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公开(公告)号:KR101738590B1
公开(公告)日:2017-06-09
申请号:KR1020160089233
申请日:2016-07-14
Applicant: 한국에너지기술연구원
CPC classification number: C25B3/04 , B01D3/06 , B01D53/1487 , B01D53/326 , B01D53/965 , C01B32/40 , C01B32/50 , C07C51/15 , C07C53/06 , C07C53/10 , C22C13/00 , C25B11/04 , C25B15/02
Abstract: 본발명은이산화탄소를전기환원시켜이산화탄소의환원생성물을제조하는방법및 장치에관한것이다. 본발명은애노드영역에물 또는전해액을공급하고, 제1온도를갖는전기화학적전지내 캐소드영역에상기제1온도보다높은제2온도를갖는가습된이산화탄소기체를공급하여상대습도가 100%를초과하는조건으로가습된이산화탄소기체를공급하면서, 상기애노드영역과캐소드영역사이에전압을인가하여애노드영역에서수소이온(H)을형성시키고상기수소이온(H)이전해질막을통과하여캐소드영역으로이동하여이산화탄소기체를전기환원시켜이산화탄소의환원생성물을생성시킴으로써액상환원반응과같이높은패러데이효율로높은농도의이산화탄소의환원생성물을에너지효율적으로제조할수 있다.
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公开(公告)号:KR1020170023392A
公开(公告)日:2017-03-03
申请号:KR1020160105456
申请日:2016-08-19
Applicant: 한국에너지기술연구원
CPC classification number: Y02C10/06 , Y02P20/152
Abstract: 본발명은실내이산화탄소처리장치및 방법에관한것으로, 더욱상세하게는캐소드영역에서는, 실내이산화탄소농도가일정수치이상으로높아지면전원이공급되어전기화학반응에의해기액흡수반응부에알칼리흡수제가생성되며, 기체확산층을통해공급된실내공기중의이산화탄소를흡수하고이산화탄소가제거된공기가배출되고, 애노드영역에서는물의전기분해에의해산소가발생하여실내공기중의산소농도를증가시킴으로써쾌적한실내공기를유지시킬수 있는장치및 방법을제공할수 있다.
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公开(公告)号:KR1020170009773A
公开(公告)日:2017-01-25
申请号:KR1020160089233
申请日:2016-07-14
Applicant: 한국에너지기술연구원
CPC classification number: C25B3/04 , B01D3/06 , B01D53/1487 , B01D53/326 , B01D53/965 , C01B32/40 , C01B32/50 , C07C51/15 , C07C53/06 , C07C53/10 , C22C13/00 , C25B11/04 , C25B15/02
Abstract: 본발명은이산화탄소를전기환원시켜이산화탄소의환원생성물을제조하는방법및 장치에관한것이다. 본발명은애노드영역에물 또는전해액을공급하고, 제1온도를갖는전기화학적전지내 캐소드영역에상기제1온도보다높은제2온도를갖는가습된이산화탄소기체를공급하여상대습도가 100%를초과하는조건으로가습된이산화탄소기체를공급하면서, 상기애노드영역과캐소드영역사이에전압을인가하여애노드영역에서수소이온(H)을형성시키고상기수소이온(H)이전해질막을통과하여캐소드영역으로이동하여이산화탄소기체를전기환원시켜이산화탄소의환원생성물을생성시킴으로써액상환원반응과같이높은패러데이효율로높은농도의이산화탄소의환원생성물을에너지효율적으로제조할수 있다.
Abstract translation: 本发明涉及通过电还原二氧化碳制备二氧化碳还原产物的方法和装置。 本发明可以通过以下方式制备具有高法拉第效率的高浓度二氧化碳与液体还原反应的还原产物:通过以下方式制备二氧化碳还原产物:通过向阳极区域供水或电解质 ; 将具有高于第一温度的第二温度的加湿二氧化碳气体供给到具有第一温度的电化学电池内的阴极区域,以将已被加湿的二氧化碳气体供给到相对湿度大于 100%,同时在阳极区域和阴极区域之间施加电压,以在阳极区域中形成氢离子(H +); 并使氢离子(H +)通过电解质膜并移动到阴极区域,从而电还原二氧化碳气体。
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114.
公开(公告)号:KR1020160119429A
公开(公告)日:2016-10-13
申请号:KR1020160041013
申请日:2016-04-04
Applicant: 한국에너지기술연구원
CPC classification number: Y02C10/04 , Y02P20/152 , B01D53/62 , B01D2257/504 , C01B32/60 , C25B9/10
Abstract: 본발명은선박배기가스로부터탄산염광물의제조및 산성가스제거방법, 및이를위한장치에관한것으로, 더욱상세하게는하나의반응기내에서, NaOH 수용액을생성하기위한 NaCl 함유물의전기분해, 및탄산또는중탄산음이온을형성시키기위한 NaOH 수용액과이산화탄소함유산성가스의반응을함께수행한다음, 상기탄산또는중탄산음이온을해수와함께광물화반응기에유입시켜탄산광물을생성함으로써선박상에서보다컴팩트한규모로이산화탄소함유산성가스를광물탄산화시키고이와동시에산성가스를제거할수 있는방법및 장치에관한것이다.
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公开(公告)号:KR101534710B1
公开(公告)日:2015-07-07
申请号:KR1020130136650
申请日:2013-11-12
Applicant: 현대자동차주식회사 , 기아자동차주식회사 , 한국에너지기술연구원
CPC classification number: B01D53/1475 , B01D53/1425 , B01D53/18 , B01D53/62 , B01D53/96 , B01D2251/30 , B01D2251/606 , B01D2252/2023 , B01D2252/20478 , B01D2252/30 , B01D2252/504 , B01D2257/302 , B01D2257/304 , B01D2257/504 , Y02C10/04 , Y02C10/06
Abstract: 본발명의실시예에따른산성가스의흡수분리장치는산성가스를포함하는가스가내부로공급되는흡수탑, 상기흡수탑과인접하여배치되는재생탑, 상기흡수탑과상기재생탑을순환하면서, 상기흡수탑에서는산성가스를흡수하고, 상기재생탑에서는산성가스를다시배출하는흡수제, 및상기재생탑에서발생되는산성가스를응축하는응축기를포함하고, 상기흡수탑의내부하부에는상기흡수제를원심력에의해서분리하는원심분리기가내장될수 있다.
Abstract translation: 根据本发明实施例的用于分离酸性气体的吸收装置包括:吸收塔,其中含有酸性气体的气体被供应到内部;再生塔,其与吸收塔相邻地布置; 以及冷凝器,用于冷凝在再生塔中产生的酸性气体,其中吸收剂设置在吸收塔的下部以具有离心力 可以使用离心分离机进行分离的离心分离机。
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公开(公告)号:KR101406711B1
公开(公告)日:2014-06-16
申请号:KR1020130032218
申请日:2013-03-26
Applicant: 한국에너지기술연구원
Abstract: The present invention relates to a method for separating carbon dioxide from mixed gas containing the carbon dioxide and, more particularly, to a method for using an amino silane group as a mixed solvent in a carbon dioxide separation apparatus including an absorption tower and a stripping tower. The method for separating carbon dioxide using the mixed solvent of the present invention includes: a step in which a carbon dioxide-mixed solvent is supplied to an upper portion of the absorption tower and the mixed gas containing carbon dioxide is introduced to a lower portion of the absorption tower so that the carbon dioxide contained in the mixed gas is absorbed into the mixed solvent; a step in which the mixed solvent into which the carbon dioxide is absorbed is sent to a re-evaporation tank (flash tank) and the carbon dioxide is stripped by pressure difference; and a step in which the mixed solvent which passes through the re-evaporation tank is sent to the stripping tower and is heated to strip the carbon dioxide. In the method for separating carbon dioxide, an amino silane-based mixed solvent is used as the mixed solvent. The amino silane solvent of the present invention has a higher carbon dioxide absorption performance and removal efficiency than existing commercial solvents, and thus capturing costs can be saved in process application. In addition, the low volatility results in excellent safety and economic feasibility in a process operation.
Abstract translation: 本发明涉及从包含二氧化碳的混合气体中分离二氧化碳的方法,更具体地说,涉及在包括吸收塔和汽提塔的二氧化碳分离装置中使用氨基硅烷基团作为混合溶剂的方法 。 使用本发明的混合溶剂分离二氧化碳的方法包括:向吸收塔的上部供给二氧化碳混合溶剂的步骤,将含有二氧化碳的混合气体导入到 吸收塔使得混合气体中所含的二氧化碳被吸收到混合溶剂中; 其中吸收二氧化碳的混合溶剂被送到再蒸发罐(闪蒸罐)并通过压力差汽提二氧化碳的步骤; 将通过再蒸发槽的混合溶剂送入汽提塔并被加热以除去二氧化碳的步骤。 在分离二氧化碳的方法中,使用氨基硅烷类混合溶剂作为混合溶剂。 本发明的氨基硅烷溶剂比现有的商业溶剂具有更高的二氧化碳吸收性能和去除效率,因此在工艺应用中可节省成本。 此外,低波动性在过程操作中导致出色的安全性和经济可行性。
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公开(公告)号:KR1020140060930A
公开(公告)日:2014-05-21
申请号:KR1020120127899
申请日:2012-11-13
Applicant: 한국에너지기술연구원
CPC classification number: Y02A50/2342 , G01N25/005 , B01D53/1475 , C01B32/50
Abstract: The present invention relates to a method for calculating regenerative heat of a chemical absorbent for carbon dioxide. The regenerative energy of a chemical absorbent for carbon dioxide is calculated by obtaining and calculating parameters using a device in a short term instead of obtaining test values of the regenerative energy of a chemical absorbent for carbon dioxide via process operation, calculating the current heat of the absorbent from the result of measuring reaction heat and specific heat of the absorbent in the process of measuring a combustion phenomenon before and after the reaction of the absorbent for carbon dioxide, calculating the latent heat for evaporation of a solvent, and summing all the values. The method for calculating regenerative heat of an absorbent for carbon dioxide from the sum of the latent heat for evaporation, the reaction heat for absorption and the current heat comprises the steps of: calculating the latent heat for evaporation of the absorbent for carbon dioxide; measuring the reaction heat for absorption of the absorbent for carbon dioxide; and calculating the specific heat of carbon dioxide before and after reaction in the process of measuring the heat capacity before reaction of the absorbent for carbon dioxide and the heat capacity after reaction of the absorbent for carbon dioxide in a state of being completely saturated with carbon dioxide, and calculating the current heat therefrom.
Abstract translation: 本发明涉及二氧化碳化学吸收剂的再生热计算方法。 二氧化碳化学吸收剂的再生能量是通过在短期内使用装置获得和计算参数来计算的,而不是通过过程操作获得用于二氧化碳的化学吸收剂的再生能量的测试值,计算当前的热量 在测量二氧化碳吸收剂反应前后的燃烧现象的过程中测量反应热和吸收剂的比热的结果,计算用于蒸发溶剂的潜热,并将所有值相加,从而得到吸收剂。 用于计算用于二氧化碳的吸收剂的再生热的方法,用于蒸发潜热,吸收反应热和当前的热量之和包括以下步骤:计算二氧化碳吸收剂的蒸发潜热; 测量吸收二氧化碳吸收剂的反应热; 计算二氧化碳吸收剂反应前的热容量和反应二氧化碳吸收剂在二氧化碳完全饱和后的反应后的热容量的反应前后的二氧化碳的比热 ,并计算当前的热量。
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118.
公开(公告)号:KR1020130126359A
公开(公告)日:2013-11-20
申请号:KR1020120050430
申请日:2012-05-11
Applicant: 한국에너지기술연구원
IPC: B01D53/14 , B01D53/62 , B01D19/00 , C07D233/58
CPC classification number: Y02C10/04 , Y02C10/06 , Y02P20/152 , B01D53/14 , B01D19/00 , B01D53/62 , C07D233/58
Abstract: Disclosed are an ether-functionalized immidazolium-based ionic liquid and a separating method of carbon dioxide using the same. The ether-functionalized imidazolium-based ionic liquid has excellent carbon dioxide absorbing ability. The absorbed carbon dioxide is easily attached and detached by heating, so the ether-functionalized imidazolium-based ionic liquid has user convenience, selectivity, thermal stability, and long lifetime, thereby being useful for collecting CO2.
Abstract translation: 公开了醚官能化的基于咪唑鎓的离子液体和使用其的二氧化碳的分离方法。 醚官能化的咪唑鎓离子液体具有优异的二氧化碳吸收能力。 吸收的二氧化碳通过加热容易地附着和分离,因此醚官能化的咪唑鎓离子液体具有用户便利性,选择性,热稳定性和长寿命,因此可用于收集二氧化碳。
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公开(公告)号:KR101316543B1
公开(公告)日:2013-10-15
申请号:KR1020110062228
申请日:2011-06-27
Applicant: 한국에너지기술연구원
CPC classification number: Y02A50/2342 , Y02C10/04 , Y02C10/06
Abstract: 본 발명은 이산화탄소 흡수 방법에 관한 것으로서, 이산화탄소 흡수공정에서 염의 생성을 최소화하고, 발생된 염을 효과적으로 제거함으로써 재생에너지를 최소화할 수 있는 이산화탄소 흡수 공정에 관한 것이다. 본 발명의 이산화탄소 흡수 공정은 알칼리탄산염에 입체장애 시클릭 아민이 첨가된 이산화탄소 흡수제에 이산화탄소가 포함된 기체를 접촉시키는 기체 접촉단계; 상기 기체로부터 이산화탄소를 흡수하는 이산화탄소 흡수단계; 상기 이산화탄소가 흡수된 흡수제에서 염을 분리하는 공정; 상기 염이 분리된 흡수제를 재생하는 단계를 포함한다.
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120.
公开(公告)号:KR101288530B1
公开(公告)日:2013-07-26
申请号:KR1020110089922
申请日:2011-09-06
Applicant: 한국에너지기술연구원
CPC classification number: B01D71/024 , C01B13/0255
Abstract: 본원은 La
1-x Sr
x Ti
1-y Fe
y O
3-δ 로 코팅된 Ba
1-x Sr
x Co
1-y Fe
y O
3-δ 의 조성을 갖는 이온전도성 산소분리용 분리막 및 이의 제조방법을 제공한다. La
1-x Sr
x Ti
1-y Fe
y O
3-δ 로
보호 코팅된 본원의 Ba
1-x Sr
x Co
1-y Fe
y O
3-δ 분리막은 코팅되지 않은 분리막과 비교하여 현저히 향상된 산소투과도 및 열적 안정성을 가져 이산화탄소를 함유하는 공기로부터 산소 분리 등에 유용하게 사용될 수 있다.
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