公开(公告)号：SK12382000A3

公开(公告)日：2001-03-12

申请号：SK12382000

申请日：1999-02-23

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A material useful as catalyst for the hydrogenation of alpha, omega-dinitriles comprises (a) iron or a compound based on iron or mixtures thereof, (b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium, (c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal, and also (d) from 0.001 to 1% by weight based on (a) of manganese.

公开(公告)号：ID26184A

公开(公告)日：2000-12-07

申请号：ID20001718

申请日：1999-02-23

Applicant: BASF AG

Inventor： VOIT HUIDO ,  OHLBACH FRANK ,  LUYKEN HERMANN ,  MERGER MARTIN ,  REHFINGER ALWIN ,  FISCHER ROLF HARTMUTH ,  BASSLER PETER ,  ANSMANN ANDREAS

IPC: B01J23/02 ,  B01J23/78 ,  C07B61/00 ,  C07C209/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A process for hydrogenation of aliphatic alpha, omega-dinitriles in the presence of a heterogeneous fixed bed catalyst comprises using a reaction mixture comprising from 2 mumol to 30 mmol NA, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, based on 10 mol of aliphatic alpha, omega-dinitrile used.

公开(公告)号：BR9908505A

公开(公告)日：2000-12-05

申请号：BR9908505

申请日：1999-02-23

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A material useful as catalyst for the hydrogenation of alpha, omega-dinitriles comprises (a) iron or a compound based on iron or mixtures thereof, (b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium, (c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal, and also (d) from 0.001 to 1% by weight based on (a) of manganese.

公开(公告)号：BR9908504A

公开(公告)日：2000-12-05

申请号：BR9908504

申请日：1999-02-23

Applicant: BASF AG

Inventor： VOIT GUIDO ,  OHLBACH FRANK ,  LUYKEN HERMANN ,  MERGER MARTIN ,  REHFINGER ALWIN ,  FISCHER ROLF HARTMUTH ,  BASSLER PETER ,  ANSMANN ANDREAS

IPC: B01J23/02 ,  B01J23/78 ,  C07B61/00 ,  C07C209/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A process for hydrogenation of aliphatic alpha, omega-dinitriles in the presence of a heterogeneous fixed bed catalyst comprises using a reaction mixture comprising from 2 mumol to 30 mmol NA, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, based on 10 mol of aliphatic alpha, omega-dinitrile used.

公开(公告)号：ID26108A

公开(公告)日：2000-11-23

申请号：ID20001717

申请日：1999-02-23

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/745 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A process for preparing aliphatic alpha, omega-diamines by hydrogenation of aliphatic alpha, omega-dinitriles in the presence of a catalyst comprises using a hydrogenation catalyst comprising(a) iron or a compound based on iron or mixtures thereof,(b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium, and also(c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal.

公开(公告)号：DE19850300A1

公开(公告)日：2000-05-04

申请号：DE19850300

申请日：1998-10-30

Applicant: BASF AG

Inventor： FISCHER ROLF ,  LIANG SHELUE ,  MERGER MARTIN ,  WULFF-DOERING JOACHIM

IPC: C07C29/149 ,  C07B41/02 ,  C07C27/00

Abstract: The invention relates to a method for the production of alcohols by vapor phase hydrogenation of carboxylic acids having formula R-COOH, wherein R represents aliphatic, cycloaliphatic, aromatic or heterocyclic radicals or the esters thereof at a high temperature and pressure in the presence of catalysts containing as hydrogenating components oxides of the elements of the fourth main group and/or sub-groups or consisting thereof, wherein hydrogenation is carried out without adding alcohols that are suitable as hydrogen carriers at temperatures ranging from 250 DEG C to 400 DEG C and pressures in the range of 25 bar to 60 bar.

公开(公告)号：AU5976299A

公开(公告)日：2000-04-10

申请号：AU5976299

申请日：1999-09-10

Applicant: BASF AG

Inventor： MERGER MARTIN ,  FISCHER ROLF ,  ANSMANN ANDREAS

IPC: C07D223/04 ,  C07B61/00 ,  C07D201/02 ,  C07D223/10 ,  C07D295/023 ,  C07D295/02

Abstract: A cyclic lactam and a cyclic amine are coproduced by reacting an aliphatic alpha, omega-diamine with water in the gas phase in the presence of a heterogeneous catalyst.

公开(公告)号：AU5736099A

公开(公告)日：2000-03-21

申请号：AU5736099

申请日：1999-08-17

Applicant: BASF AG

Inventor： FISCHER ROLF ,  BASSLER PETER ,  LUYKEN HERMANN ,  OHLBACH FRANK ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  ANSMANN ANDREAS ,  REHFINGER ALWIN DR ,  VOIT GUIDO

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/86 ,  C07C211/12

Abstract: A process for catalytic hydrogenation of adiponitrile to hexamethylenediamine at elevated temperature and elevated pressure in the presence of catalysts based on elemental iron as catalytically active component and ammonia as solvent comprisesa) hydrogenating adiponitrile at from 70 to 220° C. and from 100 to 400 bar in the presence of catalysts based on elemental iron as catalytically active component and ammonia as solvent to obtain a mixture comprising adiponitrile,6-aminocapronitrile, hexamethylenediamine and high boilers until the sum total of the 6-aminocapronitrile concentration and the adiponitrile concentration is within the range from 1 to 50% by weight, based on the ammonia-free hydrogenation mixture,b) removing ammonia from the hydrogenation effluent,c) removing hexamethylenediamine from the remaining mixture,d) separating 6-aminocapronitrile and adiponitrile from high boilers individually or together, ande) returning 6-aminocapronitrile, adiponitrile or mixtures thereof into step a).

公开(公告)号：DE19831889A1

公开(公告)日：2000-01-27

申请号：DE19831889

申请日：1998-07-17

Applicant: BASF AG

Inventor： FISCHER ROLF ,  BASLER PETER ,  LUYKEN HERMANN ,  OHLBACH FRANK ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  ANSMANN ANDREAS ,  REHFINGER ALWIN ,  VOIT GUIDO

IPC: C07C209/48 ,  C07C211/12 ,  C07C209/82

Abstract: The production of hexamethylenediamine (HDA) from adiponitrile (ADN) involves hydrogenation in ammonia with an iron-based catalyst, followed by removal of ammonia, separation of HDA, separation of 6-aminocapronitrile (ACN) and ADN from high-boilers and returning ACN and/or ADN to the hydrogenation stage. A process for the catalytic hydrogenation of adiponitrile (ADN) to hexamethylenediamine (HDA) comprises: (a) hydrogenation of ADN at 70-220 deg C and 100-400 bar in presence of a catalyst based on elementary iron as the active component and with ammonia as solvent, to give a mixture containing ADN, 6-aminocapronitrile (ACN ), HDA and high-boiling products, until the total concentration of ACN and ADN is 1-50 wt.% based on the ammonia-free hydrogenation mixture, (b) removing ammonia, (c) separating HDA, (d) separating ACN and ADN (individually or together) from the high-boilers and (e) recycling ACN and/or ADN to stage (a).

公开(公告)号：AU3408699A

公开(公告)日：1999-09-20

申请号：AU3408699

申请日：1999-02-23

Applicant: BASF AG

Inventor： VOIT GUIDO ,  OHLBACH FRANK ,  LUYKEN HERMANN ,  MERGER MARTIN ,  REHFINGER ALWIN DR ,  FISCHER ROLF HARTMUTH ,  BASSLER PETER ,  ANSMANN ANDREAS

IPC: B01J23/02 ,  B01J23/78 ,  C07B61/00 ,  C07C209/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A process for hydrogenation of aliphatic alpha, omega-dinitriles in the presence of a heterogeneous fixed bed catalyst comprises using a reaction mixture comprising from 2 mumol to 30 mmol NA, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, based on 10 mol of aliphatic alpha, omega-dinitrile used.