Abstract:
PROBLEM TO BE SOLVED: To obtain trifluoropropene being an intermediate for a specific pentafluoropropane suitable as a blowing agent and a refrigerant in a high yield, by using an azeotropic mixture composed of HF and a specific trifluorochloropropene. SOLUTION: The azeotropic mixture containing HF and 1,1,1-trifluoro-3- chloro-2-propene (hereinafter, 1233 zd) is used, preferably a rectification column is utilized and the azeotropic mixture of HF/1233 zd is removed from a system rich in HF by a liquid phase method (or HF is separated by the removal) or the azeotropic mixture of HF/1233 zd is removed from the system by a vapor- phase method to give 1233 zd being an intermediate for producing 1,1,1,3,3- pentalfuoropropene (hereinafter, 245 fatty acid) in a high yield. COPYRIGHT: (C)1999,JPO
Abstract:
A U.V. stabilizer composition having a PVC resin-swellable organic solvent and a U.V. stabilizer present in the solvent. The U.V. stabilizer is present in a concentration of at least 18 wt % and effective to incorporate in the PVC resin at ambient temperature an amount of UV stabilizer effective to stabilize the surface of the PVC resin.
Abstract:
The present invention comprises a curable composition comprising: (i) a blocked reactive component comprising a blocked isocyanate or a blocked isothiocyanate; (ii) a functional component containing reactive hydrogen; (iii) a triorganotin catalyst for promoting the reaction of the blocked reactive component with the functional component. The composition may also be admixed with water. A co-catalyst may also be employed based on Cu, Zn, Ni, Fe, Co, V, Sb and Bi and especially oxides, salts or chelates of said metal where said metals are divalent. The invention also relates to a method for curing a blocked isocyanate or blocked isothiocyanate at a temperature below about 150 DEG C which comprises combining a triorganotin catalyst with the blocked reactive component and functional component and heating at a temperature less than about 150 DEG C to obtain a cured urethane or thiourethane.
Abstract:
A surface modified, U.V. stabilized translucent or opaque polyvinyl chloride resin article and process for making same is described. The article includes a colored pigment, and is characterized by the substantial absence of titanium dioxide therein. The modified surface is substantially free of residual stabilizer and solvent, and its appearance and degree of surface perfection is substantially the same as unmodified side of the article. The process of the invention is characterized by the steps of immersing the polyvinyl chloride article in a suitable liquid media, contacting with a solution of an ultraviolet light stabilizer in a suitable organic solvent, and displacing residual stabilizer and solvent in a nonevaporative environment, that is, without contacting the air.
Abstract:
Ammonia levels in a process gas stream (10) containing carbon dioxide and ammonia are separated and measured with a gas chromatograph (18) containing a photoionization detector (46). The ammonia levels in the process stream are monitored so that the formation of ammonium bicarbonate within the process pipes can be detected.
Abstract:
New and novel poly(monoperoxycarbonates) of general structure (A), where R, R and n are defined in the summary of the invention such as 1,1,1-tris(t-butylperoxycarbonyloxymethyl)ethane, intermediates for their preparation as well as processes for their preparation and use are disclosed. The monoperoxycarbonate compounds are useful in initiating the polymerization of ethylenically unsaturated monomers, particularly styrene, curing of unsaturated polyester resins, and in modifying the molecular weight of polymers such as by cross-linking or controlled chain degradation.
Abstract:
An accelerometer (10) having a piezoelectric transducer (22) which produces electrical signals in response to its deflection and comprises an elongated, continuous beam of generally flat configuration and narrow cross section to provide a bending axis which facilitates deflection of the free ends in response to shock in one or more of the linear and torsional modes. The beam is supported intermediate its ends by a mount (29), with the free ends of the beam preferably extending equidistantly in opposite directions from the mount. By laminating a single piece of piezoelectric material to a rigid substrate and forming cantilevers in each deflection direction, an accelerometer with six degrees of freedom may be formed. Also, a compressive type angular accelerometer (122) may be formed from two piezoelectric sensor elements incorporated onto a single piece of piezoelectric polymer (126).
Abstract:
A composition for coating glass by chemical-vapor deposition comprises a mixture of a tin oxide precursor monobutyltin trichloride, a silicon dioxide precursor tetraethylorthosilicate, and an accelerant such as triethyl phosphite; the composition is gaseous below 200 DEG C, and permits coating glass having a temperature from 450 to 650 DEG C at deposition rates higher than 350 ANGSTROM /sec. The layer of material deposited can be combined with other layers to produce an article with specific properties such as controlled emissivity, refractive index, abrasion resistance, or appearance.
Abstract:
A method for coating glass by chemical-vapor deposition below 200 DEG C, at atmospheric pressure of a gaseous mixture of a tin oxide precursor, a silicon dioxide precursor and an accelerant such as triethyl phosphite provides deposition rates greater than 350 ANGSTROM per second. The layer of material deposited can be combined with other layers to produce an article with specific properties such as controlled emissivity, refractive index, abrasion resistance, and appearance.
Abstract:
The invention concerns a composition of organotin maleates resulting from reacting a mixture of an alcohol or of an epoxyalkane of low molecular weight and of an alcohol or of an epoxyalkane of high molecular weight with maleic anhydride, then in contacting the resulting medium with a dialkyltin oxide. The invention also concerns the polyvinyl chloride (PVC) stabilised and lubricated with said composition with base of organotin maleates as well as the rigid extruded objects formed from said PVC compositions.