Abstract:
A hydrogen producing reactor is disclosed. The hydrogen producing reactor has a reaction chamber containing a catalyst bed adapted to produce reaction products containing hydrogen from a hydrogen-producing feedstock. The reaction chamber also includes a hydrogen-selective, hydrogen-permeable gas separation module adapted to receive the reaction products from the catalyst bed and to separate a product stream containing hydrogen from the reaction products. The gas separation module comprises a porous substrate, an intermediate layer located at the porous substrate, and a hydrogen-selective membrane overlying the intermediate layer. The intermediate layer comprises particles and a binder metal, where the binder metal is distributed through out the intermediate layer. A steam reforming process is also disclosed using the disclosed reactor.
Abstract:
Preferred embodiments of the present invention provide methods of forming a photolithographic pattern by patternwise imaging each of two or more different modalities of light onto a multiphoton-specific photoinitiator material to form a photolithographic pattern on the surface where each of the patterns of the two or more different wavelengths of light overlap. In various embodiments, the invention provides a method of semiconductor fabrication capable of permitting the formation of an imaged feature having a dimension smaller than λ/(2NA), where λ is the smallest wavelength of imaging light, and NA is the numerical aperture of the imaging system.
Abstract:
In various aspects, the present invention provides substantially monolayer thick molecular films with photoresponsive wettability, the molecules of said films comprising a photochromic molecule coordinated to a metal atom, which is coordinated to an organic tethering molecule, surface coupling group, or both, having a group for attachment to a surface of a substrate. In various aspects, the present inventions also provide photochromic articles comprising said films, methods of forming said films, and methods of manufacturing photochromic articles using said films. In various embodiments, provided are molecular films where the photoconversion between configurations of the photochromic molecule is substantially reversible by irradiation with light. In various embodiments, provided are films where the photoconversion is substantially irreversible by irradiation with light.
Abstract:
Preferred embodiments of the present invention include methods that allow for casting alloys, and preferentially casting wrought alloys to circumvent problems such as, for example, hot tearing. Preferred embodiments of the present invention provide for alloys having predominantly spherical primary α-aluminum grains in their microstucture (i.e., substantially free of dendrites ) formed by mixing two liquids of differing compositions the are held at predetermine temperatures, such that when mixed they produce a predetermined alloy composition at a predetermined temperature that is inclined to solidify with a predominantly spherical grain structure that minimizes the alloy’s tendency towards hot tearing.
Abstract:
The present invention relates to a method for fabricating a composite gas separation module and to gas separation modules formed by the method. The present invention also relates to a method for selectively separating hydrogen gas from a hydrogen gas-containing gaseous stream. In one embodiment, the method for fabricating a composite gas separation module includes depositing a first material on a porous substrate, thereby forming a coated substrate. The coated substrate is abraded, thereby forming a polished substrate. A second material is then deposited on the polished substrate. The first material, the second material, or both the first material and the second material can include a gas-selective material. For example, the gas-selective material can include a hydrogen-selective metal , e.g., palladium, or an alloy thereof. In one embodiment, the method includes the step of forming a dense gas-selective membrane over the porous substrate. Practice of the present invention can produce gas separation modules that have thinner and/or more uniform dense gas-selective membranes than are possible using conventional manufacturing techniques.
Abstract:
The present invention relates to a novel device and method for the detection of lithium ions in a biological fluid. In a preferred embodiment, the present invention provides a novel compound and a optical sensor which incorporates said compound for the detection of lithium ions. Additionally, the present invention provides a method of detecting lithium ions which comprises placing the novel optical sensor into communication with a biological fluid. Once the novel compound of the present invention encounters a lithium ion(s), a fluorescence is generated, the intensity of which is measured and allows for the determination of lithium ion concentration. The present invention provides a medical professional with the ability to selectively determine lithium ion concentration in a biological fluid thereby facilitating the treatment of various diseases, such as manic-depressive illness.
Abstract:
Tunable pull-through energy attenuator and decelerator devices is disclosed which provide for variable force-time profiles, deceleration and kinetic energy attenuation of moving objects so as to prevent damage or injury to impacting objects, vehicles or persons. The device employs either consumable inelastic or reusable, viscoelastic deforming elements, such as tubes, rods, plates or strips, which absorb substantial amounts of energy through repeated inelastic or viscoelastic deformation when the deforming element is pulled through a tunable array of rigid pins having a variety of configurations and settings. The disclosed devices provide for variable force-time profiles which control the cumulative deformation and thereby the amount of energy absorbed and rate of deceleration of impacting objects. The device may be readily adapted and deployed as highway vehicle guardrails, road barriers or crash cushions for frontal and side impacts and as load attenuators for crash-resistant aircraft seats, spacecraft landing pods, crash-resistant aircraft landing gear, aircraft and vehicle passenger restraint harnesses, cargo tie-downs, vehicle bumpers and collapsible vehicle steering columns.
Abstract:
This invention describes a high temperature aerosol decomposition reactor for producing metal containing materials and methods of producing metal containing materials using the same. The metal containing materials produced by the method of the present invention include metal oxides, catalytic compositions, superconducting materials, and electrically conducting ceramics.
Abstract:
Materials and methods for a rapid and effective way to create a carbon negative self-healing construction material are described. The construction material uses sand aggregates, a trace amount of catalyst, a small dosage of scaffolding material with a crosslinking agent, and a calcium source. The curing is performed at a high temperature for a short period or at room temperature for a long period. The catalyst-driven method to bridge the sand particles results in a dense, stiff, strong, and tough structural material, which upon exposure to calcium source and CO2 heals itself repeatably.
Abstract:
A method for recycling secondary battery charge materials includes a one-step molten-salt process to upcycle mixed Ni-lean polycrystalline NMC cathodes into Ni-rich single-crystal NMC cathodes. The method includes receiving a recycling stream of charge materials from end-of-lifetime batteries, adding additional charge materials based on an upcycled battery chemistry intended for the upgraded, recycled battery, and sintering the combined charge materials for generating a single crystal charge material corresponding to the upcycled battery chemistry using a molten salt direct recycling process.