公开(公告)号：WO03035250A8

公开(公告)日：2003-07-24

申请号：PCT/EP0211669

申请日：2002-10-18

Applicant: BASF AG ,  ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

IPC: B01J37/18 ,  B01J23/745 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

CPC classification number: C07C253/30 ,  B01J23/745 ,  B01J23/8892 ,  C07C209/48 ,  C07C211/12 ,  C07C255/24

Abstract: The iron-containing catalyst suitable for use as a catalyst contains a) iron or a mixture containing iron and an iron-based compound. The iron has an average crystallite size ranging from 1-35 nm measured by X-ray diffraction.

Abstract translation: 适合的催化剂，其包含a）铁或含有铁和基于铁的化合物的混合物，其中通过X射线衍射测量，所述铁的平均平均微晶尺寸为1至35nm。

公开(公告)号：WO03035249A8

公开(公告)日：2003-07-24

申请号：PCT/EP0211667

申请日：2002-10-18

Applicant: BASF AG ,  ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

IPC: B01J37/18 ,  B01J23/745 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12

CPC classification number: B01J23/745

Abstract: The oxidic material suitable for use as a hydrogenation catalyst contains a) bivalent and trivalent iron, the atomic ratio of bivalent iron to trivalent iron ranging from more than 0.5 to 5.5, and b) oxygen as a counter ion to the bivalent and trivalent iron.

Abstract translation: 作为催化剂前体合适的氧化性组合物包含：a）二价铁和三价铁，其特征在于，三价铁在大于0.5的范围内的二价铁的原子比高达5.5是，和b）氧作为抗衡离子的二价铁和 铁三价。

公开(公告)号：WO9944982A3

公开(公告)日：1999-11-25

申请号：PCT/EP9901149

申请日：1999-02-23

Applicant: BASF AG ,  VOIT GUIDO ,  OHLBACH FRANK ,  LUYKEN HERMANN ,  MERGER MARTIN ,  REHFINGER ALWIN ,  FISCHER ROLF HARTMUTH ,  BASSLER PETER ,  ANSMANN ANDREAS

Inventor： VOIT GUIDO ,  OHLBACH FRANK ,  LUYKEN HERMANN ,  MERGER MARTIN ,  REHFINGER ALWIN ,  FISCHER ROLF HARTMUTH ,  BASSLER PETER ,  ANSMANN ANDREAS

IPC: B01J23/02 ,  B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

CPC classification number: C07C253/30 ,  B01J23/02 ,  B01J23/78 ,  C07C209/48 ,  C07C211/12 ,  C07C255/24

Abstract: The invention relates to a method for hydrogenating aliphatic alpha-, omega-dinitriles in the presence of a heterogeneous fixed-bed catalyst. The method is characterised in that the reaction mixture contains 2 mu mol to 30 mmol Na, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, in relation to 10 mol of the aliphatic alpha-, omega-dinitrile used.

Abstract translation: 一种用于在多相固定床催化剂存在的脂族α，ω-二腈的氢化方法，其特征在于，所述反应混合物2亩摩尔〜30的Na，K，铷，铯，镁，钙，锶，钡或Mn或它们的混合物的毫摩尔 在碱性盐的基于脂族α的10个摩尔的形式，ω-二腈中含有。

公开(公告)号：WO2006042675A2

公开(公告)日：2006-04-27

申请号：PCT/EP2005010956

申请日：2005-10-12

Applicant: BASF AG ,  DECKERT PETRA ,  BASSLER PETER ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  PFAB PETER ,  AECHTNER TOBIAS ,  SIEGEL WOLFGANG

Inventor： DECKERT PETRA ,  BASSLER PETER ,  BARTSCH MICHAEL ,  HADERLEIN GERD ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  PFAB PETER ,  AECHTNER TOBIAS ,  SIEGEL WOLFGANG

CPC classification number: B01J31/4053 ,  B01D11/0434 ,  B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J31/403 ,  B01J2231/323 ,  B01J2531/847 ,  C07C253/10 ,  C07C253/32 ,  Y02P20/584 ,  C07C255/04

Abstract: The invention relates to a method for the extractive separation of homogeneously dissolved catalysts from a reaction product from a hydrocyanation of unsaturated mononitriles to dinitriles, by extraction with a carbon material (K), characterised in that a) a non-polar aprotic liquid (F) is added to the reaction product to give a stream (I) and b) the stream (I) is extracted with a carbon material (K) at a temperature (T), to give a stream (II), containing the carbon material (K), enriched with the catalyst and a stream (III), stripped of catalyst.

Abstract translation: 通过烃的装置（K），其特征在于用于由不饱和单腈向二腈，通过萃取的氢氰化反应流出物均匀溶解的催化剂的提取分离方法，包括：a）向所述反应在非极性非质子液体（F），由此电流 在温度（T）（与烃K（I）获得，以及b）的电流（I））被提取，其特征在于，一个流（II）含有富含与催化剂烃（K）和催化剂贫流（ III）。

公开(公告)号：WO2004050587A2

公开(公告)日：2004-06-17

申请号：PCT/EP0313624

申请日：2003-12-03

Applicant: BASF AG ,  BASSLER PETER ,  SIEGEL WOLFGANG ,  ACHHAMMER GUENTHER ,  NEGELE ANTON ,  MENIG HELMUTH ,  RUPPEL WILHELM ,  ZEHNER PETER ,  LUYKEN HERMANN ,  VOGT VOLKER

Inventor： BASSLER PETER ,  SIEGEL WOLFGANG ,  ACHHAMMER GUENTHER ,  NEGELE ANTON ,  MENIG HELMUTH ,  RUPPEL WILHELM ,  ZEHNER PETER ,  LUYKEN HERMANN ,  VOGT VOLKER

IPC: B01J12/00 ,  B01J15/00 ,  B01J19/02 ,  B01J19/24 ,  B01J23/86 ,  C01C3/02 ,  C07C

CPC classification number: C01C3/0204 ,  B01J12/007 ,  B01J15/005 ,  B01J19/02 ,  B01J19/2415 ,  B01J23/866 ,  B01J2219/00135 ,  B01J2219/0236

Abstract: The invention relates to a method for producing hydrocyanic acid (HCN) by means of catalytic dehydration of gaseous formamide in a reactor having an inner reactor surface consisting of a steel-containing iron, chromium and nickel. The invention also relates to a reactor for producing hydrocyanic acid by means of catalytic dehydration of gaseous formamide, said reactor having an inner reactor surface consisting of a steel-containing iron, chromium and nickel. The invention further relates to the use of the inventive reactor in a method for producing hydrocyanic acid by means of catalytic dehydration of gaseous formamide.

Abstract translation: 本发明涉及一种通过气态甲酰胺的催化脱水反应器中制备由气态催化脱水具有用于生产氢氰酸的由钢制成的反应器内表面，包括铁和铬和镍，以及一个反应器氢氰酸（HCN） 甲酰胺，其具有由包含铁和铬和镍，以及在方法中的用途本发明的反应器用于通过气态甲酰胺的催化脱水制备氢氰酸的钢的反应器内表面的反应器中。

公开(公告)号：WO0202545A8

公开(公告)日：2002-06-20

申请号：PCT/EP0107717

申请日：2001-07-05

Applicant: BASF AG ,  TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BASSLER PETER ,  WENZEL ANNE ,  RIEBER NORBERT ,  RUDOLF PETER

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BASSLER PETER ,  WENZEL ANNE ,  RIEBER NORBERT ,  RUDOLF PETER

IPC: C07D301/12 ,  C07D301/32

CPC classification number: C07D301/32 ,  C07D301/12 ,  Y10S203/22 ,  Y10S203/24

Abstract: The invention relates to a method for the production of propylene oxide in the presence of methanol, during which propylene oxide is separated off from a mixture, comprising propylene oxide and methanol and the resulting mixture comprising methanol is worked up. The invention is characterised in that on working up, methanol is separated from a mixture containing methanol and methyl formate.

Abstract translation: 一种用于在甲醇的存在，这是从一混合物，其包含环氧丙烷和甲醇，环氧丙烷和包含甲醇所得到的混合物中分离制备环氧丙烷的过程中，在后处理，其特征在于所述后处理的混合物的包含甲醇和甲基 ，甲醇分离。

公开(公告)号：AU2003293755B2

公开(公告)日：2009-12-24

申请号：AU2003293755

申请日：2003-12-03

Applicant: BASF AG

Inventor： BASSLER PETER ,  ZEHNER PETER ,  LUYKEN HERMANN ,  MENIG HELMUTH ,  ACHHAMMER GUNTHER ,  RUPPEL WILHELM ,  VOGT VOLKER ,  SIEGEL WOLFGANG ,  NEGELE ANTON

IPC: C01C3/02 ,  B01J12/00 ,  B01J15/00 ,  B01J19/02 ,  B01J19/24 ,  B01J23/86

公开(公告)号：CA2342178C

公开(公告)日：2008-12-02

申请号：CA2342178

申请日：1999-08-17

Applicant: BASF AG

Inventor： VOIT GUIDO ,  ANSMANN ANDREAS ,  REHFINGER ALWIN ,  MERGER MARTIN ,  MELDER JOHANN-PETER ,  OHLBACH FRANK ,  LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF

IPC: C07C209/48 ,  C07B61/00 ,  C07C209/86 ,  C07C211/12

Abstract: The invention relates to a method for the catalytic hydrogenation of adipodinitrile to hexamethylene diamine at a high temperature and at high pressure in the presence of catalysts based on elementary iron as th e catalytic component, and ammonia as a solvent. The method is characterised in that a) adipodinitrile is hydrogenated at temperatures o f 70 to 220 .degree.C and at pressures of 100 to 400 bar in the presence of catalysts based on elementary iron as the catalytic component, and ammoni a as a solvent to produce a mixture containing adipodinitrile, 6-aminocapronitrile, hexamethylene diamine and high boilers, until the sum o f the 6-aminocapronitrile and adipodinitrile concentration is 1 to 50 wt. 3% in relation to the ammonia-free hydrogenation mixture; b) ammonia is separated out of the hydrogenation discharge; c) hexamethylene diamine is separated out of the remaining mixture; d) 6- aminocapronitrile and adipodinitrile are separated from the high boilers together or separately and e) 6-aminocapronitrile, adipodinitrile or their mixtures are returned to step a).

公开(公告)号：BR0207063A

公开(公告)日：2008-07-22

申请号：BR0207063

申请日：2002-02-06

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BERG ANNE ,  RUDOLF PETER ,  RIEBER NORBERT ,  BASSLER PETER

IPC: C07D301/12 ,  C07D301/19 ,  C07D301/32 ,  C07D303/04

Abstract: An organic compound having at least one C-C double bond is epoxidized by means of hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent, wherein a product mixture comprising alpha-hydroperoxyalcohols is reduced using at least one reducing agent. The process advantageously comprises at least the following steps: (i) reacting an organic compound having at least one C-C double bond with hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent to give a product mixture P1 comprising alpha-hydroperoxyalcohols; (ii) separating an epoxide formed in the reaction in step (i) and the unreacted organic compound having at least one C-C double bond from P1 or P1' to give a product mixture P2 or P2', where P2 comprises the alpha-hydroperoxyalcohols formed as by-product in the reaction in step (i) and P2' is largely free of alpha-hydroperoxyalcohols; (iii) treating P1 and/or P2 with at least one reducing agent so that the alpha-hydroperoxyalcohols are converted into corresponding glycols to give a product mixture P1' or P3.

公开(公告)号：PL383682A1

公开(公告)日：2008-04-14

申请号：PL38368204

申请日：2004-02-24

Applicant: BASF AG

Inventor： BARTSCH MICHAEL ,  BAUMANN ROBERT ,  HADERLEIN GERD ,  FLORES MIGUEL ,  JUNGKAMP TIM ,  LUYKEN HERMANN ,  SCHEIDEL JENS ,  SIEGEL WOLFGANG ,  BASSLER PETER

IPC: C07C253/10 ,  C07C253/34 ,  C07C255/04