C08K5/549 , C08L83/05 , C08L83/06
Abstract: The present invention is based on the discovery that various metal catalysts will catalyze the ring opening polymerization of epoxides to yield polyethers. The present invention therefore provides a method of making a polymeric product by ring-opening polymerization of heterocyclic epoxide monomer including the steps of preparing a mixture comprised of a catalyst; a Si--H containing compound; and at least one compound which is a heterocyclic epoxide containing monomer; and reacting the mixture at a temperature effective to promote ring-opening polymerization of the at least one compound to produce a polymeric product, preferably at room temperature.The present invention additionally provides for the silicone-polyether compositions created by this method.
Abstract translation: 本发明基于以下发现：各种金属催化剂将催化环氧化物的开环聚合以产生聚醚。 因此，本发明提供了通过杂环环氧化物单体的开环聚合制备聚合物的方法，包括以下步骤：制备由催化剂组成的混合物; 含Si-H的化合物; 和至少一种含杂环氧化物的单体的化合物; 并在有效促进至少一种化合物的开环聚合的温度下使该混合物反应，以产生聚合产物，优选在室温下。 本发明另外提供了通过该方法制备的硅氧烷 - 聚醚组合物。
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Patent Agency Ranking6.发明授权Preparation of diaryliodonium salt photoinitiators having long chain ester groups concatenated with aryl groups 失效制备具有与芳基连接的长链酯基的二芳基碘盐光引发剂
公开(公告)号：US5079378A
公开(公告)日：1992-01-07
申请号：US558627
申请日：1990-07-27
Applicant: James V. Crivello
Inventor： James V. Crivello
CPC classification number: C08F2/50 , C07C69/712 , C07J9/00 , C08G59/68 , C08G65/105 , G03F7/028
Abstract: A highcarbon-containing diaryliodonium initiator for cationic polymerization which possesses enhanced solubility characteristics over conventional diaryliodonium initiators. By the disclosed process, a novel photo/thermal initiator is obtained which is uniquely characterized by the concatenation of a long chain ester with an aryl group, resulting in a total number of carbon atoms in the entire moiety attached to the iodine atom in excess of 20.
Abstract translation: 具有比常规二芳基碘鎓引发剂更高的溶解性特征的用于阳离子聚合的高碳二芳基碘鎓引发剂。 通过公开的方法，获得了一种新型的光/热引发剂，其特征在于长链酯与芳基的连接，导致连接在碘原子上的整个部分中的总碳原子数超过 20。
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7.发明授权Encapsulation method, microelectronic devices made therefrom, and heat curable compositions based on epoxy resins, diaryliodonium hexafluroantimonate salts and free radical generators 失效封装方法，由其制成的微电子器件和基于环氧树脂的热固化组合物，二芳基碘鎓六氟锑酸盐和自由基发生剂
公开(公告)号：US5015675A
公开(公告)日：1991-05-14
申请号：US386670
申请日：1989-07-31
Applicant: Erik W. Walles , John H. Lupinski , James V. Crivello
Inventor： Erik W. Walles , John H. Lupinski , James V. Crivello
Abstract: A heat curable composition is provided which is useful for encapsulating microelectronic devices using a heat curable epoxy composition having a diaryliodonium hexafluoroantimonate salt as a catalyst in combination with an effective amount of a free radical generating aromatic compound as a cocatalyst.
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公开(公告)号：US4689289A
公开(公告)日：1987-08-25
申请号：US857662
申请日：1986-04-30
Applicant: James V. Crivello
Inventor： James V. Crivello
IPC: C08F293/00 , C08G85/00 , C08K5/00 , C08L53/00 , C08L83/10 , G03F7/075 , G03C1/495 , C08F2/50 , C08F30/08 , C08F230/08
CPC classification number: G03F7/0757 , C08G85/004 , C08K5/0025 , C08L83/10 , Y10S430/114 , Y10S430/122 , Y10S430/126
Abstract: Block polymer compositions are provided which are useful as positive or negative resists utilizing aryl onium salts in combination with silicone-organic block polymers, such as polydimethylsiloxane-poly-t-butylmethacrylate block polymers. A silicone prepolymer is used in combination with certain polymerizable vinyl monomers such as t-butylmethacrylate. The silicone prepolymer has chemically combined pinacolate groups in the backbone or terminal positions which are capable of generating free-radicals upon thermolysis.
Abstract translation: 提供嵌段聚合物组合物，其可用作利用芳基鎓盐与硅氧烷 - 有机嵌段聚合物如聚二甲基硅氧烷 - 聚甲基丙烯酸叔丁酯嵌段聚合物的组合的正性或负性抗蚀剂。 硅氧烷预聚物与某些可聚合的乙烯基单体如甲基丙烯酸叔丁酯组合使用。 硅氧烷预聚物在主链或末端位置化学结合频哪对的基团，这些基团能够在热分解时产生自由基。
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9.发明授权Photopolymerizable organic compositions and diaryliodonium salts used therein 失效其中使用的可光聚合的有机组合物和二芳基碘鎓盐
公开(公告)号：US4683317A
公开(公告)日：1987-07-28
申请号：US721244
申请日：1985-04-08
Applicant: James V. Crivello , Julia L. Lee
Inventor： James V. Crivello , Julia L. Lee
Abstract: Aryliodonium salts resulting from the condensation of aryliodosotosylates and aryl ketones are provided which are used as photoinitiators to effect deep section UV cures. Deep section photopolymerizable organic materials are also provided which can be used as encapsulating agents to encapsulate a wide variety of electronic components.
Abstract translation: 提供由芳基碘代甲酸酯和芳基酮缩合产生的芳基碘盐，其用作光引发剂以实现深部分UV固化。 还提供了深层可光聚合的有机材料，其可以用作封装剂以封装各种各样的电子部件。
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公开(公告)号：US4617238A
公开(公告)日：1986-10-14
申请号：US763758
申请日：1985-08-07
Applicant: James V. Crivello , Richard P. Eckberg
Inventor： James V. Crivello , Richard P. Eckberg
CPC classification number: C08G77/38 , C08K5/0025 , Y10T428/31663
Abstract: Photo-curable vinyloxy-functional organosiloxane polymers are provided. Also provided are release coating compositions made by combining said polymers with various photo-initiators. The polymers have a unique vinyloxy functionality; and the release coating compositions cure with brief exposure to ultraviolet radiation to form premium abhesive coatings. Process for preparing the vinyloxy-functional polysiloxanes and the release coating are also disclosed.
Abstract translation: 提供光固化乙烯基氧基官能的有机硅氧烷聚合物。 还提供了通过将所述聚合物与各种光引发剂组合制备的脱模涂料组合物。 聚合物具有独特的乙烯基氧基官能团; 并且释放涂料组合物在短时间暴露于紫外线辐射下固化以形成优质的粘合剂涂层。 还公开了制备乙烯氧基官能聚硅氧烷和脱模涂层的方法。
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