Process for removing sulfur from organic sulfides
    132.
    发明公开
    Process for removing sulfur from organic sulfides 失效
    Verfahren zur Entfernung von Schwefel aus organischen Sulfiden。

    公开(公告)号:EP0399185A1

    公开(公告)日:1990-11-28

    申请号:EP90106410.5

    申请日:1990-04-04

    CPC classification number: C07C319/22 C07C321/14

    Abstract: A process for removing sulfur from an organic sulfide containing three or more chemically bound sulfur atoms is disclosed wherein said sulfide is contacted with a defined catalyst at elevated temperature to increase the disproportionation rate and the corresponding sulfide of lower sulfur rank is continuously removed from the reaction zone.

    Abstract translation: 公开了一种从含有三个或更多化学结合的硫原子的有机硫化物中除去硫的方法,其中所述硫化物在高温下与规定的催化剂接触以增加歧化速率,并且从反应中连续除去相应的较低硫等级的硫化物 区。

    Process for producing 1,1-dichloro-1-fluoroethane and/or 1-chloro-1,1-difluoroethane free of vinylidene chloride
    134.
    发明公开
    Process for producing 1,1-dichloro-1-fluoroethane and/or 1-chloro-1,1-difluoroethane free of vinylidene chloride 失效
    一种制备1,1-二氯-1-氟乙烷和/或1-氯-1,1-二氟乙烷,游离的偏二氯乙烯的过程。

    公开(公告)号:EP0391103A1

    公开(公告)日:1990-10-10

    申请号:EP90104928.8

    申请日:1990-03-15

    CPC classification number: C07C17/206 C07C19/12

    Abstract: 1,1-Dichloro-1-fluoroethane and 1-chloro-1,1-­difluoroethane are prepared from the liquid phase fluorina­tion of 1,1,1-trichloroethane by HF in the presence of a homogenous catalyst. 1,1-Dichloro-1-fluoroethane or 1-­chloro-1,1-difluoroethane are selectively produced substan­tially free of vinylidene chloride.

    Abstract translation: 1,1-二氯-1-氟乙烷和1-氯-1,1-二氟乙烷是由1,1,1-三氯乙烷的液相氟化由HF在均相催化剂的存在下制备。 1,1-二氯-1-氟乙烷或1-氯-1,1-二氟乙烷选择性地产生基本上不含偏二氯乙烯。

    Gas phase process for the production of 1,1-dichloro-1-fluoroethane and/or 1-chloro-1,1-difluoroethane from vinylidene chloride
    135.
    发明公开
    Gas phase process for the production of 1,1-dichloro-1-fluoroethane and/or 1-chloro-1,1-difluoroethane from vinylidene chloride 失效
    一种用于在的1,1-二氯-1-氟乙烷和/或1-氯-1,1-二氟乙烷自偏二氯乙烯的气相制备方法。

    公开(公告)号:EP0391102A1

    公开(公告)日:1990-10-10

    申请号:EP90104927.0

    申请日:1990-03-15

    CPC classification number: C07C17/087 C07C17/21 C07C19/12

    Abstract: A novel gas phase process for the production of 1,1-dichloro-1-fluoroethane from vinylidene chloride and hydrogen fluoride is provided. The process is charac­terized by high conversion of vinylidene chloride to product, with a high selectivity for 1,1-dichloro-1-fluoro­ethane. The process may also be operated to selectively form 1-chloro-1,1-difluoroethane. Few volatile by-products and substantially no tar or oligomeric material is formed. Catalyst performance remains constant over extended periods of time.

    Abstract translation: 提供了一种用于从偏二氯乙烯和氟化氢生产1,1-二氯-1-氟乙烷的新颖的气相方法。 该过程由高转化率的偏二氯乙烯产品表征,与1,1-二氯-1-氟乙烷的高选择性。 因此,该方法可以被操作以选择性地形成1-氯-1,1-二氟乙烷。 很少有挥发性副产物,并且基本上无焦油或低聚物材料形成。 催化剂性能保持在长期时间常数。

    HELIUM PRESSURE SEAL FOR A CRYOGENIC REFRIGERATOR
    136.
    发明公开
    HELIUM PRESSURE SEAL FOR A CRYOGENIC REFRIGERATOR 失效
    氦压力密封于低温冷却器。

    公开(公告)号:EP0382782A1

    公开(公告)日:1990-08-22

    申请号:EP89900045.0

    申请日:1988-10-21

    Inventor: WEEKS, Alan, L.

    CPC classification number: F16L23/20 F16J15/0881

    Abstract: Un joint d'étanchéité à pression est utilisé pour contenir de l'hélium dans un réfrigérateur cryogénique qui utilise un ensemble d'entraînement linéaire. Un joint déformable (30) est utilisé pour assurer l'étanchéité des éléments de carter qui renferme l'unité d'entraînement linéaire de manière à réduire les fuites d'hélium. Des organes cannelés de manière concentrique (31, 32) compriment le joint en métal doux (30) sur ses côtés opposés pour former à l'intérieur des rainures d'étanchéité ayant la configuration d'un labyrinthe.

    U.V. stabilizer composition for surface modifying a pvc resinous sheet
    138.
    发明公开
    U.V. stabilizer composition for surface modifying a pvc resinous sheet 失效
    紫外光 表面改性PVC树脂片的稳定剂组合物

    公开(公告)号:EP0306006A3

    公开(公告)日:1990-08-16

    申请号:EP88114218.6

    申请日:1988-08-31

    CPC classification number: C08J7/02 C08J7/065 C08J2327/06 C08K5/005 C08L27/06

    Abstract: What is described herein is a liquid U.V. stabilizer composition and process for effectively surface modifying a PVC resinous body to provide a stabilizing amount of U.V. stabilizer within the surface region of the body within a predetermined solu­tion contact time without leaving an appreciable amount of solvent therein or stabilizer on the surface of the body, and without af­fecting the surface appearance of the modified surface of the body. In one form of the invention, the U.V. stabilizer com­position comprises about 10 to 50 wt/vol%, preferably 15 to 35 wt/vol%, of a U.V. stabilizer dissolved in a mixture of methylene chloride and a liquid fluorochloro hydrocarbon. Suitably the methylene chloride component of the solvent mixture comprises about 40 to 99%, preferably about 50 to 85%, and the fluorochloro hydrocarbon component comprises about 1 to 60%, preferably about 15 to 50%, of the solvent mixture. A preferred fluorochloro hydrocarbon is 1,1,2-trifluoro-1,2,2-trichloroethylene.

    Polymer bound light stabilizer coating resins
    140.
    发明公开
    Polymer bound light stabilizer coating resins 失效
    Überzugsharze,die ein chemisch gebundenes Licht-Stabilisierungsmittel enthalten。

    公开(公告)号:EP0370501A2

    公开(公告)日:1990-05-30

    申请号:EP89121619.4

    申请日:1989-11-23

    Abstract: Acrylic coating resins with attached light stabilizer functional groups are provided, which resins are prepared by reacting light stabilizer hydrazides, LS-C(=O)-NR³-NH₂, with an acrylic prepolymer containing at least two different types of reactive functional groups, one of which is a hydroxyalkyl ester group and the other is carboxyl, anhydride, epoxy or isocyanate. LS is a light stabilizer moiety, e.g., of formula

    wherein R³ is, e.g., hydrogen and R¹⁵ is, e.g., a direct bond. The reaction may be carried out in an inert solvent or in the bulk state.
    The acrylic resins so produced are particularly useful in the stabilization of enamel or lacquer coatings and exhibit outstanding weatherability and durability. As a result of being chemically bound, the light stabilizers are resistant to loss due to volatility and extractability during typical coatings bake operations and exposure to the elements of weather.

    Abstract translation: 提供具有附着的光稳定剂官能团的丙烯酸涂料树脂,该树脂通过使稳定剂酰肼LS-C(= O)-NR 3 -NH 2与含有至少两种不同类型的反应性官能团的丙烯酸类预聚物 基团,其中一个是羟烷基酯基,另一个是羧基,酸酐,环氧基或异氰酸酯。 LS是光稳定剂部分,例如式CHEM,其中R 3是例如氢,R 1 5是例如直接键。 该反应可以在惰性溶剂中或在大量状态下进行。 所生产的丙烯酸树脂特别可用于搪瓷或漆涂料的稳定化,并且具有出色的耐候性和耐久性。 作为化学结合的结果,光稳定剂由于在典型的涂层烘烤操作期间的挥发性和萃取性以及暴露于天气元素而具有耐损失性。

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