Abstract:
A discharge lamp is disclosed comprising an enclosed discharge vessel for the generation of an electrical discharge and a casing made of glass which surrounds the discharge vessel. In order to achieve as constant properties as possible over the service life of the lamp, it is proposed that the glass material of the casing be doped with sodium in a concentration of at least 10 ppm, and preferably at least 30 ppm. According to a further embodiment, it is proposed that other alkali metals (except for sodium) be contained in a maximum concentration of 25 ppm. Surprisingly, by the appropriate choice of the outer bulb, not in direct contact with the actual discharge, the diffusion of sodium from the discharge vessel is reduced. In addition to this, the material of the outer bulb has a reduced inclination to crystallization.
Abstract:
A photosensitive glass made of a ternary compound SiO2:SnO2:R2O where R is a Group I element such as Na, K or Li. The addition of an oxide of a Group I element increases the solubility of tin oxide in a silica matrix and produces a glass which is highly photosensitive and in which optically written refractive index modulations have remarkable temperature stability (solid circles) at least as good as that of the binary glass SiO2:SnO2 (open circles) and much superior to that of conventional germanosilicate glass (solid triangles) or borogermanosilicate glass (open triangles). The inclusion of the Group I oxide effectively increases the solubility of tin oxide in the non-crystalline silica matrix well above the 1% limit of SiO2:SnO2 photosensitive glass, at which Sn would normally crystallize in the oxide. By contrast to boron or phosphorous co-dopants, the introduction of the Group I element does not appear to cause any increase in the background refractive index, allowing the manufacture of waveguide devices compatible with standard telecommunication fibers.
Abstract:
The invention relates to a glass excellent in infrared absorption capability and corrosion resistance, and its fabrication process. A compound of divalent copper and a compound of a metal species for a network modifier oxide are introduced in a wet gel. Then, the wet gel is dipped in a dipping solution having a low solubility with respect to the compound of divalent copper and the compound of a metal species for a network modifier oxide for the precipitation in the wet gel of the divalent-t copper compound and the compound of a metal species for a network modifier oxide, followed by drying and firing. Thus, an infrared absorbing glass comprising 70 to 98 mol % of SiO2, 1 to 12 mol % of CuO and 1 to 18 mol % of a network modifier oxide other than CuO is fabricated.
Abstract:
A chemically durable porous glass of which the skeleton mainly comprises SiO.sub.2 -ZrO.sub.2 system glass having a ZrO.sub.2 content of 2 or more wt %, and a process for the production of such glass.
Abstract:
This invention relates to the immobilization of toxic, e.g., radioactive, materials in a silicate glass or silica gel matrix for extremely long periods of time. Toxic materials, such as radioactive wastes containing radioactive cations, which may be in the form of liquids, or solids dissolved or dispersed in liquids or gases, are incorporated into a glass or silica gel matrix, having alkali metal, Group Ib metal and/or ammonium cations bonded to silicon atoms of said glass or silica gel through divalent oxygen linkages, by a process which involves the ion exchange of said toxic or radioactive cations with said alkali metal, Group Ib metal and/or ammonium cations to bind said toxic or radioactive cations to silicon atoms of said glass or silica gel through said silicon-bonded divalent oxygen linkages. Thereafter, the resulting glass or silica gel now characterized by toxic or radioactive cations bonded to silicon atoms through divalent oxygen linkages can be stored, or packaged in suitable containers, or disposed of as by burial, and/or sintered to collapse the pores thereof.
Abstract:
A process for producing transparent high-annealing-point 96% silica glass comprising the steps of depositing a carbon film on the pore walls of the glass, heating the glass and film under non-oxidizing conditions, and removing the carbon film by oxidation, is described.
Abstract:
Thermally stable, mechanically strong microporous glass articles with large pore volumes, surface areas, and varying pore sizes, and methods for making such articles are disclosed. In particle form, such as beads, the microporous glass articles are useful as catalyst supports in applications such as petroleum catalytic refiners, chemical processes and motor vehicle catalytic mufflers. The mechanical strength and the dimensional stability of the microporous glass articles at elevated temperatures can be improved if the articles are preshrunk, such as by brief exposure to high temperatures, before their intended use, and can be improved even further if treated with certain metal oxides.
Abstract:
Thermally stable, mechanically strong microporous glass articles with large pore volumes, surface areas, and varying pore sizes, and methods for making such articles are disclosed. In particle form, such as beads, the microporous glass articles are useful as catalyst supports in applications such as petroleum catalytic refiners, chemical processes and motor vehicle catalytic mufflers. The mechanical strength and the dimensional stability of the microporous glass articles at elevated temperatures can be improved if the articles are preshrunk, such as by brief exposure to high temperatures, before their intended use, and can be improved even further if treated with certain metal oxides.
Abstract:
1. A METHOD FOR MAKING A LOW ALKALI-CONTAINING POROUS GLASS ARTICLE HAVING A HIGH THERMAL STABILITY COMPRISING: (A) HEATING A PHASE-SEPARABLE ALKALI-BOROSILICATE GLASSS TO A TEMPERATURE SUFFFICIENT TO SEPARATE THE GLASS INTO TWO PHASES, ONE OF WHICH IS A BORATE-RICH PHASE AND IS SOLUBLE IN AN AQUEOUS SOLUTION, (B) A FIRST LEACHING OF THE PHASE-SEPARATED GLASS WITH WATER FOR A TIME AND AT A TEMPERATURE SUFFICIENT TO REMOVE A MAJOR PORTION OF THE BORATE-RICH PHASE TO FORM A POROUS GLASS HIGH IN SILICA, (C) A SUBSEQUENT LEACHING OF THE PREVIOUSLY LEACHED POROUS GLASS WITH AN ACID FOR A TIME AND AT A TEM-
PERATURE SUFFICIENT TO REMOVE SUFFICIENT ALKALI AND BORATE NOT REMOVAL IN THE FIRST LEACHING TO PROVIDE A LOW ALKALI-BORATE CONTAINING MICROPOROUS GLASS STRUCTURE HAVING A HIGH THERMAL STABILITY.