公开(公告)号：WO2013062410A1

公开(公告)日：2013-05-02

申请号：PCT/NL2012/050741

申请日：2012-10-24

Applicant: STAMICARBON B.V.

Inventor： SCHAAFSMA, Stefan Hendrikus

IPC: B01J2/02 ,  B01J2/26 ,  C05C9/00 ,  C05G3/00

CPC classification number: C05G3/0088 ,  A61K9/1694 ,  B01J2/006 ,  B01J2/02 ,  B01J2/26 ,  C05G3/0029

Abstract: The invention pertains to a method of making urea-containing particles wherein with a lower degree of cooling, high mechanical strengths are obtained. The method comprises the steps of (a) providing a first polymer 10 layer; (b) feeding urea droplets onto said first polymer layer, (c) cooling the droplets provided on the first polymer layer to a temperature between 55º C and 120º C; (d) applying a second polymer layer onto the first polymer layer comprising the droplets so as to form encapsulated urea droplets; and (e) separating the encapsulated urea droplets.

Abstract translation: 本发明涉及一种制备含尿素颗粒的方法，其中在较低的冷却程度下获得高的机械强度。 该方法包括以下步骤：（a）提供第一聚合物10层; （b）将尿素液滴输送到所述第一聚合物层上，（c）将设置在第一聚合物层上的液滴冷却至55℃至120℃之间的温度; （d）将第二聚合物层施加到包含液滴的第一聚合物层上，以形成包封的尿素液滴; 和（e）分离包封的尿素液滴。

公开(公告)号：WO2013015687A1

公开(公告)日：2013-01-31

申请号：PCT/NL2012/050533

申请日：2012-07-26

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER ,  IAQUANIELLO, Gaetano ,  PALO, Emma ,  CONTALDO, Palma

Inventor： IAQUANIELLO, Gaetano ,  PALO, Emma ,  CONTALDO, Palma

IPC: C01B3/38 ,  C01B3/48 ,  C01B3/50 ,  C01B3/56

CPC classification number: C01B3/382 ,  C01B3/384 ,  C01B3/48 ,  C01B3/501 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/068 ,  C01B2203/0883 ,  C01B2203/0888 ,  C01B2203/0894 ,  C01B2203/1023 ,  C01B2203/1029 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2203/142

Abstract: The present invention relates to a process for producing a hydrogen containing gas mixture comprising the following steps: (i) providing a preheated mixture comprising a fossil fuel, preferably methane, and steam, (ii) conducting an adiabatic reaction between the fossil fuel and the steam, in the presence of a catalyst, wherein a first reaction product mixture is formed comprising methane, hydrogen and carbon dioxide, and (iii) conducting an oxygen-assisted reforming reaction in the presence of a catalyst between said first reaction product mixture and an oxygen comprising stream, wherein the oxygen comprising stream comprises at least 40 vol% oxygen, forming a second reaction product mixture comprising hydrogen and carbon monoxide. The invention also relates to a system suitable for hydrogen production from a hydrocarbon feed according to the present invention.

Abstract translation: 本发明涉及一种含氢气体混合物的制备方法，包括以下步骤：（i）提供包含化石燃料，优选甲烷和蒸汽的预热混合物，（ii）在化石燃料与化学燃料之间进行绝热反应 蒸汽，在催化剂存在下，其中形成包含甲烷，氢气和二氧化碳的第一反应产物混合物，和（iii）在催化剂存在下，在所述第一反应产物混合物和 含氧气流，其中所述含氧气流包含至少40体积％的氧气，形成包含氢气和一氧化碳的第二反应产物混合物。 本发明还涉及适用于根据本发明的烃进料的氢气生产的系统。

公开(公告)号：WO2013002638A1

公开(公告)日：2013-01-03

申请号：PCT/NL2012/050455

申请日：2012-06-28

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER ,  UNIVERSITÄT STUTTGART ,  Traa, Yvonne ,  Geiss, Daniel

Inventor： Traa, Yvonne ,  Geiss, Daniel

IPC: C07C2/76 ,  C07C15/02 ,  C07C15/27 ,  C07D213/06

CPC classification number: C07C2/66 ,  B01J29/068 ,  B01J29/44 ,  B01J37/08 ,  B01J37/18 ,  B01J2229/186 ,  C07C2/76 ,  C07C2529/06 ,  C07C2529/40 ,  C07C2529/44 ,  C07C2529/48 ,  C07C2529/65 ,  C07C2529/67 ,  C07C2529/69 ,  C07C2529/85 ,  C07C2531/22 ,  C07D213/06 ,  C07C15/02 ,  C07C15/27

Abstract: Disclosed is a process for the direct alkylation of aromatic compounds with alkanes. To this end a judicious catalyst combination is provided. The composition comprises palladium as a catalytically active metal, and zinc as a promoter, or a metal such as tin having a comparable promoting action. The metals are contained in a zeolite support, or a similar support of a metal organic framework type or a silico alumino phosphate type.

Abstract translation: 公开了用烷烃直接烷基化芳族化合物的方法。 为此，提供了明智的催化剂组合。 组合物包含作为催化活性金属的钯，作为助催化剂的锌，或具有可比较的促进作用的金属如锡。 金属包含在沸石载体中，或类似的金属有机骨架型或硅铝型磷酸盐载体。

公开(公告)号：WO2012134284A1

公开(公告)日：2012-10-04

申请号：PCT/NL2012/050201

申请日：2012-03-28

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER ,  PALO, Emma ,  IAQUANIELLO, Gaetano

Inventor： PALO, Emma ,  IAQUANIELLO, Gaetano

IPC: C07C5/333 ,  C07C7/144 ,  C07C11/02 ,  C07C11/06 ,  B01D53/22

CPC classification number: C07C5/321 ,  B01D53/22 ,  B01D2256/24 ,  B01D2257/108 ,  C07C5/3335 ,  C07C5/3337 ,  C07C2523/26 ,  C07C2523/42 ,  Y10T29/49718 ,  C07C11/02

Abstract: Disclosed is a process for the catalytic dehydrogenation of alkanes so as to form the corresponding olefins. The reaction mixture is subjected to membrane separation of hydrogen, in a separate unit. Preferably a plurality of alternating reaction and separation units is used. The process of the invention serves the purpose of reducing coke formation on the catalyst, and also of achieving a higher alkane conversion without a similar increase in coke formation. The process can also be used for the production of hydrogen.

Abstract translation: 公开了烷烃的催化脱氢以形成相应的烯烃的方法。 将反应混合物在单独的单元中进行氢分离。 优选地，使用多个交替的反应和分离单元。 本发明的方法用于减少催化剂上的焦炭形成，并且还实现了较高的烷烃转化率而没有类似的焦炭形成增加。 该方法也可用于生产氢气。

公开(公告)号：WO2012090182A1

公开(公告)日：2012-07-05

申请号：PCT/IB2011/056026

申请日：2011-12-30

Applicant: STAMICARBON B.V. ,  PASQUALON, Ezio

Inventor： PASQUALON, Ezio

IPC: F01K23/10 ,  F01K23/14

CPC classification number: F01K13/02 ,  F01K23/101 ,  F01K23/14 ,  F01K23/16 ,  F02C6/00 ,  F02C9/00 ,  Y02E20/16

Abstract: A method for startup and management of a combined cycle heating system for the production of power includes the execution of several functional units according to a predefined sequence.

Abstract translation: 用于启动和管理用于生产电力的联合循环加热系统的方法包括根据预定义的顺序执行若干功能单元。

公开(公告)号：WO2012081977A1

公开(公告)日：2012-06-21

申请号：PCT/NL2011/050847

申请日：2011-12-12

Applicant: STAMICARBON B.V. ACTING UNDER THE NAME OF MT INNOVATION CENTER ,  FACCHI, Edoardo

Inventor： FACCHI, Edoardo

IPC: B01J19/18 ,  B01J19/20

CPC classification number: B01J19/1875 ,  B01J19/20 ,  B01J2219/00029 ,  B01J2219/00063 ,  B01J2219/00081 ,  B01J2219/00085 ,  B01J2219/00094 ,  B01J2219/002 ,  B01J2219/00238 ,  B01J2219/00247 ,  B01J2219/00254 ,  C08G69/00

Abstract: Batch reactor comprising a reaction vessel that is longitudinally shaped and has a side wall that encloses a reaction space of the reaction vessel. The reaction vessel is arranged for holding in the reaction space a reaction mixture that comprises polyamide and/or a liquid monomer composition. The reaction further has a bottom wall that further encloses the reaction space. The side wall extends in a longitudinal direction of the reaction vessel that is, in use, directed upwards. The batch reactor has an outer heat exchanger for exchanging heat with the reaction space for enabling a polymerization reaction. The outer heat exchanger covers at least a part of the side wall. The batch reactor comprises an inner heat exchanger that is provided in the reaction space. The inner heat exchanger is, at least partly, surrounded by the outer heat exchanger. The batch reactor comprises an agitator for transporting the reaction mixture.

Abstract translation: 分批反应器包括纵向成形并具有包围反应容器的反应空间的侧壁的反应容器。 反应容器布置成在反应空间中保持包含聚酰胺和/或液体单体组合物的反应混合物。 该反应还具有进一步封闭反应空间的底壁。 侧壁沿着使用中的向上指向的反应容器的纵向方向延伸。 间歇式反应器具有用于与反应空间进行热交换以便进行聚合反应的外部热交换器。 外部热交换器覆盖侧壁的至少一部分。 间歇式反应器包括设置在反应空间中的内部热交换器。 内部热交换器至少部分地被外部热交换器包围。 间歇式反应器包括用于输送反应混合物的搅拌器。

公开(公告)号：WO2011099844A1

公开(公告)日：2011-08-18

申请号：PCT/NL2010/050069

申请日：2010-02-12

Applicant: STAMICARBON B.V. ,  ELIASSON, Johanna ,  ERIKSSON, Ylva ,  Holmstrom David ,  Hulteberg, P. Christian ,  KARLSSON, Hans, T. ,  Nilsson Filip ,  Ojala, Frida ,  VAN DEN TILLAART, Johan, Albert, Arno

Inventor： ELIASSON, Johanna ,  ERIKSSON, Ylva ,  Holmstrom David ,  Hulteberg, P. Christian ,  KARLSSON, Hans, T. ,  Nilsson Filip ,  Ojala, Frida ,  VAN DEN TILLAART, Johan, Albert, Arno

IPC: C07C273/04

CPC classification number: C07C273/04 ,  B01D53/58 ,  B01D2253/102 ,  B01D2253/108 ,  Y02A50/2346 ,  Y02P20/142 ,  Y02P20/582

Abstract: Disclosed is a method for the removal of ammonia from the off-gas of a finishing section of a urea production plant. The method comprises contacting the off-gas with a solid adsorbent capable of physically adsorbing ammonia, particularly activated carbon or zeolite. Thereupon the solid adsorbent having ammonia adsorbed thereon is separated from the gas and regenerated by dissolving ammonia in an extraction liquid, preferably water. After separating the water from the solid adsorbent, the latter is re-used in the process.

Abstract translation: 公开了一种从尿素生产设备的精加工部分的废气中除去氨的方法。 该方法包括使废气与能够物理吸附氨，特别是活性炭或沸石的固体吸附剂接触。 因此，将吸附有氨的固体吸附剂与气体分离，并通过将氨溶解在萃取液中，优选水中再生。 在从固体吸附剂中分离水后，后者在该过程中被重新使用。

公开(公告)号：WO1991017203A1

公开(公告)日：1991-11-14

申请号：PCT/NL1991000072

申请日：1991-04-29

Applicant: STAMICARBON B.V. ,  BASTIAANSEN, Cornelis, Wilhelmus, Maria

Inventor： STAMICARBON B.V.

IPC: C08J05/18

CPC classification number: C08J5/18 ,  B29C55/005 ,  B29K2023/0683 ,  B29K2105/24 ,  C08J2323/06 ,  C08L23/06 ,  C08L2666/04

Abstract: The invention relates to crosslinked oriented high molecular weight polyethylene, containing up to 30 % (wt) crosslinked poly-1,4-butadiene. The poly-1,4-butadiene preferably consists for at least 90 % (mole) of poly-trans-1,4-butadiene. The invention also relates to a process for preparing articles from such polyethylene.

Abstract translation: 本发明涉及交联取向的高分子量聚乙烯，其含有高达30％（重量）的交联聚1,4-丁二烯。 聚-1,4-丁二烯优选为至少90％（摩尔）的聚反式1,4-丁二烯。 本发明还涉及从这种聚乙烯制备制品的方法。

公开(公告)号：WO1991006586A1

公开(公告)日：1991-05-16

申请号：PCT/NL1990000163

申请日：1990-10-30

Applicant: STAMICARBON B.V. ,  HOFLAND, Adriaan ,  PONS, Dick, Adriaan

Inventor： STAMICARBON B.V.

IPC: C08F220/68

CPC classification number: C08F220/68

Abstract: The invention relates to a water-soluble resin that can be used as a dispersant. The resin is substantially built up from units of: A) polyethylene glycol with (5-100) ethylene oxide units, B) a compound containing one or more allyl and/or (meth)acrylate groups and C) the reaction product of one or more unsaturated fatty acids or one or more polyalcohol(s) wholly or partly esterified with unsaturated fatty acids with a compound, where the A:C molar ratio is between 0.5:1 and 4:1 and the B:C molar ratio is between 0.5:1 and 4:1.

Abstract translation: 本发明涉及可用作分散剂的水溶性树脂。 树脂基本上由以下单元组成：A）具有（5-100）环氧乙烷单元的聚乙二醇，B）含有一个或多个烯丙基和/或（甲基）丙烯酸酯基团的化合物，和C）一种或多种 更多不饱和脂肪酸或一种或多种用不饱和脂肪酸与化合物全部或部分酯化的多元醇，其中A：C摩尔比为0.5:1至4:1，B:C摩尔比为0.5 ：1和4：1。

公开(公告)号：WO1991001346A1

公开(公告)日：1991-02-07

申请号：PCT/NL1990000096

申请日：1990-07-16

Applicant: STAMICARBON B.V. ,  PIETERSE, Jan, Karel ,  BASTIAANSEN, Cornelis, Wilhelmus, Maria ,  HEFFELS, Frans ,  PONTENAGEL, Willibrordus, Marie, Gertrud, ...

Inventor： STAMICARBON B.V.

IPC: C08K03/00

CPC classification number: C04B35/63408 ,  C04B35/634 ,  C04B35/63416 ,  C08K3/013 ,  C08K3/22 ,  C08K3/24 ,  H01G4/206 ,  C08L23/06

Abstract: Thin self-supporting green compact, less than 25 mu thick, containing an inorganic substance and as a binder a polymer with a weight average molecular weight of more than 400,000, which polymer in a suitable solvent can form a thermoreversible gel above room temperature, the volume fraction of the inorganic substance being more than 45 % relative to the total amount of binder plus inorganic substance and a process to prepare such green compacts.

Abstract translation: 薄的自支撑生坯，小于25微米厚，含有无机物质和作为粘合剂的重均分子量大于400,000的聚合物，该合成溶剂中的该聚合物可以在室温以上形成热可逆凝胶， 无机物的体积分数相对于粘合剂加无机物质的总量大于45％，以及制备这种生坯的方法。