Azeotropic mixture of hf and 1233zd
    1.
    发明专利
    Azeotropic mixture of hf and 1233zd 有权
    HF和1233ZD的AZEOTROPIC混合物

    公开(公告)号:JPH11279088A

    公开(公告)日:1999-10-12

    申请号:JP1540099

    申请日:1999-01-25

    CPC classification number: C07C21/18 C07C17/00 C07C17/38 C07C17/383

    Abstract: PROBLEM TO BE SOLVED: To obtain trifluoropropene being an intermediate for a specific pentafluoropropane suitable as a blowing agent and a refrigerant in a high yield, by using an azeotropic mixture composed of HF and a specific trifluorochloropropene.
    SOLUTION: The azeotropic mixture containing HF and 1,1,1-trifluoro-3- chloro-2-propene (hereinafter, 1233 zd) is used, preferably a rectification column is utilized and the azeotropic mixture of HF/1233 zd is removed from a system rich in HF by a liquid phase method (or HF is separated by the removal) or the azeotropic mixture of HF/1233 zd is removed from the system by a vapor- phase method to give 1233 zd being an intermediate for producing 1,1,1,3,3- pentalfuoropropene (hereinafter, 245 fatty acid) in a high yield.
    COPYRIGHT: (C)1999,JPO

    Abstract translation: 要解决的问题:通过使用由HF和特定的三氟氯丙烯组成的共沸混合物,获得作为适合作为发泡剂的特定五氟丙烷和高收率制冷剂的中间体的三氟丙烯。 溶液:使用含有HF和1,1,1-三氟-3-氯-2-丙烯(以下称为1233zd)的共沸混合物,优选使用精馏塔,将HF / 1233zd的共沸混合物从 通过液相法(或通过除去HF分离HF)或HF / 1233zd的共沸混合物通过气相法从体系中除去富含HF的体系,得到1233zd为制备1, 1,1,3,3-戊二酸(以下称为245脂肪酸)。

    U.V. STABILIZER COMPOSITION FOR SURFACE MODIFYING A PVC RESINOUS SHEET
    2.
    发明申请
    U.V. STABILIZER COMPOSITION FOR SURFACE MODIFYING A PVC RESINOUS SHEET 审中-公开
    紫外光 表面改性PVC树脂片的稳定剂组合物

    公开(公告)号:WO1993001228A1

    公开(公告)日:1993-01-21

    申请号:PCT/US1991004774

    申请日:1991-07-10

    CPC classification number: C08J7/065 C08J2327/06

    Abstract: A U.V. stabilizer composition having a PVC resin-swellable organic solvent and a U.V. stabilizer present in the solvent. The U.V. stabilizer is present in a concentration of at least 18 wt % and effective to incorporate in the PVC resin at ambient temperature an amount of UV stabilizer effective to stabilize the surface of the PVC resin.

    Abstract translation: 一个U.V. 稳定剂组合物,其具有PVC树脂溶胀性有机溶剂和U.V. 稳定剂存在于溶剂中。 紫外线 稳定剂以至少18重量%的浓度存在,并且在环境温度下有效地在PVC树脂中引入一定量的有效稳定PVC树脂表面的UV稳定剂。

    CATALYSTS FOR LOW TEMPERATURE CURE OF BLOCKED ISOCYANATES
    3.
    发明申请
    CATALYSTS FOR LOW TEMPERATURE CURE OF BLOCKED ISOCYANATES 审中-公开
    用于低温阻塞异氰酸酯的催化剂

    公开(公告)号:WO1995004093A1

    公开(公告)日:1995-02-09

    申请号:PCT/US1994008293

    申请日:1994-07-26

    Abstract: The present invention comprises a curable composition comprising: (i) a blocked reactive component comprising a blocked isocyanate or a blocked isothiocyanate; (ii) a functional component containing reactive hydrogen; (iii) a triorganotin catalyst for promoting the reaction of the blocked reactive component with the functional component. The composition may also be admixed with water. A co-catalyst may also be employed based on Cu, Zn, Ni, Fe, Co, V, Sb and Bi and especially oxides, salts or chelates of said metal where said metals are divalent. The invention also relates to a method for curing a blocked isocyanate or blocked isothiocyanate at a temperature below about 150 DEG C which comprises combining a triorganotin catalyst with the blocked reactive component and functional component and heating at a temperature less than about 150 DEG C to obtain a cured urethane or thiourethane.

    Abstract translation: 本发明包括可固化组合物,其包含:(i)包含封端异氰酸酯或封端异硫氰酸酯的封闭反应性组分; (ii)含有反应性氢的功能组分; (iii)用于促进阻断的反应性组分与官能组分的反应的三有机锡催化剂。 组合物也可以与水混合。 还可以使用基于Cu,Zn,Ni,Fe,Co,V,Sb和Bi的助催化剂,特别是所述金属的二价氧化物,盐或螯合物。 本发明还涉及一种在低于约150℃的温度下固化封端的异氰酸酯或封闭的异硫氰酸酯的方法,该方法包括将三有机锡催化剂与封闭的反应性组分和官能组分组合并在小于约150℃的温度下加热得到 固化的氨基甲酸酯或硫代氨基甲酸酯。

    SURFACE MODIFIED, U.V. STABILIZED, POLYVINYL CHLORIDE ARTICLE
    4.
    发明申请
    SURFACE MODIFIED, U.V. STABILIZED, POLYVINYL CHLORIDE ARTICLE 审中-公开
    表面改性 稳定氯化聚氯乙烯

    公开(公告)号:WO1991016143A1

    公开(公告)日:1991-10-31

    申请号:PCT/US1991002449

    申请日:1991-04-15

    CPC classification number: C08J7/065

    Abstract: A surface modified, U.V. stabilized translucent or opaque polyvinyl chloride resin article and process for making same is described. The article includes a colored pigment, and is characterized by the substantial absence of titanium dioxide therein. The modified surface is substantially free of residual stabilizer and solvent, and its appearance and degree of surface perfection is substantially the same as unmodified side of the article. The process of the invention is characterized by the steps of immersing the polyvinyl chloride article in a suitable liquid media, contacting with a solution of an ultraviolet light stabilizer in a suitable organic solvent, and displacing residual stabilizer and solvent in a nonevaporative environment, that is, without contacting the air.

    Abstract translation: 表面改性 描述了稳定的半透明或不透明聚氯乙烯树脂制品及其制备方法。 该制品包括着色颜料,其特征在于其中基本上不存在二氧化钛。 改性表面基本上没有残留的稳定剂和溶剂,其外观和表面完全程度与制品的未改性侧基本相同。 本发明的方法的特征在于将聚氯乙烯制品浸入合适的液体介质中,与紫外光稳定剂在合适的有机溶剂中的溶液接触,并在非蒸发环境中置换残留的稳定剂和溶剂,即 ,不接触空气。

    NOVEL POLY(MONOPEROXYCARBONATES)
    6.
    发明申请
    NOVEL POLY(MONOPEROXYCARBONATES) 审中-公开
    新型聚(单环氧羰基)

    公开(公告)号:WO1998007684A1

    公开(公告)日:1998-02-26

    申请号:PCT/US1997014694

    申请日:1997-08-22

    Abstract: New and novel poly(monoperoxycarbonates) of general structure (A), where R, R and n are defined in the summary of the invention such as 1,1,1-tris(t-butylperoxycarbonyloxymethyl)ethane, intermediates for their preparation as well as processes for their preparation and use are disclosed. The monoperoxycarbonate compounds are useful in initiating the polymerization of ethylenically unsaturated monomers, particularly styrene, curing of unsaturated polyester resins, and in modifying the molecular weight of polymers such as by cross-linking or controlled chain degradation.

    Abstract translation: 新型和新型的通式(A)的聚(单过氧碳酸酯),其中R,R 1和n在本发明的概述中定义,例如1,1,1-三(叔丁基过氧羰基氧基甲基)乙烷,其中间体 公开了制备及其制备和使用的方法。 单过氧碳酸酯化合物可用于引发烯属不饱和单体,特别是苯乙烯的聚合,不饱和聚酯树脂的固化,以及改性聚合物的分子量,例如通过交联或受控的链降解。

    MULTI-MODE ACCELEROMETER
    7.
    发明申请
    MULTI-MODE ACCELEROMETER 审中-公开
    多模式加速度计

    公开(公告)号:WO1993013426A1

    公开(公告)日:1993-07-08

    申请号:PCT/US1992011207

    申请日:1992-12-23

    CPC classification number: G01P15/0922 G01P15/18

    Abstract: An accelerometer (10) having a piezoelectric transducer (22) which produces electrical signals in response to its deflection and comprises an elongated, continuous beam of generally flat configuration and narrow cross section to provide a bending axis which facilitates deflection of the free ends in response to shock in one or more of the linear and torsional modes. The beam is supported intermediate its ends by a mount (29), with the free ends of the beam preferably extending equidistantly in opposite directions from the mount. By laminating a single piece of piezoelectric material to a rigid substrate and forming cantilevers in each deflection direction, an accelerometer with six degrees of freedom may be formed. Also, a compressive type angular accelerometer (122) may be formed from two piezoelectric sensor elements incorporated onto a single piece of piezoelectric polymer (126).

    Abstract translation: 一种具有压电换能器(22)的加速度计(10),该压电传感器(22)响应于其偏转而产生电信号,并且包括大体上平坦的构型和窄横截面的细长的连续梁,以提供弯曲轴线,该弯曲轴线有利于自由端的响应 在一个或多个线性和扭转模式中受到冲击。 梁通过安装件(29)在其端部之间支撑,梁的自由端优选地与安装件相反的方向等距离地延伸。 通过将单片压电材料层叠到刚性基板并在每个偏转方向上形成悬臂,可以形成具有六个自由度的加速度计。 此外,压缩式角加速度计(122)可以由结合到单片压电聚合物(126)上的两个压电传感器元件形成。

    COATING COMPOSITION FOR GLASS
    8.
    发明申请
    COATING COMPOSITION FOR GLASS 审中-公开
    玻璃涂料组合物

    公开(公告)号:WO1993013393A1

    公开(公告)日:1993-07-08

    申请号:PCT/US1992010873

    申请日:1992-12-21

    Abstract: A composition for coating glass by chemical-vapor deposition comprises a mixture of a tin oxide precursor monobutyltin trichloride, a silicon dioxide precursor tetraethylorthosilicate, and an accelerant such as triethyl phosphite; the composition is gaseous below 200 DEG C, and permits coating glass having a temperature from 450 to 650 DEG C at deposition rates higher than 350 ANGSTROM /sec. The layer of material deposited can be combined with other layers to produce an article with specific properties such as controlled emissivity, refractive index, abrasion resistance, or appearance.

    Abstract translation: 用于通过化学气相沉积涂覆玻璃的组合物包括氧化锡前体单丁基三氯化锡,二氧化硅前体四乙基原硅酸盐和促进剂如亚磷酸三乙酯的混合物; 该组合物是低于200℃的气体,并且允许以高于350安培/秒的沉积速率在450至650℃的温度下涂覆玻璃。 沉积的材料层可以与其他层结合,以产生具有特定性质如受控发射率,折射率,耐磨性或外观的制品。

    METHOD FOR COATING GLASS SUBSTRATES
    9.
    发明申请
    METHOD FOR COATING GLASS SUBSTRATES 审中-公开
    涂层玻璃基材的方法

    公开(公告)号:WO1993012892A1

    公开(公告)日:1993-07-08

    申请号:PCT/US1992010872

    申请日:1992-12-21

    Abstract: A method for coating glass by chemical-vapor deposition below 200 DEG C, at atmospheric pressure of a gaseous mixture of a tin oxide precursor, a silicon dioxide precursor and an accelerant such as triethyl phosphite provides deposition rates greater than 350 ANGSTROM per second. The layer of material deposited can be combined with other layers to produce an article with specific properties such as controlled emissivity, refractive index, abrasion resistance, and appearance.

    Abstract translation: 通过化学气相沉积在200℃,氧化锡前体,二氧化硅前体和促进剂如亚磷酸三乙酯的气体混合物的大气压下涂覆玻璃的方法提供大于每分钟350安培的沉积速率。 沉积的材料层可以与其他层组合以产生具有特定性质的物品,例如受控的发射率,折射率,耐磨性和外观。

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