126.
    发明专利
    未知

    公开(公告)号:DE2042580B2

    公开(公告)日:1979-08-16

    申请号:DE2042580

    申请日:1970-08-27

    Abstract: 1301646 Preparation of lactams UBE INDUSTRIES Ltd 27 Aug 1970 [29 Aug 1969 1 Sept 1969] 41376/70 Heading C2C A process for the preparation of lactams comprises treating a lactam-stannic halide complex of formula in which n is an integer of from 3 to 11, R 1 and R 2 which may be the same or different each represents a hydrogen atom or an alkyl or alkenyl group and X is a halogen atom, with an alicyclic ketoxime of general formula in which m is an integer of from 3 to 11 and R 3 and R 4 which may be the same or different each represents a hydrogen atom or an alkyl or alkenyl group to form the lactam and an alicyclic ketoxime-stannic halide complex. The examples describe the preparation of #-caprolactam employing cyclohexanone oxime and #-caprolactam-stannic chloride complex.

    HYDROGENATION CATALYST FOR ELASTOMERS AND THE PROCESS OF HYDROGENATION

    公开(公告)号:GB1482440A

    公开(公告)日:1977-08-10

    申请号:GB5408374

    申请日:1974-12-13

    Abstract: 1482440 Hydrogenating elastomers FIRESTONE TIRE & RUBBER CO 13 Dec 1974 [13 Dec 1973] 54083/74 Heading C3P [Also in Division C2] Unsaturated elastomers, e.g. polybutadiene and butadiene-styrene copolymer, are hydrogenated using as hydrogenation catalyst a cobalt(I) complex prepared by reducing with a trialkyl or triaryl aluminium hydride or dialkyl or diaryl aluminium hydride a cobaltous chloride complex which is the reaction product of cobaltous chloride with 1 to 8 molar equivalents of (a) lactams having the formula in which n is = 0 to 20, (b) other amides having the formula in which R 1 and R 2 are the same or different and each is hydrogen, an alkyl group containing 1 to 10 carbon atoms, or an aryl group of the class consisting of phenyl, tolyl or xylyl, or (c) ureas having the formula in which R 1 , R 2 , R 3 and R 4 are the same or different and each is hydrogen, a straight or branched saturated or unsaturated aliphatic hydrocarbon radical or cyclic alkyl group containing 1 to 8 carbon atoms or an aryl group.

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