公开(公告)号：WO1998018848A1

公开(公告)日：1998-05-07

申请号：PCT/US1997019403

申请日：1997-10-28

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  NELSON, Gregory, Wayne ,  NICELY, Vincent, Alvin ,  TURNER, Sam, Richard

IPC: C08G63/88

CPC classification number: C08L67/02 ,  B29K2105/0002 ,  C08G63/88 ,  C08L77/00 ,  Y10S264/64 ,  C08L2666/20 ,  C08L2666/18

Abstract: The present invention discloses a process for producing molded, shaped or extruded articles comprising the steps of: a) melt reacting, in the presence of a catalyst which is substantially free of Co compounds, at least one glycol and at least one dicarboxylic acid to form a polyester having an I.V. of at least about 0.5 dL/g, wherein said at least one glycol is selected from the group consisting of glycols having up to 10 carbon atoms and mixtures thereof and said dicarboxylic is selected from the group consisting of alkyl dicarboxylic acids having 2 to 16 carbon atoms, aryl dicarboxylic acids having 8 to 16 carbon atoms and mixtures thereof; b) adding an acetaldehyde reducing additive to said polyester to form a reduced acetaldehyde polyester; and c) forming said reduced acetaldehyde polyester into articles directly from step b. Thus, the present invention provides a process for directly producing from the melt article having extremely low acetaldehyde content.

Abstract translation: 本发明公开了一种生产模塑，成型或挤出制品的方法，包括以下步骤：a）在基本上不含Co化合物的催化剂存在下熔融反应至少一种二醇和至少一种二羧酸形成 具有IV的聚酯 至少约0.5dL / g，其中所述至少一种二醇选自具有至多10个碳原子的二醇及其混合物，并且所述二羧酸选自具有2至16个碳原子的烷基二羧酸 8-18个碳原子的芳基二羧酸及其混合物; b）向所述聚酯中加入乙醛还原添加剂以形成还原乙醛聚酯; 和c）直接从步骤b将所述还原的乙醛聚酯制成制品。 因此，本发明提供了由具有极低乙醛含量的熔融制品直接生产的方法。

公开(公告)号：WO1998016688A1

公开(公告)日：1998-04-23

申请号：PCT/US1997017964

申请日：1997-10-06

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  COX, Stephen, Todd ,  BRADLEY, Robert, Lee, Jr. ,  KENNEDY, Paul, Jay ,  MASSIE, Guy, Fostine, Jr. ,  MITCHELL, Melvin, Glenn ,  WILLIAMS, Freddie, Wayne ,  UNGAR, Israel, Sindel

IPC: D21H27/22

CPC classification number: B32B29/002 ,  B32B23/04 ,  B32B29/06 ,  B32B37/04 ,  B32B2262/062 ,  B32B2451/00 ,  D21H13/06 ,  D21H15/10 ,  D21H17/07 ,  D21H17/09 ,  D21H17/675 ,  D21H27/26 ,  Y10T428/25 ,  Y10T428/31895 ,  Y10T428/31993

Abstract: A decorative paper sheet for use in preparing a decorative laminate is made up of a matrix containing from about 15 to about 60 weight percent of cellulose and from about 40 to about 85 weight percent of cellulose acetate. The sheet also contains a plasticizer for the cellulose acetate in an amount ranging from about 40 to about 90 weight percent based on the weight of the cellulose acetate in said matrix. A filler material may be present in the sheet in an amount ranging from about 1 to about 18 weight percent based on the weight of the matrix. A low pressure laminate may be made from sheet and a structural substrate therefor by application of heat and pressure. The plasticized cellulose acetate fuses and resolidifies to bond the sheet to the structural substrate.

Abstract translation: 用于制备装饰层压板的装饰纸片由含有约15至约60重量％的纤维素和约40至约85重量％的醋酸纤维素的基质组成。 基于所述基质中的乙酸纤维素的重量，该片材还含有用于乙酸纤维素的增塑剂，其量为约40至约90重量％。 基于基质的重量，填料材料可以以约1至约18重量％的量存在于片材中。 可以通过施加热和压力由片材和其结构基材制成低压层压体。 增塑的乙酸纤维素保温并重新固化以将片材结合到结构基材上。

公开(公告)号：WO1998016687A1

公开(公告)日：1998-04-23

申请号：PCT/US1997017942

申请日：1997-10-06

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  BUCHANAN, Charles, Michael ,  ELLERY, Eric, Eugene ,  WOOD, Matthew, Davie

IPC: D21H13/06

CPC classification number: D21H13/06 ,  C08L1/02 ,  C08L1/10 ,  D21H17/24 ,  D21H19/32 ,  Y10T428/1303 ,  Y10T442/2025 ,  Y10T442/2033 ,  C08L2666/02

Abstract: This invention relates to compositions, paper, thermoplastic sheets, and medical paper containing cellulose ester, alkylpolyglycoside (APG) or a mixture of APG and polyether glycol, and, optionally, cellulose. The process of incorporating APG or a mixture of APG and polyether glycol in paper composed of cellulose ester fibers and cellulose fibers and to calendaring of such paper is also disclosed.

Abstract translation: 本发明涉及含有纤维素酯，烷基多糖苷（APG）或APG和聚醚二醇的混合物以及任选的纤维素的组合物，纸，热塑性片和医用纸。 还公开了将APG或APG和聚醚二醇的混合物掺入由纤维素酯纤维和纤维素纤维组成的纸中并且对该纸进行压延的方法。

公开(公告)号：WO1998016569A1

公开(公告)日：1998-04-23

申请号：PCT/US1997018660

申请日：1997-10-16

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  BOWERS, David, Taylor ,  JONES, Ronnie, Jay +di ,  CLIFFTON, Michael, Duane ,  KNIGHT, Joseph, Franklin ,  QUILLEN, Donna, Rice

IPC: C08G63/78

CPC classification number: C08G63/183 ,  C08G63/189 ,  C08G63/78

Abstract: The application relates to a process for producing a high molecular weight polyester having less than about 0,5 weight % diethylene glycol comprising adding at least one carbonate compound to the ester exchange reaction product produced from reaction of a glycol component comprising ethylene glycol and an ester component comprising dimethylterephthalate, dimethylnaphthalenedicarboxylate and mixtures thereof wherein said reaction product is formed without a Ti catalyst.

Abstract translation: 本申请涉及制备具有小于约0.5重量％二甘醇的高分子量聚酯的方法，该方法包括向由乙二醇和酯的二醇组分的反应产生的酯交换反应产物中加入至少一种碳酸酯化合物 组分包括对苯二甲酸二甲酯，萘二甲酸二甲酯及其混合物，其中所述反应产物不用Ti催化剂形成。

公开(公告)号：WO1998010010A1

公开(公告)日：1998-03-12

申请号：PCT/US1997015346

申请日：1997-08-29

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  WEAVER, Max, Allen ,  PRUETT, Wayne, Payton ,  SHACKELFORD, Kay, Hunt ,  HILBERT, Samuel, Daniel

IPC: C08G75/30

CPC classification number: C08G75/30 ,  G03G9/0908

Abstract: Thermoplastic compositions containing certain anthraquinone polysulfonamide colorants incorporated therein as toners or colorants. The anthraquinone colorant moieties which are incorporated into the polymer chain of the polysulfonamide colorants are not leachable, sublimable or extractable and do not exude from the thermoplastic compositions. The anthraquinone polysulfonamide colorants may be added to the thermoplastic polymer during production or melt blended with the polymer by conventional techniques to produce transparent thermoplastic compositions useful for a variety of end uses where nonmigrating or nonextractable colorants are needed.

Abstract translation: 含有某些蒽醌聚磺酰胺着色剂作为调色剂或着色剂的热塑性组合物。 掺入聚磺酰胺着色剂的聚合物链中的蒽醌着色剂部分不可浸出，可升华或可萃取，并且不会从热塑性组合物中渗出。 蒽醌多磺酰胺着色剂可以在生产过程中加入到热塑性聚合物中，或者通过常规技术与聚合物熔融混合，以产生用于需要不偏色或不可萃取的着色剂的各种最终用途的透明热塑性组合物。

公开(公告)号：WO1998002404A1

公开(公告)日：1998-01-22

申请号：PCT/US1997010940

申请日：1997-07-16

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  MCKENZIE, Peter, B. ,  KANEL, Jeffrey, S. ,  FALLING, Stephen, N. ,  WILSON, Alan, K.

IPC: C07C29/10

CPC classification number: C07C29/86 ,  C07C29/106 ,  C07C33/035

Abstract: This invention pertains firstly to the use of mixtures of hydriodic acid and organic solvent soluble iodide salts as catalysts for the hydration of gamma, delta-epoxyalkenes to form a mixture of the corresponding 2-alkene-1,4-diol and 3-alkene-1,2-diol isomers. Secondly, this invention describes the use of pH to control the 2-alkene-1,4-diol/3-alkene-1,2-diol product ratio, and achieves improved 2-alkene-1,4-diol selectivities by controlling the pH to near neutral values.

Abstract translation: 本发明首先涉及使用氢碘酸和有机溶剂可溶性碘盐的混合物作为γ，δ-环氧烯烃水合的催化剂，以形成相应的2-烯-1,4-二醇和3-烯烃 - 1,2-二醇异构体。 其次，本发明描述了使用pH控制2-烯-1,4-二醇/ 3-烯-1,2-二醇的产物比例，并通过控制2-烯烃-1,4-二醇的选择性来实现改进的2-烯-1,4-二醇选择性 pH值接近中性值。

公开(公告)号：WO1997050053A2

公开(公告)日：1997-12-31

申请号：PCT/US1997016028

申请日：1997-06-23

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  CYR, Michael, John ,  KRUTAK, James, John, Sr. ,  CLAUBERG, Horst ,  MEADE, Randy, Barnett ,  MOORE, James, Edward ,  PATONAY, Gabor

IPC: G06K07/12

CPC classification number: G06K7/12 ,  G02B6/3861 ,  G02B6/3862 ,  G02B6/3887

Abstract: An apparatus for detecting an invisible, near infrared fluorescing mark disposed on a background comprises: an excitation source for exciting the mark, the source having sufficient power to provide a fluorescent signal from a mark situated on at least reflective portion of the background; signal detecting means for detecting the fluorescent signal from the mark; and power modulating means for varying the power between zero and the maximal power level of the excitation source, which is preferably a laser, in a manner effective to produce a decodable fluorescent signal from a mark disposed on any portion of the background. A process for decoding an invisible mark comprising a near infrared fluorescing material comprises: providing at least one invisible, near infrared fluorescing mark disposed on at least one portion of a background; exciting the mark with a laser having a maximal power level sufficient to provide a fluorescent signal from the mark when it is disposed on at least reflective portion of the background; and detecting the fluorescent signal and concurrently varying the power of the laser between zero and its maximal power, thereby obtaining a decodable fluorescent signal at a laser power level between zero and the maximal of a mark disposed on any portion of the background.

Abstract translation: 用于检测设置在背景上的不可见的近红外荧光标记的装置包括：用于激发标记的激励源，源具有足够的功率以从位于背景的至少反射部分上的标记提供荧光信号; 信号检测装置，用于检测来自标记的荧光信号; 以及功率调制装置，用于以有效地从设置在背景的任何部分上的标记产生可解码的荧光信号的方式来改变优选为激光的激发源的零和最大功率电平之间的功率。 用于解码包含近红外荧光材料的不可见标记的方法包括：提供设置在背景的至少一部分上的至少一个不可见的近红外荧光标记; 利用具有足够的最大功率水平的激光来激励标记，以便当它被设置在背景的至少反射部分上时从标记提供荧光信号; 并且检测荧光信号并同时改变激光在0和最大功率之间的功率，从而获得在零和设置在背景的任何部分上的标记的最大值之间的激光功率电平的可解码的荧光信号。

公开(公告)号：WO1997049757A1

公开(公告)日：1997-12-31

申请号：PCT/US1997011189

申请日：1997-06-24

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  SHIH, Wayne, Ken

IPC: C08K05/103

CPC classification number: C08J5/18 ,  C08J2367/02 ,  C08K5/103 ,  C08L67/02

Abstract: This invention relates to polyester/plasticizer blends which are useful as heat-shrinkable films or sheets in low temperature shrink packaging applications. The heat-shrinkable films or sheets comprise a blend of (A) 90 to 99 weight percent of a polyester having a glass transition temperature of 40 DEG C to 150 DEG C and an inherent viscosity of 0.5 to 1.2 dL/g and (B) 1 to 10 weight percent of a plasticizer selected from a C7 to C33 monoglyceride prepared from the reaction of glycerol and a fatty acid having 4 to 30 carbon atoms, wherein the combined weights of (A) and (B) total 100 percent. The polyester comprises a dicarboxylic acid component comprising repeat units from at least 80 mole percent of an aromatic dicarboxylic acid having 8 to 14 carbon atoms and a diol component comprising repeat units from at least 10 mole percent of 1,4-cyclohexanedimethanol, based on 100 mole percent dicarboxylic acid and 100 mole percent diol.

Abstract translation: 本发明涉及在低温收缩包装应用中可用作热收缩膜或片材的聚酯/增塑剂共混物。 热收缩膜或片材包含（A）90-99重量％的玻璃化转变温度为40-150℃，特性粘度为0.5-1.2dL / g的聚酯和（B） 1至10重量％的选自由甘油和具有4至30个碳原子的脂肪酸反应制备的C7至C33单甘油酯的增塑剂，其中（A）和（B）的总重量为100％。 聚酯包含二羧酸组分，其包含至少80摩尔％的具有8至14个碳原子的芳族二羧酸的重复单元和包含至少10摩尔％1,4-环己烷二甲醇的重复单元的二醇组分，基于100 摩尔百分比的二羧酸和100摩尔％的二醇。

公开(公告)号：WO1997045094A1

公开(公告)日：1997-12-04

申请号：PCT/US1997008719

申请日：1997-05-16

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  DOBBS, Suzanne, Winegar ,  KRUTAK, James, John, Sr. ,  OLDFIELD, Terry, Ann

IPC: A61K07/027

CPC classification number: A61K8/85 ,  A61K2800/57 ,  A61Q1/02 ,  A61Q1/04

Abstract: This invention relates to an aqueous lip gloss and cosmetic composition and method for coloring lips and skin comprising the use of a water-dispersible, colored sulfopolyester wherein the colorant moiety is incorporated into or onto a carbonyloxy and/or carbonylamide backbone of the sulfopolyester. The sulfopolyesters are uniquely designed to offer cosmetically desirable color coatings on lips and skin.

Abstract translation: 本发明涉及用于使嘴唇和皮肤着色的水性唇彩和化妆品组合物和方法，其包括使用水分散着色的磺基聚酯，其中着色剂部分被引入到磺基聚酯的羰氧基和/或羰基酰胺主链中或上。 磺基聚酯的独特设计可以在唇部和皮肤上提供美观的色彩涂层。

公开(公告)号：WO1997043433A1

公开(公告)日：1997-11-20

申请号：PCT/US1997008668

申请日：1997-05-16

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  HUBBS, John, Clark

IPC: C12P17/04

CPC classification number: C12P17/04 ,  C12P7/60 ,  Y10S435/836 ,  Y10S435/847 ,  Y10S435/913 ,  Y10S435/921 ,  Y10S435/933

Abstract: The present invention is directed toward efficient, high-yield processes for making ascorbic acid, 2-keto-L-gulonic acid, and esters of 2-keto-L-gulonic acid. The processes comprise reacting the appropriate starting materials with a hydrolase enzyme catalyst such as a protease, an esterase, a lipase or an amidase.

Abstract translation: 本发明涉及用于制备抗坏血酸，2-酮-L-古洛糖酸和2-酮-L-古洛糖酸的酯的有效的高产率方法。 该方法包括使合适的原料与水解酶催化剂如蛋白酶，酯酶，脂肪酶或酰胺酶反应。