Abstract:
In the manufacture of aqueous dispersions of polymers of monoolefinically unsaturated carboxylic acid esters by emulsion copolymerization, polymerization is effected in the presence of a mixture of (a) non-ionic emulsifiers, (b) anionic emulsifiers, (c) a protective colloid based on an N-vinyl pyrrolidone polymer and (d) a hydroxyl-containing protective colloid.
Abstract:
New homopolymers and copolymers and their solutions or dispersions having numerous applications are prepared by homopolymerization or copolymerization of olefinically unsaturated sulfitobetaines in bulk, suspension, solution or emulsion.
Abstract:
Aqueous dispersions of copolymers having a glass transition temperature of not more than -45 DEG C. and a K value greater than 80 consist of not less than 80% by weight of acrylates of alkanols of 8 to 12 carbon atoms, from 1 to 4% by weight of alpha , beta - monoolefinically unsaturated carboxylic acids and/or their amide derivatives and from 0.1 to 3% by weight of alpha -methylstyrene, and are used for the production of self-adhesive structures having good tack at as low as -40 DEG C.
Abstract:
1440768 Aqueous dispersions of ester polymers BASF AG 15 Nov 1973 [16 Nov 1972] 52977/73 Heading C3P An aqueous dispersion of a polymer of a mono-olefinically unsaturated carboxylic ester is prepared by emulsion polymerization of said ester in the presence of (a) 0À05 to 7% of a non-ionic emulsifier (b) 0À05 to 5% of an anionic emulsifier (c) 0À01 to 5% of a protective colloid based on an N-vinyl pyrrolidone polymer and (d) 0À01 to 7% of a hydroxyl containing protective colloid which is a polyvinyl alcohol, a water-soluble partially saponified vinyl acetate polymer or a mixture thereof, said percentages being by weight of the total weight of monomer. The non-ionic emulsifier may be an adduct of 25 moles of ethylene oxide and 1 mole of pisooctyl phenol, C 18 fatty alcohol or a fatty alcohol mixture of C 16 -C 19 alcohols, 50% of which' are saturated, and the anionic emulsifier may be the sodium salt of the sulphuric acid monoester of the adduct of 25 moles of ethylene oxide and 1 mole of p-isooctyl or p-nonyl phenol. Examples describe the production of copolymers of (1) vinyl acetate, vinyl 2-ethylhexanate and crotonic acid, (2) ethyl acrylate, acrylic acid and sodium vinylsulphonate, (3) vinyl acetate, dibutyl maleate, acrylic acid and sodium vinyl sulphonate, (4) styrene, 2-ethylhexyl acrylate, acrylic acid and sodium vinyl sulphonate, (5) vinyl acetate, n-butyl acrylate, acrylic acid and sodium vinyl sulphonate, (6) as (5) plus butanediol-1,4-diacrylate, and (7) vinyl acetate, 2-ethylhexyl acrylate and acrylic acid.
Abstract:
Aqueous dispersions of copolymers of (a) from 70 to 85% by weight of nontertiary butyl (meth)acrylates, (b) from 8 to 27.2% by weight of (meth)acrylates (A) whose homopolymers have a glass transition temperature greater than that of the polybutyl (meth)acrylate up to 0.degree.C and (meth)acrylates (B) whose homopolymers have a glass transition temperature below that of the polybutyl (meth)acrylate, the weight ratio of the (meth)acrylates (A) to the (meth)acrylates (B) being from 3 : 1 to 1 : 3, (c) from 2 to 15% by weight of methyl methacrylate, styrene and/or acrylonitrile and (d) from 0.8 to 5% by weight of monoolefinically un saturated mono- and/or dicarboxylic acids of 3 to 5 carbon atoms and/or their amides which are unsubstituted or substituted at the nitrogen atoms by alkyl and/or alkylol radicals of 1 to 4 carbon atoms and/or hydroxyalkyl (meth)acrylates where the alkyl groups are of 2 to 5 carbon atoms, are used for coating sheet-like substrates.
Abstract:
Contact adhesive dispersions contain (A) an aqueous dispersion of a copolymer A which has a glass transition temperature below 0.degree.C and consists of (a) from 50 to 99 % by weight of esters of acrylic acid with non-tertiary alkanols, (b) from 0 to 50 % by weight of esters of acrylic or methacrylic acid and/or vinyl esters and/or (meth)acrylonitrile and/or styrene and/or tert.butyl acrylate, (c) from 0.5 to 5 % by weight of monoolefinitally unsaturated carboxylic acids and/or their amides which are unsubstituted or substituted at the nitrogen atoms by alkyl and/or alkylol radicals, and/or hydroxyalkyl (meth)acrylates, and (d) from 0.5 to 5% by weight of carbonylcontaining monomers and (8) from 0.05 to 2 moles of a water-soluble dihydrazine compound per mole of carbonyl groups present in the copolymer A.
Abstract:
Crosslinkable polymeric compositions which are dissolved or dispersed in an organic solvent, a process for their preparation and their use. These polymeric compositions which undergo crosslinking at room temperature or elevated temperatures after drying are obtained by reacting polymeric organic compounds containing carbonyl groups with polyhydrazides in the presence of monoketones or monoaldehydes. They are useful as crosslinking agents for polyepoxide compounds.