Abstract:
The invention provides branched trialkylamine oxides with improved properties. The trialkylamine oxides of the invention produced from branched trialkylamines, in one embodiment, can be made using certain branched C10-12 enals and aldehydes. The invention also provides an trialkylamine oxide having the formula: wherein R5, R6 and R7 are independently at least one of C3H7, C2H5, CH3, or H, or mixtures thereof; and wherein R5 and R6 are not H at the same time. In one embodiment, the trialkylamine oxides of the invention can be useful in making various products, for example, as surfactants.
Abstract:
The invention relates to a process for the preparation of nitrosobenzenes from aromatic amines by oxidation with hydrogen peroxide in the presence of sodium molybdate dihydrate and an inert organic solvent.
Abstract:
Disclosed is a process for the preparation of 5-alkoxy-2-nitrosophenols by the nitrosation of 3-alkoxyphenols using an alkali metal nitrite and an alkanoic acid wherein the selectivity of the nitrosation is improved. Also disclosed is a 2-step process for the preparation of 5-alkoxy-2-nitrophenols by oxidizing the 5-alkoxy-2-nitrosophenols obtained in accordance with the present invention.
Abstract:
Tris(disubstituted amino)sulfonium perfluorocarbanion salts, process for their preparation and the use thereof as catalysts in group transfer polymerization.
Abstract:
An improved process for the preparation of nitrosobenzene by catalytically reducing nitrobenzene is disclosed. The improvement comprises performing the reduction in the absence of a reducing agent.
Abstract:
PIGMENTARY COMPOSITIONS COMPRISING AN INTIMATE DISPERSION OF A CRYSTALLINE, LIGHT-STABLE NICKEL CHELATE OF 1NITROSO-2-NAPTHOL AND FROM 0.10 TO 1.0 MOLE, PER MOLE OF THE NICKEL CHELATE, OF CERTAIN ESTER PLASTICIZERS ARE DESCRIBED. THE COMPOSITIONS HAVE IMPROVED TEXTURE AND DISPERSIBILITY AND ARE PRODUCED BY WETTING THE HYDRATED NICKEL CHELATE OF 1-NITROSO-2-NAPHTHOL IN AQUEOUS MEDIUM WITH THE PLASTICIZER, ISOLATING THE WETTED CHELATE AND THEN HEATING THE ISOLATED PRODUCT AT 65-105*C. UNTIL DEHYDRATION IS COMPLETE AND THE CHELATE IS CONVERTED TO ITS CRYSTALLINE, LIGHT-STABLE FORM.
Abstract:
A process for the formation of carbonyl compounds and certain new ketone compositions by reacting the appropriate acyclic or alicyclic Type II, III, IV or V olefin with an organic nitrite in the presence of an acid catalyst. The specific end product(s) produced depend upon the starting olefin, type of organic nitrite employed, etc.
Abstract:
THE COMPOUNS ARE OF THE CLASS OF (P-(3,6-DIHYDRO-2H1,2-OXAZIN- 2-YL)-PHENYL)-ALKANOIC ACIDS, THE METHYL AND ETHYL ESTERS THEREOF, AS WELL AS THE PHARMACEUTICALLY ACCEPTABLE SALTS THEREOF AND HAVE ANALGESIC AND ANTI-INFLAMMATORY ACTIVITY; THE COMPOUNDS ARE ACTIVE INGREDIENTS OF PHARMACEUTICAL COMPOSITIONS AND ARE USEFUL FOR ALLEVIATING PAIN AND TREATING INFLAMMATORY DISEASES IN MAMMALS;AN ILLUSTRATIVE EMBODIMENT IS (P-3,6-DIHYDRO-2H-1,2-OXAZIN2-YL)-PHENYL)-ACETIC ACID.