MANUFACTURE OF AQUEOUS DISPERSIONS OF POLYMERS OF MONOOLEFINICALLY UNSATURATED CARBOXYLIC S

    公开(公告)号:CA1018690A

    公开(公告)日:1977-10-04

    申请号:CA185879

    申请日:1973-11-15

    Applicant: BASF AG

    Abstract: 1440768 Aqueous dispersions of ester polymers BASF AG 15 Nov 1973 [16 Nov 1972] 52977/73 Heading C3P An aqueous dispersion of a polymer of a mono-olefinically unsaturated carboxylic ester is prepared by emulsion polymerization of said ester in the presence of (a) 0À05 to 7% of a non-ionic emulsifier (b) 0À05 to 5% of an anionic emulsifier (c) 0À01 to 5% of a protective colloid based on an N-vinyl pyrrolidone polymer and (d) 0À01 to 7% of a hydroxyl containing protective colloid which is a polyvinyl alcohol, a water-soluble partially saponified vinyl acetate polymer or a mixture thereof, said percentages being by weight of the total weight of monomer. The non-ionic emulsifier may be an adduct of 25 moles of ethylene oxide and 1 mole of pisooctyl phenol, C 18 fatty alcohol or a fatty alcohol mixture of C 16 -C 19 alcohols, 50% of which' are saturated, and the anionic emulsifier may be the sodium salt of the sulphuric acid monoester of the adduct of 25 moles of ethylene oxide and 1 mole of p-isooctyl or p-nonyl phenol. Examples describe the production of copolymers of (1) vinyl acetate, vinyl 2-ethylhexanate and crotonic acid, (2) ethyl acrylate, acrylic acid and sodium vinylsulphonate, (3) vinyl acetate, dibutyl maleate, acrylic acid and sodium vinyl sulphonate, (4) styrene, 2-ethylhexyl acrylate, acrylic acid and sodium vinyl sulphonate, (5) vinyl acetate, n-butyl acrylate, acrylic acid and sodium vinyl sulphonate, (6) as (5) plus butanediol-1,4-diacrylate, and (7) vinyl acetate, 2-ethylhexyl acrylate and acrylic acid.

    CONTACT ADHESIVE DISPERSIONS FOR THE PRODUCTION OF SELF-ADHESIVE ARTICLES

    公开(公告)号:CA1245794A

    公开(公告)日:1988-11-29

    申请号:CA455059

    申请日:1984-05-24

    Applicant: BASF AG

    Abstract: Contact adhesive dispersions contain (A) an aqueous dispersion of a copolymer A which has a glass transition temperature below 0.degree.C and consists of (a) from 50 to 99 % by weight of esters of acrylic acid with non-tertiary alkanols, (b) from 0 to 50 % by weight of esters of acrylic or methacrylic acid and/or vinyl esters and/or (meth)acrylonitrile and/or styrene and/or tert.butyl acrylate, (c) from 0.5 to 5 % by weight of monoolefinitally unsaturated carboxylic acids and/or their amides which are unsubstituted or substituted at the nitrogen atoms by alkyl and/or alkylol radicals, and/or hydroxyalkyl (meth)acrylates, and (d) from 0.5 to 5% by weight of carbonylcontaining monomers and (8) from 0.05 to 2 moles of a water-soluble dihydrazine compound per mole of carbonyl groups present in the copolymer A.

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