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    5-(1-Methyl-3,4,5,6,7,7-hexachloro-norborn-4-ene-1)-isophthalic acid
    110.
    发明授权
    5-(1-Methyl-3,4,5,6,7,7-hexachloro-norborn-4-ene-1)-isophthalic acid 失效
    5-（1-甲基-3,4,5,6,7,7-六氯 - 降冰片-4-烯-1） - 间苯二甲酸

    公开(公告)号：US3903144A

    公开(公告)日：1975-09-02

    申请号：US40248673

    申请日：1973-10-01

    Applicant: STANDARD OIL CO OHIO

    Inventor： FIELDS ELLIS K ,  STEITZ JR ALFRED

    IPC: C07C17/30 ,  C07C63/14 ,  C08G63/682 ,  C08G69/42 ,  C07C61/00

    CPC classification number: C08G69/42 ,  C07C17/30 ,  C07C327/00 ,  C08G63/6828 ,  C07C23/30

    Abstract: New chemical compounds useful as intermediates are 5-(1-methyl3,4,5,6,7,7-hexahalo-norborn-4-ene-1)-isophthalic acid and 4-(1methyl-3,4,5,6,7,7-hexaholo-norborn-4-ene-1)-orthophthalic acid, formed by oxidation of the primary or secondary alkyl groups containing from one to ten carbon atoms on the benzene ring of the Diels-Alder adduct of equimolecular amounts of hexahalocyclopentadiene and either 3,5-dialkyl- Alpha -methylstyrene and 3,4-dialkyl- Alpha -methylstyrene. The acyl derivatives of these intermediates do not burn or support combustion and are also useful as extreme-pressure additives in lubricating oils. The following acyl derivatives of 5-(1-methyl3,4,5,6,7,7-hexachloro-norborn-4-ene-1)-isophthalic acid have been prepared: the dichloride, diamide, dianilide, diethylester, polyphenylester, poly(chlorophenyl) ester, poly-ethylene glycol ester, diphenylthioester, di-methallylester, and unsaturated polyester. Also, the co-polyphenylesters of 5-(1-methyl3,4,5,6,7,7-hexachloro-norborn-4-ene-1)- isophthalic acid and terephthalic or adipic acid; the polyamide of 5-(1-methyl3,4,5,6,7,7-hexachloro-norborn-4-ene-1)-isophthalic acid and 1,6hexanediamine; the copolyamides of 5-(1-methyl-3,4,5,6,7,7hexachloronorborn-4-ene-1) isophthalic acid and 1,6-hexanediamine and terephthalic acid or adipic acid; the co-polyethylene glycol ester of 5-(1-methyl-3,4,5,6,7,7-hexachloro-norborn-4-ene-1) isophthalic acid and terephthalic acid; and a phosphorus adduct of 5-(1-methyl-3,4,5,6,7,7- hexachloro-norborn-4-ene-1) have been prepared.

    Abstract translation: 可用作中间体的新化合物是5-（1-甲基-3,4,5,6,7,7-六氢降冰片-4-烯-1） - 间苯二甲酸和4-（1-甲基-3,4 ，5,6,7,7-六氢降冰片-4-烯-1） - 邻苯二甲酸，其通过在Diels-Alder加合物的苯环上氧化含有1至10个碳原子的伯或仲烷基而形成 的等摩尔量的六氢环戊二烯和3,5-二烷基-α-甲基 - 苯乙烯和3,4-二烷基-α-甲基苯乙烯。 这些中间体的酰基衍生物不燃烧或支持燃烧，也可用作润滑油中的极压添加剂。 制备了以下5-（1-甲基-3,4,5,6,7,7-六氯 - 降冰片-4-烯-1） - 间苯二甲酸的酰基衍生物：二氯化物，二酰胺，二酰苯胺，二乙酯， 聚苯基酯，聚（氯苯基）酯，聚乙二醇酯，二苯硫酯，二 - 甲代烯丙基酯和不饱和聚酯。 此外，5-（1-甲基-3,4,5,6,7,7-六氯 - 降冰片-4-烯-1） - 间苯二甲酸和对苯二甲酸或己二酸的共聚苯酯; 5-（1-甲基-3,4,5,6,7,7-六氯 - 降冰片-4-烯-1） - 间苯二甲酸和1,6-己二胺的聚酰胺; 5-（1-甲基-3,4,5,6,7,7-六氯乙烯-4-烯-1）间苯二甲酸和1,6-己二胺和对苯二甲酸或己二酸的共聚酰胺; 5-（1-甲基-3,4,5,6,7,7-六氯 - 降冰片-4-烯-1）间苯二甲酸和对苯二甲酸的共聚乙二醇酯; 并制备了5-（1-甲基-3,4,5,6,7,7-六氯 - 降冰片-4-烯-1）的磷加成物。

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