公开(公告)号：WO1994028402A1

公开(公告)日：1994-12-08

申请号：PCT/US1993005130

申请日：1993-05-28

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  NODING, Stephen, A.

IPC: G01N27/404

CPC classification number: G01N33/0006

Abstract: A device is provided for reliably generating a wide range of known concentrations of an oxidizing or a reducing gas in an inert carrier gas. The gas-generating electrode (42) is sandwiched between a porous diffusion membrane (44) and an ion-exchange membrane (38) which has been preconditioned by exposure to a source of a precursor ion for the gas to be generated, and the minimal void volume defined between the ion-exchange membrane and porous diffusion membrane and surrounding the gas-generating electrode is filled with a solution of the precursor ion for the gas to be generated.

Abstract translation: 提供了用于在惰性载气中可靠地产生大范围已知浓度的氧化还原气体的装置。 气体发生电极（42）夹在多孔扩散膜（44）和离子交换膜（38）之间，该离子交换膜（38）通过暴露于待产生气体的前体离子源而被预处理， 在离子交换膜和多孔扩散膜之间限定并围绕气体发生电极的空隙体积填充有待产生的气体的前体离子溶液。

公开(公告)号：WO1994028392A1

公开(公告)日：1994-12-08

申请号：PCT/US1994005968

申请日：1994-05-26

Applicant: THE DOW CHEMICAL COMPANY ,  BENEDETTO, Elizabeth, E. ,  LYONS, John, W. ,  WOOD, Stewart, P.

Inventor： THE DOW CHEMICAL COMPANY

IPC: G01N15/02

CPC classification number: G01N15/0205 ,  G01N2021/4707

Abstract: An apparatus and method are disclosed which allow the size of a particle (20) suspended in a medium to be determined virtually independent of the materials' refractive index. The apparatus includes a means (12) for producing a beam of collimated light (22), a means (13) for exposing the particles (20) to the collimated light (22), thereby scattering the light, a detector (14, 31), and a means (17, 41, 43) for preventing any of the light which was scattered by the particles (20) from reaching the detector (14, 31). The method of the invention comprises passing the medium containing the particle (20) through a beam of collimated light (22), so that the light which contacts the particle (20) will be scattered; deterring the light which was scattered by the particles (20) from being detected; detecting the light which was not scattered by the particle, and determining the size of the particle (20) from the decrease in the light intensity incident on the detector (14, 31).

Abstract translation: 公开了一种允许悬浮在介质中的颗粒（20）的尺寸实质上与材料的折射率无关的装置和方法。 该装置包括用于产生准直光束（22）的装置（12），用于将颗粒（20）暴露于准直光（22）的装置（13），从而散射光;检测器（14,31 ）和用于防止由颗粒（20）散射的任何光到达检测器（14,31）的装置（17,41,43）。 本发明的方法包括使含有颗粒（20）的介质通过准直光束（22），使得与颗粒（20）接触的光将被散射; 阻止由颗粒（20）散射的光被检测; 检测不被颗粒散射的光，以及从入射到检测器（14,31）上的光强度的降低来确定颗粒（20）的尺寸。

公开(公告)号：WO1994028040A1

公开(公告)日：1994-12-08

申请号：PCT/US1994004162

申请日：1994-04-15

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  LADIKA, Mladen ,  FISK, Thomas, E.

IPC: C08F246/00

CPC classification number: C07B57/00 ,  C08F246/00

Abstract: Optically-active, amphiphilic, free-radical addition copolymers having an optically-active hydrophobic portion and an ionic hydrophilic portion are effective resolving agents. This utility is based on a unique combination of properties, viz., water solubility, chirality and amphiphilicity, i.e., having a dual hydrophobic and hydrophilic nature.

Abstract translation: 具有光学活性疏水部分和离子亲水部分的光学活性，两亲性，自由基加成共聚物是有效的拆分剂。 该实用性基于特性的独特组合，即水溶性，手性和两亲性，即具有双疏水性和亲水性。

公开(公告)号：WO1994026755A1

公开(公告)日：1994-11-24

申请号：PCT/US1993004356

申请日：1993-05-06

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  KIEFER, Garry, E. ,  SIMON, Jaime

IPC: C07F09/6561

CPC classification number: C07F9/6561 ,  A61K51/0482 ,  A61K51/1093 ,  A61K2121/00 ,  A61K2123/00

Abstract: Complexes of bicyclopolyazamacrocyclophosphonic acid compounds with a metal ion, e.g. Sm, Lu, Gd, Pm, La, Yb, Ho, Y, Sc, Re, Re, Pr, Tc, Ga, Ga, Rh, Ru, In, In or In ion, are disclosed. The complexes can be covalently attached to a biologically active molecule, e.g. an antibody or antibody fragment, to form conjugates. The complexes and conjugates are useful as radiopharmaceutical agents for therapy and/or diagnostic purposes. Processes for preparing the complex and conjugate are discussed.

Abstract translation: 双环多氮杂环亚烷基膦酸化合物与金属离子的络合物，例如 Sm，177 Lu，159 Gd，149 Pm，140 La，175 Yb，166 Ho，90 Y，47 Sc，186 Re， Re，142，Pr，99m Tc，67 Ga，68 Ga，105 Rh，97 Ru，111 In，113 m In或115 m In In ，被披露。 络合物可以共价连接到生物活性分子，例如， 抗体或抗体片段，以形成缀合物。 复合物和缀合物可用作用于治疗和/或诊断目的的放射性药物。 讨论了制备复合物和共轭物的方法。

公开(公告)号：WO1994026754A1

公开(公告)日：1994-11-24

申请号：PCT/US1993004325

申请日：1993-05-06

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  KIEFER, Garry, E. ,  SIMON, Jaime ,  GARLICH, Joseph, R.

IPC: C07F09/6561

CPC classification number: C07F9/6561 ,  A61K49/106 ,  A61K51/0482 ,  A61K2123/00

Abstract: Bicyclopolyazamacrocyclophosphonic acid compounds are disclosed which may form inert complexes with Gd, Mn or Fe ions. The overall charge of the complex can be varied to alter the in vivo biolocalization. Such complexes can be covalently attached to an antibody, antibody fragment or other biologically active molecule to form conjugates. The complexes and conjugates are useful as contrast agents for diagnostic purposes. Processes for the preparation of the ligand, complex and conjugate are also disclosed.

Abstract translation: 公开了可与Gd，Mn或Fe离子形成惰性络合物的双环多氮杂泛膦酸化合物。 可以改变复合物的总电荷以改变体内生物定位。 这样的复合物可以共价连接到抗体，抗体片段或其他生物活性分子上以形成缀合物。 复合物和缀合物可用作诊断目的的造影剂。 还公开了制备配体，复合物和缀合物的方法。

公开(公告)号：WO1994026690A1

公开(公告)日：1994-11-24

申请号：PCT/US1993012060

申请日：1993-12-10

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  DURVASULA, V., Rao ,  HEFNER, Robert, E., Jr. ,  EARLS, Jimmy, D.

IPC: C07C217/90

CPC classification number: C08G59/504 ,  C07D303/24 ,  C08G59/20

Abstract: The present invention concerns bis(aminophenoxy)-alpha-substituted stilbenes represented by Formula (I) wherein each R is independently hydrogen or a hydrocarbyl or hydrocarbyloxy group having from one to about 10, preferably one to about 4, carbon atoms, a halogen atom, preferably chlorine, bromine or fluorine, a nitro group, a nitrile group or a -CO-R group; each R is independently hydrogen or a hydrocarbyl group having from one to about 10, preferably one to about 6, carbon atoms; X is a (a) or (b) group, each R is independently hydrogen or a hydrocarbyl group having from one to about 10, preferably one to about 2, carbon atoms; R is a hydrocarbyl group having from one to about 10, preferably one to about 2, carbon atoms and may be chlorine or a nitrile group, when n has a value of zero; and n has a value of zero or one. Bis(aminophenoxy)-alpha-substituted stilbenes are prepared by reacting a dihydroxy-alpha-substituted stilbene with a halonitrobenzene in the presence of a basic acting substance such as potassium carbonate and hydrogenating the resulting bis(nitrophenoxy)-alpha-substituted stilbene to convert the nitro groups to amino groups. These compounds are useful as curing agents for epoxy resins.

Abstract translation: 本发明涉及由式（I）表示的双（氨基苯氧基）-α-取代的二苯乙烯，其中每个R独立地为氢或具有1至约10个，优选1至约4个碳原子的烃基或烃氧基，卤素原子 优选氯，溴或氟，硝基，腈基或-CO-R 2基团; 每个R 1独立地为氢或具有1至约10个，优选1至约6个碳原子的烃基; X为（a）或（b）基团，每个R 2独立地为氢或具有1至约10个，优选1至2个碳原子的烃基; 当n为零时，R 3为具有1至约10个，优选1至约2个碳原子的烃基，并且可为氯或腈基; n的值为零或一。 双（氨基苯氧基）-α-取代的二苯乙烯通过在碱性作用物质如碳酸钾存在下使二羟基-α-取代的二苯乙烯与卤代硝基苯反应并氢化得到的双（硝基苯氧基）-α-取代的二苯乙烯来转化 硝基为氨基。 这些化合物可用作环氧树脂的固化剂。

公开(公告)号：WO1994025903A1

公开(公告)日：1994-11-10

申请号：PCT/US1994004535

申请日：1994-04-25

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  FOSTER, Pamela, S. ,  ECKER, Ernest, L. ,  RUTTER, Edward, W., Jr. ,  MOYER, Eric, S.

IPC: G03F07/038

CPC classification number: G03F7/0757 ,  C09D4/00 ,  C08G77/00

Abstract: A process for forming a partially polymerized DVS resin comprising heating DVS monomer in a solvent at a concentration of DVS monomer in the solvent such that: (a) the DVS resin, when applied and polymerized in a thin layer on a solid substrate does not craze; and (b) the DVS resin, is rendered photocurable by the addition of at least one photosensitive agent in an amount sufficient to convert the mixture to an organic-insoluble solid upon exposing the mixture to photon radiation and the film retention upon development with a solvent is at least 50 percent. The process may be more readily scaled up to a commercial scale, may generate little or no low molecular weight fraction that must be separated from a precipitating solvent and may make a novel DVS resin which may be used to form a film on a substrate which retains its integrity.

Abstract translation: 一种用于形成部分聚合的DVS树脂的方法，包括在溶剂中以DVS单体的浓度将DVS单体加入到溶剂中，使得：（a）DVS树脂当在固体基材上薄层聚合时不会发泡 ; 和（b）DVS树脂通过添加至少一种光敏剂使其变得光固化，其量足以将混合物暴露于光子辐射时将混合物转化为有机不溶性固体，并且用溶剂显影时的膜保留 至少有50％。 该方法可以更容易地扩大到商业规模，可能产生很少或不产生必须与沉淀溶剂分离的低分子量分数，并且可以制备新的DVS树脂，其可以用于在保留的基材上形成膜 其诚信。

公开(公告)号：WO1994025648A1

公开(公告)日：1994-11-10

申请号：PCT/US1994003789

申请日：1994-04-06

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  MAUGANS, Rexford, A. ,  KNICKERBOCKER, Edward, N. ,  KNIGHT, George, W.

IPC: D01F06/30

CPC classification number: D04H3/16 ,  C08L23/0815 ,  C08L2314/06 ,  D01F6/30 ,  D01F8/06 ,  C08L2666/04

Abstract: Elastic fibers and fabrics made from homogeneously branched linear ethylene polymers are disclosed. The elastic fibers and fabrics can be used to produce structures that can have recycle compatibility between elastic and non elastic components. The novel fibers have at least 50 percent recovery at 100 percent strain. The fibers and fabrics are especially useful in making fabricated articles and components thereof (e.g., disposable diapers).

Abstract translation: 公开了由均匀支化的线性乙烯聚合物制成的弹性纤维和织物。 弹性纤维和织物可以用于产生可以在弹性和非弹性组分之间具有循环相容性的结构。 新型纤维在100％应变下具有至少50％的回复率。 纤维和织物在制造制品及其部件（例如一次性尿布）中特别有用。

公开(公告)号：WO1994024206A1

公开(公告)日：1994-10-27

申请号：PCT/US1994000790

申请日：1994-01-21

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  WESSEL, Thomas, E. ,  HUANG, Yi-Bin ,  THILL, Bruce, P.

IPC: C08L25/06

CPC classification number: C08L25/06 ,  C08K5/098 ,  C08L53/02 ,  C08L71/126 ,  C08L2666/24 ,  C08L2666/04

Abstract: An impact modified syndiotactic vinylaromatic polymer comprises: A) from 25 to 90 parts by weight of a syndiotactic, vinylaromatic thermoplastic resin, B) from 1 to 50 parts by weight of a rubbery, impact absorbing, domain forming polymer, having a melt flow rate, Condition X (315 DEG C, 5.0 Kg) from 0 to 0.5 g/10 min, C) from 0.1 to 30 parts by weight of a nucleator for the syndiotactic, vinylaromatic thermoplastic resin, D) from 0 to 90 parts by weight of a reinforcing agent, and E) from 0 to 90 parts by weight of a polyarylene ether or polar group modified polyarylene ether.

Abstract translation: 抗冲改性间同立构乙烯基芳族聚合物包括：A）25至90重量份的间同立构乙烯基芳族热塑性树脂，B）1至50重量份的具有熔体流动速率的橡胶状，冲击吸收性区域形成聚合物 ，条件X（315℃，5.0Kg），0〜0.5g / 10分钟，C）0.1〜30重量份间同立构乙烯基芳族热塑性树脂的成核剂，D）0〜90重量份 增塑剂，E）0〜90重量份聚亚芳基醚或极性基团改性聚亚芳基醚。

公开(公告)号：WO1994024202A1

公开(公告)日：1994-10-27

申请号：PCT/US1993003618

申请日：1993-04-16

Applicant: THE DOW CHEMICAL COMPANY ,  HELMER, Bradley, J. ,  LOUGHNEY, Shirley, J. ,  MACDONAGH-DUMLER, Jon

Inventor： THE DOW CHEMICAL COMPANY

IPC: C08L09/04

CPC classification number: D21H19/58 ,  C08F220/28 ,  C08F236/04 ,  C08F290/062

Abstract: The present invention relates to a latex copolymer comprising in polymerized form one or more ethylenically unsaturated poly(ethylene glycol) monomers represented by formula (I) where R is an ethylenically unsaturated functional group, R is H, OH or OCH3, and n is from 3 to 20, and one or more comonomers. Paper coating compositions comprising this latex copolymer impart improved sheet gloss and dry pick characteristics to the coated paper. Additional embodiments include a process for the preparation of the ethylenically unsaturated poly(ethylene glycol) monomer-containing latex copolymer and the paper coating composition.

Abstract translation: 本发明涉及一种胶乳共聚物，其包含聚合形式的一种或多种由式（I）表示的烯属不饱和聚（乙二醇）单体，其中R 1是烯属不饱和官能团，R是H，OH或OCH 3，和 n为3至20，和一种或多种共聚单体。 包含该胶乳共聚物的纸涂料组合物赋予涂布纸更好的片材光泽度和干燥选择特性。 另外的实施方案包括制备含烯属不饱和聚（乙二醇）单体的胶乳共聚物和纸涂料组合物的方法。