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公开(公告)号:CA901192A
公开(公告)日:1972-05-23
申请号:CA901192D
Applicant: BASF AG
Inventor: DRUSCHKE WOLFGANG , WIDDER RUDI , MUELLER ALFRED , STANGER BERND , DISTLER HARRY
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公开(公告)号:CA882702A
公开(公告)日:1971-10-05
申请号:CA882702D
Applicant: BASF AG
Inventor: DISTLER HARRY , WIDDER RUDI
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公开(公告)号:CA878527A
公开(公告)日:1971-08-17
申请号:CA878527D
Applicant: BASF AG
Inventor: DISTLER HARRY , WIDDER RUDI
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公开(公告)号:CA823684A
公开(公告)日:1969-09-23
申请号:CA823684D
Applicant: BASF AG
Inventor: HAARER ERICH , DISTLER HARRY , FUCHS FRIEDRICH
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公开(公告)号:CA793346A
公开(公告)日:1968-08-27
申请号:CA793346D
Applicant: BASF AG
Inventor: OSIEKA HANS , DISTLER HARRY , KOENIG KARL-HEINZ , JUNG JOHANN
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公开(公告)号:FR1438645A
公开(公告)日:1966-05-13
申请号:FR16326
申请日:1965-05-07
Applicant: BASF AG
Inventor: DISTLER HARRY , THEWIS JOSEF
IPC: D06M13/248 , D06M13/278
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公开(公告)号:GB1002892A
公开(公告)日:1965-09-02
申请号:GB4365061
申请日:1961-12-06
Applicant: BASF AG
Inventor: FRIEDRICHSEN WILHELM , DISTLER HARRY
IPC: C07C303/30 , C07C309/67 , C08K5/42
Abstract: The invention comprises an unsaturated sulphonic acid aryl ester of the general formula R1.SO2.OR2 in which R1 denotes a hydrocarbon radical having at least five carbon atoms, preferably 5 to 22 carbon atoms, and containing one olefinic double linkage, in d ,e -position to the sulphonic acid ester group, and R2 denotes an aryl radical, preferably phenyl or naphthyl, which may be substituted one to five times by saturated hydrocarbon radicals of 1 to 12 carbon atoms, halogens, alkoxy groups of 1 to 6 carbon atoms and/or esterified carboxyl groups. The novel compounds may be made by reacting a mono-olefine containing at least one methyl or methylene group adjacent to the double linkage with a vinylsulphonic acid aryl ester at a temperature between 100 DEG and 300 DEG C. Pressures from atmospheric up to 200 atm. may be used, if necessary with the use of an inert gas. Suitable starting materials are specified. Examples describe the preparation of the following new compounds: pentene - (1) - sulphonic acid - (5) phenyl ester; 2-methyl-pentene-(1)-sulphonic acid-(5) phenyl ester; 1-phenyl-pentene-(1)-sulphonic acid - (5) o - methylphenyl ester; decene - sulphonic acid o - methylphenyl esters and guaiacol esters; tetradecenesulphonic acid o-methylphenyl esters; tetradecensulphonic acid b -naphthyl esters; 2-methyl-pentene-(1)-sulphonic acid-(5) (11,11,31,31-tetramethylbutyl ester, o - chlorophenyl ester, (21,41 - dichloro) - phenyl ester, (ac-a -tetralyl) ester, (41-chloro-31-methyl)-phenyl ester and phenyl salicylate ester.
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公开(公告)号:FR1408470A
公开(公告)日:1965-08-13
申请号:FR986373
申请日:1964-08-27
Applicant: BASF AG
Inventor: BILLE HEINZ , DISTLER HARRY , DITTUS GEORG , RUEMENS WILHELM
IPC: D06M13/278
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公开(公告)号:FR1392400A
公开(公告)日:1965-03-12
申请号:FR973895
申请日:1964-05-09
Applicant: BASF AG
Inventor: BILLE HEINZ , DISTLER HARRY , DITTUS GEORG , MUELLER WERNER , RUETTIGER WILHELM
IPC: C07C381/12 , D06M13/278
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公开(公告)号:FR1330354A
公开(公告)日:1963-06-21
申请号:FR898204
申请日:1962-05-21
Applicant: BASF AG
Inventor: DISTLER HARRY , LEIBNER GERHARD , FUST KLAUS JUERGEN , POMMER ERNST-HEINRICH , STUMMEYER HERBERT
IPC: A01N41/08 , C07C309/65
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