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公开(公告)号:JPH08231975A
公开(公告)日:1996-09-10
申请号:JP3645395
申请日:1995-02-24
Applicant: BRIDGESTONE CORP , TOKYO SILICONE KK
Inventor: MIYANO MARI , SAITO TASUKU , ARAI HISAMI , KIDA NOBUTSUGU , YUSA SACHIKO
IPC: F16F9/53 , C08L83/04 , C10M107/50 , C10M169/04 , C10M177/00 , C10N20/00 , C10N20/02 , C10N20/04 , C10N20/06 , C10N30/00 , C10N30/08 , C10N40/14 , C10N70/00
Abstract: PURPOSE: To obtain an oily medium excellent in stability at elevated temperatures, and to obtain an electroviscous fluid using the medium, having high electroviscous fluid effect with low power consumption and excellent in response and stability at elevated temperatures. CONSTITUTION: This oily medium consists of a polymer obtained by heat treatment of a siloxane polymer composed of 0-90mol% of dimethylsiloxane unit and 10-100mol% of 3,3,3-trfluoropropylmethylsiloxane unit. The number - average molecular weight and the dispersion degree of the molecular weight distribution of the siloxane polymer in this medium stand at 500-1000 and 1.05-1.25, respectively. The amount of ionic impurities contained in the medium is 5ppm or less. The other objective electroviscous fluid is obtained by dispersing dielectric particles in this oily medium.
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公开(公告)号:JPH08143886A
公开(公告)日:1996-06-04
申请号:JP29102694
申请日:1994-11-25
Applicant: BRIDGESTONE CORP
Inventor: MIYANO MARI , SAKURAI MAKOTO , SHII HAWAADO , SAITO TASUKU
Abstract: PURPOSE: To obtain the subject fluid consisting of a specific carbonaceous pow der and silicone oil, excellent in electroviscus characteristics in wide temperature area, having low initial viscosity, free from settling of disperse phase, excellent in re-dispersibility, long-term dispersibility, long-term stability and responsiveness in application of electric field and requiring a small consumed power. CONSTITUTION: This fluid comprises (A) 1-60wt.% of carbonaceous powder having dielectric (e.g. carbonaceous powder having 0.01-100μm average particle diameter and obtained by carrying out thermal polymerization of a condensed polycyclic aromatic compound consisting essentially of naphthalene as a main component in the presence of HF/BF3 catalyst, carrying out heat treatment of the resultant 100% mesophase pitch having 150-400 deg.C softening point at a temperature of 50-400 deg.C not higher than its melting point in an oxidizing atmosphere so as to give 5-25wt.% oxygen content in the pitch, then carrying out heat treatment of the pitch at 300-700 deg.C in an inert gas atmosphere to carbonize the pitch so as to give 3-20wt.% oxygen content in the pitch) and (B) a modified silicone oil (e.g. a polyether-modified, epoxy-modified, methacrylic acid-modified or carbinol-modified silicone oil) contained in an amount of 0.1-20% based on the component A and having 0.65-1000cSt viscosity at 25 deg.C.
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公开(公告)号:JPH07173485A
公开(公告)日:1995-07-11
申请号:JP32284893
申请日:1993-12-21
Applicant: BRIDGESTONE CORP
Inventor: SAKURAI MAKOTO , OGINO TAKAO , SAITO TASUKU
IPC: C10M169/04 , C10N40/14
Abstract: PURPOSE:To provide a fluid which has a high electroviscous effect to attain small power consumption and is excellent in response and stability in production. CONSTITUTION:This fluid comprises a particulate carbonaceous substance dispersed in an oily medium having electrical-insulating properties, and contains substantially no impurities which are positively or negatively charged upon application of an electric current. The content of these impurities is preferably not higher than 1,000ppm in the fluid.
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公开(公告)号:JPH0718283A
公开(公告)日:1995-01-20
申请号:JP16229193
申请日:1993-06-30
Applicant: KAWASAKI STEEL CO , BRIDGESTONE CORP
Inventor: HATANO HITOMI , HARAOKA TAKUJI , FUKUDA NORIYOSHI , TAKAGI KO , MARUYAMA TAKAYUKI , SAITO TASUKU , OGINO TAKAO
IPC: B01J13/00 , C01B31/02 , C10M125/02 , C10N20/00 , C10N20/06 , C10N40/04 , C10N40/08 , C10N40/14 , C10N70/00
Abstract: PURPOSE:To provide an electroviscous fluid which has excellent electroviscous characteristics such as an excellent response due to the much more stable viscosity or electric current under applied voltage than the conventional ones and a low electric current under applied voltage. CONSTITUTION:An electroviscous fluid is obtd. by using, as fine dielectric particles, a carbonaceous powder which provides an extract having an extinction of 2.5 or lower at a certain wavelength in the range of 400-500nm when the powder is extracted with the same wt. of toluene at its b.p. for 10min or longer.
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公开(公告)号:JPH06279018A
公开(公告)日:1994-10-04
申请号:JP4058091
申请日:1991-02-13
Applicant: BRIDGESTONE CORP
Inventor: FUKUYAMA YOSHIKI , KURACHI IKUO , ISHINO YUICHI , SAITO TASUKU
IPC: C01B33/26 , C01B33/40 , C10M103/00 , C10N30/02 , C10N40/14
Abstract: PURPOSE:To obtain composite powder of carbon/layered clay mineral expected for uses as dispersing phase solid particles in electroviscous fluid, a filler for providing electric characteristics to high polfmers or improving rubber elasticity, a catalyst, a heat resistant material, an electrically conductive material for electrode materials, etc., and a precursor for synthesizing fine ceramic powder, and an electroviscous fluid containing the powder as a dispersing phase. CONSTITUTION:This composite powder of carbon/layered clay mineral contains 2-20wt.% carbon between layers of powder particles of layer clay mineral. The electroviscous fluid is composed of 1-60wt.% dispersing phase consisting of a carbon/layered clay mineral composite powder containing 2-20wt.% carbon between layers of powder particles of the layered clay mineral and having 0.01-100mum average particle diameter and 40-99wt.% liquid phase consisting of an electrical insulating oil having 0.65-1000cSt kinematic viscosity at ambient temperature.
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公开(公告)号:JPH06234985A
公开(公告)日:1994-08-23
申请号:JP2115993
申请日:1993-02-09
Applicant: KAWASAKI STEEL CO , BRIDGESTONE CORP
Inventor: HARAOKA TAKUJI , HATANO HITOMI , FUKUDA NORIYOSHI , SAITO TASUKU , OGINO TAKAO , MARUYAMA TAKAYUKI
IPC: B01J13/00 , C01B31/02 , C10M103/02 , C10N40/14 , C10N70/00
Abstract: PURPOSE:To obtain an electroviscous fluid which, upon application of a given voltage, undergoes a viscosity change at a lower value of electric current flowing through the fluid and which has a low initial viscosity. CONSTITUTION:The electroviscous fluid is a dispersion of either a particulate carbonaceous substance produced through melting at 300-500 deg.C or a particulate carbonaceous substance produced from a material scarcely containing any nitrogen, oxygen, and sulfur.
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公开(公告)号:JPH06234512A
公开(公告)日:1994-08-23
申请号:JP2019893
申请日:1993-02-08
Applicant: KAWASAKI STEEL CO , BRIDGESTONE CORP
Inventor: HARAOKA TAKUJI , TAKAGI KO , HATANO HITOMI , FUKUDA NORIYOSHI , MARUYAMA TAKAYUKI , OGINO TAKAO , SAITO TASUKU
IPC: C01B31/02 , C10M125/02
Abstract: PURPOSE:To produce an electroviscous fluid reduced in the viscosity at the time of applying no voltage (initial viscosity). CONSTITUTION:In the electroviscous fluid obtained by dispersing a dielectric particulate in an oily medium excellent in electric insulation, the specific surface area of the particle used as a dispersoid is controlled to /g. The particle has preferably 0.5-40mum particle diameter, =20mum particle diameter and
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公开(公告)号:JPH05120913A
公开(公告)日:1993-05-18
申请号:JP30843691
申请日:1991-10-28
Applicant: BRIDGESTONE CORP
Inventor: SAKURAI MAKOTO , KURACHI IKUO , FUKUYAMA YOSHIKI , MARUYAMA TAKAYUKI , SAITO TASUKU
IPC: C08K3/00 , C08L101/00 , H01B1/20
Abstract: PURPOSE:To provide functional gel and a soft plastic body whose viscoelasticity can be extensively changed by applying an electric field. CONSTITUTION:At least one kind or more of fine powder bodies, whose mean particle diameter is 0.5-5.00mum, being selected from B-(1) the fine powder body, whose conductivity, under a dispersed state in a matrix phase, is one tenth or less of the conductivity of the matrix phase, (2) the fine powder body, whose conductivity, under the dispersed state in the matrix phase, is ten times or more of the conductivity of the matrix phase, and (3) the fine powder body being composed of two dimensional layer-like complex particles are dispersed in electrically insulating high polymer material, being selected from A-(1) a high polymer, whose viscosity is 10 centistokes or more, and (2) partially crosslinked high polymer gel-like medium, whose penetration is 40 or more at a room temperature, so as to produce an electrically responsive soft plastic body or electrically responsive gel.
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公开(公告)号:JPH055099A
公开(公告)日:1993-01-14
申请号:JP28037991
申请日:1991-10-02
Applicant: BRIDGESTONE CORP
Inventor: ISHINO YUICHI , MARUYAMA TAKAYUKI , SAITO TASUKU
Abstract: PURPOSE:To provide an electrically viscoelastic semi-solid substance which comprises a gel produced by dispersing specific carbon powder in a partially cross-linked electrically insulating polymer, which changes its viscoelastic characteristics by the application of electric fields and which has extremely low fluidity. CONSTITUTION:An electrically viscoelastic semi-solid substance comprises an electrically responsible gel produced by dispersing (A) 20-70 pts.wt. of carbon powder having an average particle of 0.1-500mum and a carbon/hydrogen atomic ratio (C/H ratio) of 1.2-5 in (B) 80-30 pts.wt. of a partially cross-linked electrically insulating polymer having a penetration of >=40 at room temperature. The component A may be dispersed in an electrically insulating oil or polymer having a viscosity of >=500 centistokes at room temperature.
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公开(公告)号:JPH05810A
公开(公告)日:1993-01-08
申请号:JP25031591
申请日:1991-09-04
Applicant: BRIDGESTONE CORP
Inventor: FUKUYAMA YOSHIKI , KURACHI IKUO , MARUYAMA TAKAYUKI , ISHINO YUICHI , SAITO TASUKU
Abstract: PURPOSE:To provide carbonaceous powder which is used as the disperse phase of an electroviscous liquid whose power consumption is small and whose oxidizing resistance is increased and to provide the electroviscous liquid where the carbonaceous powder is used as its disperse phase. CONSTITUTION:After pitch powder is heat treated below its melting point and at temp. of >=50 deg.C and =300 deg.C and
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