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公开(公告)号：KR1020080006402A
公开(公告)日：2008-01-16
申请号：KR1020060065576
申请日：2006-07-12
Applicant: 한국화학연구원
CPC classification number: C01B32/00 , B82B3/0009 , B82Y40/00 , C01B32/20 , C01B2204/00
Abstract: A hollow graphitic nanocarbon of which an inner part is hollow, and which has a graphite layer formed on an outer part thereof prepared using specific polymers containing metal catalysts is provided to have an excellent graphitic crystal properties through a low temperature of heat treatment. A preparation method of a hollow graphitic nanocarbon comprises: a first step of a mixed aqueous solution into which an inorganic material with a particle size of 20 to 100 nm and a transition metal or lanthanide metal catalytic precursor are dissolved; a second step of subjecting the mixed aqueous solution and a carbon precursor having a hydroxy group to a polymerization reaction in the presence of an acid to prepare an inorganic material-metal-carbon precursor composite; a third step of carbonizing the inorganic material-metal-carbon precursor composite to form an inorganic material-metal-carbon composite; and a fourth step of subjecting the inorganic material-metal-carbon composite to base treatment and acid treatment to remove an inorganic material and a metal from the inorganic material-metal-carbon composite. As hollow particles of which an inner part is hollow, and which has a graphite layer formed on an outer portion thereof, a hollow graphitic nanocarbon is characterized in that the hollow inner part of the particles is in a diameter range from 20 to 160 nm, the graphite layer has a thickness range from 3 to 30 nm, and the particles have a particle size range from 30 to 220 nm.
Abstract translation: 提供一种中空石墨纳米碳，其内部是中空的，并且在其外部使用含有金属催化剂的特定聚合物制成的石墨层被提供以通过热处理的低温具有优异的石墨晶体性能。 中空石墨纳米碳的制备方法包括：溶解粒径为20〜100nm的无机材料和过渡金属或镧系金属催化剂前体的混合水溶液的第一工序; 在酸的存在下使混合水溶液和具有羟基的碳前体进行聚合反应以制备无机材料 - 金属 - 碳前体复合材料的第二步骤; 将无机材料 - 金属 - 碳前体复合材料碳化以形成无机材料 - 金属 - 碳复合材料的第三步骤; 以及对无机材料 - 金属 - 碳复合材料进行基础处理和酸处理以从无机材料 - 金属 - 碳复合材料中除去无机材料和金属的第四步骤。 作为中空粒子，其内部是中空的，并且在其外部形成有石墨层，中空石墨纳米碳的特征在于，所述粒子的中空内部部分的直径范围为20〜160nm， 石墨层的厚度范围为3〜30nm，粒子的粒径为30〜220nm。
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公开(公告)号：KR100692917B1
公开(公告)日：2007-03-12
申请号：KR1020060015497
申请日：2006-02-17
Applicant: 한국화학연구원
Abstract: An electrochemical analysis apparatus for developing a fuel cell catalyst is provided to compare quantified current densities of catalyst points in cyclic voltammetry(CV) and quickly derive composition ratio of individual metal in developing alloy catalysts. The apparatus is fabricated of: an automatic dispenser(15) that has optionally relative electrode(21) and reference electrode(22) or micro injector and is movable in X-Y-Z axis direction; a precursor chamber(16) that contains a metal precursor solution generated by dissolving different metal salts in a proper solvent; a combinatorial solution storage plate(17) that has multiple tubes containing a mixture solution which comprises the metal precursor solution with different compositions and contents; a reactive electrode array(18) having multiple catalyst points based on multi-component alloy, which are formed by dispensing the mixture solution to the conductive plate; a microfine hole plate(19) having multiple thru-path holes corresponding to the catalyst points; and a potential measuring device(23) electrically connected to the array as well as the relative electrode and the reference electrode, simultaneously.
Abstract translation: 提供了一种用于显影燃料电池催化剂的电化学分析装置，以比较循环伏安法（CV）中催化剂点的量化电流密度并快速推导出显影合金催化剂中各种金属的组成比。 该设备由以下部件制成：自动分配器（15），其具有可选的相对电极（21）和参考电极（22）或微型喷射器并且可沿X-Y-Z轴方向移动; 包含通过将不同金属盐溶解在适当溶剂中而产生的金属前体溶液的前体室（16） 组合溶液储存板（17），其具有包含混合物溶液的多个管，所述混合物溶液包含具有不同组成和含量的金属前体溶液; 具有基于多组分合金的多个催化剂点的反应性电极阵列（18），其通过将所述混合物溶液分配到所述导电板而形成; 具有与催化剂点对应的多个通路孔的微细孔板（19） 和同时电连接到阵列以及相关电极和参考电极的电位测量装置（23）。
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公开(公告)号：KR1020060110236A
公开(公告)日：2006-10-24
申请号：KR1020060035451
申请日：2006-04-19
IPC: H01M10/05
CPC classification number: H01M14/005 , H01G9/038 , H01G11/18 , H01G11/26 , H01G11/58 , H01G11/64 , H01M4/366 , H01M4/62 , H01M10/0567 , H01M10/0568 , H01M10/4235 , H01M2004/028 , H01M2300/0025 , Y02E60/13
Abstract: Provided is a functional additive for an electrolyte, which inhibits the reaction heat generated from side reactions between a cathode and an electrolyte, and thus improves the quality of a battery while maintaining the battery quality. The electrolyte comprises: (a) an electrolyte salt; (b) an organic solvent; and (c) at least one compound selected from the group consisting of the compounds represented by the following formulae (I) and (II). In formulae (I) and (II), each of R1, R2 and R3 represents independently H or a C1-C6 lower alkyl; R4 is a single bond or the formula (a); X is -O- or -OC(O)O-; each of n and m is an integer of 0-1000; each of p and q is an integer of 0-20, with the proviso that p and q cannot represent 0 at the same time; r is an integer of 1-6; each o i and j is an integer of 1-1000; and s is an integer of 1-20.
Abstract translation: 提供了用于电解质的功能添加剂，其抑制由阴极和电解质之间的副反应产生的反应热，从而在保持电池质量的同时提高电池的质量。 电解质包括：（a）电解质盐; （b）有机溶剂; 和（c）至少一种选自由下式（I）和（II）表示的化合物的化合物。 在式（I）和（II）中，R 1，R 2和R 3各自独立地表示H或C 1 -C 6低级烷基; R4是单键或式（a）; X是-O-或-OC（O）O-; n和m各自为0-1000的整数; p和q各自为0-20的整数，条件是p和q不能同时表示0; r为1-6的整数; 每个o i和j是1-1000的整数; s是1-20的整数。
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公开(公告)号：KR100588475B1
公开(公告)日：2006-06-09
申请号：KR1020040041502
申请日：2004-06-07
Applicant: 한국화학연구원
CPC classification number: H01M10/0565 , C08G77/20 , C08G77/46 , C08L83/12 , H01M10/052 , H01M2300/0082 , H01M2300/0094 , Y02T10/7011 , C08L83/00
Abstract: 본 발명은 폴리실록산계 화합물을 포함하는 고체 고분자 전해질 조성물에 관한 것으로서, 더욱 상세하게는 메틸 실록산 폴리머 직쇄에 폴리알킬렌옥시드기 및 아크릴기를 측쇄로 도입하여 가교가 용이하고 상기 아크릴기의 농도에 따라 가교도를 조절할 수 있는 폴리실록산계 화합물과, 상기 폴리실록산계 화합물을 가교제로 사용하여 상온에서 이온 전도도와 전기화학적 안정성이 개선되어 전해질 박막, 소형 및 대용량 리튬-폴리머 이차전지의 고분자 전해질 등으로 적용할 수 있을 뿐만 아니라 상기 폴리실록산계 화합물의 가교도 조절에 의해 전해질의 기계적 물성을 용이하게 조절할 수 있는 고체 고분자 전해질 조성물에 관한 것이다.
실록산 폴리머, 이온 전도도, 가교성, 고체 고분자 전해질-
公开(公告)号：KR1020050116475A
公开(公告)日：2005-12-13
申请号：KR1020040041502
申请日：2004-06-07
Applicant: 한국화학연구원
CPC classification number: H01M10/0565 , C08G77/20 , C08G77/46 , C08L83/12 , H01M10/052 , H01M2300/0082 , H01M2300/0094 , Y02T10/7011 , C08L83/00
Abstract: 본 발명은 폴리실록산계 화합물과 이를 이용하는 고체 고분자 전해질 조성물에 관한 것으로서, 더욱 상세하게는 메틸 실록산 폴리머 직쇄에 폴리알킬렌옥시드기 및 아크릴기를 측쇄로 도입하여 가교가 용이하고 상기 아크릴기의 농도에 따라 가교도를 조절할 수 있는 폴리실록산계 화합물과, 상기 폴리실록산계 화합물을 가교제로 사용하여 상온에서 이온 전도도와 전기화학적 안정성이 개선되어 전해질 박막, 소형 및 대용량 리튬-폴리머 이차전지의 고분자 전해질 등으로 적용할 수 있을 뿐만 아니라 상기 폴리실록산계 화합물의 가교도 조절에 의해 전해질의 기계적 물성을 용이하게 조절할 수 있는 고체 고분자 전해질 조성물에 관한 것이다.
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Patent Agency Ranking
公开(公告)号：KR100473352B1
公开(公告)日：2005-03-11
申请号：KR1020020071663
申请日：2002-11-18
Applicant: 한국화학연구원
IPC: H01M10/05
CPC classification number: H01M10/0565 , H01M10/052
Abstract: 본 발명은 리튬 안정성이 향상된 폴리알킬렌 옥시드계 고분자 전해질 조성물에 관한 것으로서, 더욱 상세하게는 리튬염과, 연결 중심원자 주위에 2개 이상의 페닐알킬렌글리콜 아크릴레이트의 관능기가 도입되어 있는 가교제와 경화형 개시제 및 비수용액계 극성용매가 포함되어 있는 전해질 조성물 중에, 리튬 표면에 안정한 보호층을 형성하고 이온전도 경로를 쉽게 유지할 수 있도록 하는 폴리알킬렌 옥시드 작용기를 가지고 있는 특정의 리튬 표면 안정제를 추가로 첨가함으로써 충방전시 리튬 금속과 전해질 계면간의 안정화를 도모하고 리튬 충방전 효율을 크게 향상시키는 효과를 가지고 있으므로, 금속 리튬을 음극으로 사용하는 리튬 금속-고분자 이차전지의 전해질로 유용한 폴리알킬렌 옥시드계 고분자 전해질 조성물에 관한 것이다.
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127.发明公开다공성 나노 탄소 구형 지지체 및 이에 담지된백금/루테늄합금 직접메탄올 연료전지용 전극촉매 및 이의제조방법 失效具有改善电导率和高表面积的多孔纳米球形支撑体，用于直接甲醇燃料电池的Pt / Ru合金电极催化剂及其制造方法
公开(公告)号：KR1020040104239A
公开(公告)日：2004-12-10
申请号：KR1020030035773
申请日：2003-06-03
Applicant: 한국화학연구원
Abstract: PURPOSE: Provided is a porous nanocarbon spherical support, which has improved conductivity and high surface area by heat treatment and is useful in manufacturing an electrode catalyst for a direct methanol fuel cell by dispersing Pt/Ru alloy nanoparticles. CONSTITUTION: The porous nanocarbon spherical support is manufactured by the method comprising the steps of: providing porous nanocarbon spherical particles by using a conventional method; heat treating the particles at high temperature under argon atmosphere; dispersing the heat treated particles in distilled water; carrying out ultrasonic treatment and centrifugal separation; and drying the resultant particles at 100 deg.C under vacuum. The electrode catalyst for a direct methanol fuel cell is obtained by adsorbing platinum(H2PtCl6) and ruthenium(RuCl3) ions on the above heat-treated porous nanocarbon spherical support and then reducing the ions with a reducing agent(NaBH4) at room temperature.
Abstract translation: 目的：提供一种多孔纳米碳球形载体，其通过热处理具有改善的导电性和高表面积，并且可用于通过分散Pt / Ru合金纳米颗粒制造用于直接甲醇燃料电池的电极催化剂。 构成：通过包括以下步骤的方法制造多孔纳米碳球形支撑体：通过使用常规方法提供多孔纳米碳球形颗粒; 在氩气氛下高温热处理颗粒; 将热处理的颗粒分散在蒸馏水中; 进行超声波处理和离心分离; 并在100℃真空干燥所得颗粒。 通过在上述热处理的多孔纳米碳球形载体上吸附铂（H 2 PtCl 6）和钌（RuCl 3）离子，然后在室温下用还原剂（NaBH 4）还原离子，获得直接甲醇燃料电池用电极催化剂。
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公开(公告)号：KR100419864B1
公开(公告)日：2004-03-04
申请号：KR1020010070969
申请日：2001-11-15
Applicant: 한국화학연구원
IPC: C08K5/5415
CPC classification number: H01M10/052 , C08F230/08 , C08G77/46 , H01M10/0565 , H01M2300/0082 , Y02E60/122 , Y02T10/7011
Abstract: 본 발명은 신규 가교제와 이를 함유하는 가교형 고체 고분자 전해질에 관한 것으로서, 더욱 상세하게는 폴리알킬렌 옥시드기가 곁가지로 도입된 메틸 실록산 폴리머 양 말단에 열 또는 광에 의해 가교 가능한 아크릴기가 도입되어 있는 신규 가교제와, 상기한 신규 가교제, 리튬염, 유기 용매 및 경화형 개시제가 일정 함량비로 함유되어 있음으로써 상온에서의 이온 전도도가 우수한 전해질 박막 제조가 가능해졌고, 제막성 및 전기화학적 안정성이 우수하므로 휴대폰, 노트북 컴퓨터 등의 휴대용 정보단말기 및 캠코더 등의 기기에 적용되는 소형 리튬-폴리머 이차전지는 물론 전력평준화용 전력저장장치 및 전기자동차에 적용가능한 대용량 리튬-폴리머 이차전지의 고분자 전해질로 폭 넓게 적용 가능한 가교형 고체 고분자 전해질 조성물에 관한 것이 다.
Abstract translation: 本发明涉及一种交联剂，其包含具有聚亚烷基氧化物基团作为分支基团并在两端具有丙烯酰基的主链的甲基硅氧烷聚合物和包含交联剂，锂盐，有机溶剂的可交联固体聚合物电解质组合物 ，以一定比例混合固化引发剂。 该交联性固体高分子电解质组合物在室温下具有高离子电导率并且可以容易地形成膜，因此适用于可应用于电动汽车的大尺寸锂聚合物二次电池，用于功率调整的蓄电装置和 以及适用于摄像机的小尺寸锂聚合物二次电池，便携式数据终端如手机和笔记本电脑等。
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公开(公告)号：KR1020040003403A
公开(公告)日：2004-01-13
申请号：KR1020020038093
申请日：2002-07-03
Applicant: 한국화학연구원
IPC: C07D217/24
Abstract: PURPOSE: A π-conjugate compound for molecular electronic devices is provided. The compound can be self-assembled, has easy electron-delocalized structure by π -conjugate linkage of total molecules, and properties to easily trap electron by electric filed produced from the outside because cation is contained within the molecules. CONSTITUTION: A π-conjugate compound for molecular electronic devices is characterized by being represented by the formula(1) of R¬1-Z- £Redox|¬1-Z-R¬2, containing center £Redox| capable of oxidation/reduction, and being connected to aromatic compounds directly or via acetylene bond,, wherein R1 is selected from benzene, CH3COS-benzene, CH3SS-benzene and SiS-benzene; R2 is selected from S-COCH3-benzene and (S-benzene)2; Z is single bond or triple bond; £Redox|1 is selected from X-N+R3-benzene, N+R3-naphthalene, and N+CH3CH3R3-naphthalene; R3 is selected from hydrogen, C1-C4 alkyl and benzyl; X- is selected from I-, Cl-, Br-, CF3SO3, CH3-benzene-SO3-, C12H25-benzene-SO3-, BF4-, PF6- and SbF6-.
Abstract translation: 目的：提供分子电子器件的π-共轭化合物。 该化合物可以是自组装的，通过总共分子的π-共轭键具有容易的电子离域结构，以及由于阳离子包含在分子内而由外界产生的电场容易地捕获电子的性质。 构成：用于分子电子器件的π-共轭化合物的特征在于由式（1）表示：R 1-Z-£氧化还原|¬-Z-R-2，其含有中心£Redox | 能够进行氧化/还原，并直接或通过乙炔键与芳族化合物连接，其中R1选自苯，CH3COS-苯，CH3SS-苯和SiS-苯; R2选自S-COCH 3 - 苯和（S-苯）2; Z是单键或三键; £Redox | 1选自X-N + R3-苯，N + R3-萘和N + CH3CH3R3-萘; R3选自氢，C1-C4烷基和苄基; X-选自I-，Cl-，Br-，CF 3 SO 3，CH 3 - 苯-SSO 3 - ，C 12 H 25 - 苯-SSO 3 - ，BF 4 - ，PF 6 - 和SbF 6 - 。
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公开(公告)号：KR1020030089545A
公开(公告)日：2003-11-22
申请号：KR1020020026979
申请日：2002-05-16
Applicant: 한국화학연구원
CPC classification number: H01L51/0595 , B82Y30/00 , H01L51/005 , H01L51/4206
Abstract: PURPOSE: A molecular electronic device having such a layer structure that gold nanoparticles are adhered to the upper part of self-assembled monolayer, and gold is deposited on the gold nanoparticles is provided, and a preparation method of the molecular electronic device is provided. CONSTITUTION: In a molecular electronic device in which gold (Au) is deposited on the upper part of monolayer, the molecular electronic device is characterized in that gold (Au) nanoparticles are assembled between the monolayer and gold (Au) deposition layer, wherein size of the gold (Au) nanoparticles is larger than size of defects formed on the monolayer. The preparation method of molecular electronic devices comprises process of manufacturing a monolayer by assembling an organic molecule into gold (Au) electrode, wherein the organic molecule is structured in such a manner that different functional groups are substituted for both ends of a molecular device; process of adhering gold nanoparticles to the upper part of the monolayer; and process of depositing gold (Au) on the upper part of the gold nanoparticles.
Abstract translation: 目的：提供具有金纳米颗粒粘附到自组装单层的上部并且金沉积在金纳米颗粒上的层结构的分子电子器件，并提供分子电子器件的制备方法。 构成：在其中金（Au）沉积在单层上部的分子电子器件中，分子电子器件的特征在于金（Au）纳米颗粒组装在单层和金（Au）沉积层之间，其中尺寸 的金（Au）纳米颗粒大于在单层上形成的缺陷的尺寸。 分子电子器件的制备方法包括通过将有机分子组装成金（Au）电极制造单层的方法，其中有机分子以不同官能团取代分子器件的两端的方式构成; 将金纳米颗粒粘附到单层的上部的过程; 以及在金纳米颗粒上部沉积金（Au）的过程。
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